2014 Vol. 4, No. 3

Water Pollution Control Technology and Resource Utilization
Statistical Analysis of Influent Quality Characteristics of Municipal Wastewater Treatment Plants in Tianjin
SUN Yan, ZZHANG FENG, HU Hong-ying, NIU Zhang-bin
2014, 4(3): 173-180. doi: 10.3969/j.issn.1674-991X.2014.03.029
Abstract(2571) PDF(748KB)(866)
Abstract:
The influents of 24 wastewater treatment plants (WWTPs) in Tianjin were investigated to analyze the characteristics of water quality, the probability distribution of the main pollution indicators, and the correlations among the organic matter, suspended solids, nitrogen and phosphorus. The results showed that the trend of BOD5, CODCr, SS, NH3-N, TN and TP in the influents were in accordance with positively skewed distribution, and the concentrations of BOD5, CODCr, SS, NH3-N, TN and TP (monthly median) were in the range of 95-140 mg/L, 280-370 mg/L, 130-155 mg/L, 15-30 mg/L, 20-35 mg/L and 3-5 mg/L, respectively. Simple linear relationships among the six indicators could be observed, where BOD5 and TP have a significant correlation, and the correlation coefficients R2 was 0.983. The probability distribution of BOD5/CODCr ratios between 0.4 and 0.6 was 39.4%, and between 0.2 and 0.4 was at 50.2% of the cumulative frequency, indicating an adequate biodegradation ability of the influents. The probability distribution of BOD5/TN ratios less than 4 was 54.4%, 77.9% of the BOD5/TP ratios were above 20, which could meet the demand for biological phosphorus removal but not for denitrification. The probability distribution of TN/TP ratios between 5 and 15 was 73.6% with an average of 9.7, and 81.6% of the values were above 5. Therefore, the influents could meet the demands of nitrogen and phosphorus for microbial growth.
Effects of Cleaner Production Technologies of a Corn Starch Enterprise on Wastewater Treatment Effectiveness
GAO Peng, NIAN Yue-gang, YAN Hai-hong, YIN Qin, XIE Ya-wei, GUO Xiao-ya
2014, 4(3): 181-186. doi: 10.3969/j.issn.1674-991X.2014.03.030
Abstract(2128) PDF(507KB)(1056)
Abstract:
The problem diagnosis was performed for EGSB+A/O wastewater treatment process of a corn starch enterprise, and the cleaner production renovation measure were proposed for the enterprise. The effects of the cleaner production renovation measure on wastewater treatment effectiveness were investigated. The results showed that the operational efficiency of EGSB reactor could be enhanced by adding a centrifuge in the main workshop and vertical flow sedimentation tank in wastewater pretreatment section. The average CODCr concentrations of the inlet and outlet were reduced by 59% and 62% respectively, and the specific methane production rate was increased by 45%. After renovation engineering, the average CODCr, BOD5, NH4+-N, SS concentrations of the effluent wastewater from the secondary sedimentation tank were reduced from 124, 31, 57 and 33 mg/L to 55, 9, 4.5 and 19 mg/L, respectively, and the pH value was 6.3-6.9, all meeting with Discharge Standard of Water Pollutants for Starch Industry (GB 25461-2010). The clean production renovation engineering could also create an annual economic benefit of 1.320 4 million Yuan.
Test on Pretreatment of Wet-spun Acrylic Fibre Wastewater by Fe-C Microelectrolysis Process
CUI Xiao-yu, ZENG Ping, TIAN Zhi-yong, SONG Yong-hui, SHAN Yong-ping, XIAO Shu-hu
2014, 4(3): 187-191. doi: 10.3969/j.issn.1674-991X.2014.03.031
Abstract(2142) PDF(362KB)(758)
Abstract:
Wet-spun acrylic fibre wastewater was pretreated by Fe-C microelectrolysis reactor process. The effects of iron dosage, active carbon dosage and reaction time on the pretreatment results were investigated by single factor experiments. The results showed that the wet-spun acrylic fibre wastewater with initial CODCr of 1 076 mg/L, CN- of 5.50 mg/L could be effectively pretreated by Fe-C microelectrolysis process. The CODCr removal efficiency reached above 36.0%, while CN- removal efficiency reached higher than 90 % under the conditions of both iron and activated carbon dosages 35 g/L, reaction time 90 min, pH 4.50. The process was effective and easy to control. The BOD5/CODCr ratio was increased from 0.39 to 0.56, so the biodegradability of wastewater was increased significantly.
Pollution Control and Watershed Management
Influence Assessment of Environmental Governance Project on Aquatic Ecosystem Health of Lihu Lake
DU Yun-xuan, JIANG Xia, WANG Wen-wen, LI Jia-lu, WANG Shu-hang
2014, 4(3): 192-198. doi: 10.3969/j.issn.1674-991X.2014.03.032
Abstract(2121) PDF(418KB)(770)
Abstract:
To reveal the influence of the environmental governance project on aquatic ecosystem health of Lihu Lake, an aquatic ecosystem health comprehensive index (EHCI) system was developed by physicochemical indexes and ecological indexes, and weight coefficient of each index was established based on entropy weight method. The results showed that the aquatic EHCI was between 21.65 and 72.74 during 1992-2012, which mainly decreased first and then rose remarkably. The health level increased from grade Ⅳ“poor” in 2003 to gradeⅡ“good” in 2012 after the implementation of environmental governance project since 2003. Spatially, the aquatic ecological health level in West Lihu Lake was better than that in East Lihu Lake, especially in the returning fishery to lake area (Area A), which was close to gradeⅠ“very good”. However, due to less management engineering, Area D was worse and was still in grade Ⅲ “medium”. The evaluation results conformed to the actual survey results for aquatic ecosystem in each area of Lihu Lake. The method can provide reference for aquatic ecological health evaluation of other similar lakes.
Distribution, Sources and Risk Assessment of Polycyclic Aromatic Hydrocarbons in Sediments from Zhushan Bay Littoral Zone, Lake Taihu
CHEN Ming-hua,  LI Chun-hua,  YE Chun,   XU Shi-hong
2014, 4(3): 199-204. doi: 10.3969/j.issn.1674-991X.2014.03.033
Abstract(2285) PDF(387KB)(820)
Abstract:
Surface sediment samples were collected from lakeside zone of Zhushan Bay, Lake Taihu, of which 10 samples were collected from the littoral zone and one sample was collected from the center of the lake. The concentrations of 16 US EPA-priority-controlled polycyclic aromatic hydrocarbons (PAHs) were analyzed by GC-MS. The results showed that PAHs content varied from 61.2 to 2 032.3 ng/g, and the mean value was 1 131.5 ng/g. The spectra of PAHs showed that 4 rings and 5-6 rings were predominant ones in littoral zone, accounting for 28.6% and 60.9%, respectively, while 2-3 rings PAHs were predominant in the center of the lake, accounting for 88.1%. The source of PAHs in littoral zone sediments was mainly attributed to high-temperature combustion of coal, oil and other fossil fuels, but that in center of the lake was mainly attributed to oil spill. No significant PAH ecological risk was found in littoral zone of Lake Taihu according to ecological risk assessment. However, some PAH concentrations exceeded the effects range low (ERL) in some sampling sites. Potential harmful effects on organisms might exist, and ecological risk should be prevented.
Air Pollution Control Technology and Usage of Clean Energy
Study on Co-oxidation of Gaseous Elemental Mercury of Coal-fired Flue Gas by Wastewater Injection
SHI Ying-jie, DU Ji-jun, WANG Hong-mei, WANG Xiang-feng, TIAN Gang, ZHANG Fan, SANG Jian
2014, 4(3): 205-211. doi: 10.3969/j.issn.1674-991X.2014.03.034
Abstract(2124) PDF(451KB)(816)
Abstract:
The Hg0, Hg2+ and Hgp distribution of coal-fired flue gas was investigated by the OHM and hydride generation-inductively coupled plasma atomic emission spectrometry (HG-ICP-AES) method. The impacts of chlorine and sodium content of wastewater and SO2 and NO concentration of flue gas on Hg0 oxidation were tested on the coal-fired test furnace in hot state. The results showed that the ferrous and chlorine content in the test coal was low and the ratio of Hg0 to HgT was 68.3% and 80.6% for coal-fired flue gas 1# and 2# respectively, while Hg2+ ratio was only 22.2% and 13.1% respectively. When the sodium acrylate and naphthalene sulfonate wastewater liquid to flue gas ratio was 0.028 L/m3, the Hg2+ ratio reached higher than 80% and 75% in coal-fired flue gas 1# and 2# respectively. While, there were no significance variations for Hgp ratio in flue gas. When the wastewater liquid to flue gas ratio was 0.028 L/m3, the SO2 concentration decreased by 11.4%-15.7% and 12.2%-17.7% for coal-fired flue gas 1# and 2# respectively, which accelerated Hg0 oxidation. There was no significant effect of NO in flue gas on Hg0 oxidation.
Research Progress of Indoor Ammonia Pollution in Civil Buildings
NIE Peng, WANG Zong-shuang, WANG Sheng, TAN Yu-fei, XU Shu, CHE Fei, LI Qin, WU Xue-fang
2014, 4(3): 212-219. doi: 10.3969/j.issn.1674-991X.2014.03.035
Abstract(2246) PDF(318KB)(786)
Abstract:
Aiming at the problem of indoor ammonia pollution in civil buildings, the research progress of current status, polluting sources, releasing rules, effects on human health and related control measures of indoor ammonia pollution at home and abroad was introduced. The results show as follows: the indoor ammonia pollution in China is complex, and the hairdressing sites are highly polluted with ammonia; in other civil constructions, the indoor ammonia pollution is mainly due to the construction and decoration materials and has regional differences, with worse pollution in northern part of the country than in southern part. The pollution abroad is less serious in foreign developed countries. The research on the effect of low-level ammonia pollution on human health is rare both at home and abroad. The domestic researches focused on indoor ammonia pollution prevention while foreign researches mainly focused on the control of indoor ammonia pollution at the field of husbandry and aquaculture. China had established a series of standards or regulations about indoor ammonia pollution while there were no related reports in other developed countries except Finland. Finally, suggestions on further researches on indoor ammonia pollution were put forward.
Solid Waste and Chemical Management Technique Center of Ministry of Environment Protection
YE Jing, HUO Li-bin, NIE Jing-lei
2014, 4(3): 220-224. doi: 10.3969/j.issn.1674-991X.2014.03.036
Abstract(2151) PDF(239KB)(1123)
Abstract:
The legal basis, pollutants selection and evaluation of toxic air pollution control in USA were introduced in terms of chemical substances. The approaches to toxic air pollution control stipulated by the laws and regulations were also introduced. Finally, the suggestions on strengthening chemical environmental management and jointly promoting air environmental protection were proposed.
Pollution Control Technology Evaluation and Planning
A Correlation Analysis of Heavy Metals (Lead) in Lead-acid Battery Manufacture
BAI Wei-nan, YAO Yang, QIAO Qi, ZHANG Yue, SUN Qi-hong
2014, 4(3): 225-230. doi: 10.3969/j.issn.1674-991X.2014.03.037
Abstract(2167) PDF(441KB)(933)
Abstract:
In order to implement the national heavy metal pollution prevention and control plan, it is imperative to establish the management and evaluation methods for intensity access of heavy metals in key industries. The existing problems in the development of the lead-acid battery manufacture in China were briefly reviewed, and the major processes and pollution generation links analyzed. Correlation analysis for lead generation intensities in both wastewater and waste gas was performed based on the statistical analysis software of SPSS. The results showed that two factors including water usage intensity and seven factors with intensity of gas emissions, which were significantly correlated to lead generation intensity in wastewater and waste gas respectively, could be used as indicative factors for lead generation intensity. The findings could provide indirect judgment for industries to promote improvement of production and management for reduction of lead generation intensity. They could also provide new perspectives for study on establishment of evaluation index system of heavy metal generation intensities.
Development of Non-ferrous Smelting Pollution Source Emission Compliance Assessment and Dynamic Management System
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2014, 4(3): 231-236. doi: 10.3969/j.issn.1674-991X.2014.03.038
Abstract(1843) PDF(356KB)(806)
Abstract:
It is an important aspect of environmental management to guarantee the industrial pollution emission in compliance with the standards. The compliance assessment needs to adopt the idea of the whole process control and track the emission dynamically. On the basis of projecting the emissions of pollutants, the assessment method for emission compliance feasibility of pollution sources of non-ferrous smelting enterprises was proposed, including the Emission Coefficient and Emission Model methods. The non-ferrous smelting pollution source emission compliance and dynamic management system (N-FSPSECDMS) was developed. The system with Emissions Model method was chosen to evaluate the pollution emission from chimneys of anode stove in enterprise A. The results showed: the SO2 emission concentration (538 mg/m3) from anode furnace cannot meet with the emission standard requirement, and thus three options to increase the environmental performance were proposed including saving energy, performing clean production audit and establishing environmental management system. According to modeling and optimization of the system, the SO2 emission concentration of the three options were 370, 365 and 292 mg/m3 respectively, all meeting with the emission standard.
Cleaner Production and Eco-industrial Technology
Case Analysis and Suggestions of Implementing Cleaner Production in Aluminum Electrolytic Industry
SHEN Chen, ZHOU Chang-bo, LI Xuhua, PEI Qian-qian, ZHU Ningfang, LI Zi, DANG Chun-ge, FANG Gang
2014, 4(3): 237-242. doi: 10.3969/j.issn.1674-991X.2014.03.039
Abstract(2207) PDF(304KB)(924)
Abstract:
Based on the current situation and development trend of the aluminum electrolytic industry in China, it was pointed out that the effective way of sustainable development of aluminum electrolytic industry is carrying out cleaner production audit in the whole industry. One case of cleaner production audit in an aluminum electrolytic enterprise showed that, during the process of cleaner production audit, the pollution reduction ability and the energy resource utilization efficiency were improved and great benefits in both economy and environment for the enterprise obtained. Through summarizing the results of enterprise cleaner production audit, several suggestions were put forward in pursuing cleaner production, such as policy guiding, technology R&D and demonstrations setting.
Evaluation Method of Best Available Cleaner Production Technology Based on Emission Reduction of Ammonia in Nitrogen Fertilizer Industry
LUO Qi-jin, CHEN Jian-yu, WANG Zhen-xing, PANG Zhi-hua, YE Wan-sheng
2014, 4(3): 243-247. doi: 10.3969/j.issn.1674-991X.2014.03.040
Abstract(2234) PDF(322KB)(1176)
Abstract:
The current environmental technologies evaluation methods are mainly based on experts’ qualitative estimation and lack of comprehensive evaluation methods. Aiming at this problem and combined with the total ammonia discharge control requested by National Economic and Social Development Plan in 2011-2015 and the ammonia discharge reduction demand of nitrogen fertilizer industry, the index system and an integrated evaluation method for cleaner production technology evaluation based on ammonia discharge reduction was built. The weight of each index was obtained with analytic hierarchy process (AHP), and the discharge reduction technologies evaluated using grey correlation analysis method. The modeling process of the mathematical model of the integrated evaluation method was provided with an application example analyzed.
Biological and Ecological Engineering and Recovery Technology
Analysis of carbon fixation and oxygen release capabilities of 17 afforest plants of rural-urban fringe in Beijing
XIONG Xiang-yan, HAN Yong-wei, GAO Xin-ting, SHANG Hong-lei, ZHENG Ye, WANG Bao-liang
2014, 4(3): 248-255. doi: 10.3969/j.issn.1674-991X.2014.03.041
Abstract(2227) PDF(491KB)(858)
Abstract:
Carbon fixation and oxygen release (CFOR) is an important ecological service of the plants. Li-6400 portable photosynthesis test system and Li-2000 plant canopy test system were employed to observe the physiological velocity and leaf area index of 17 widely used afforestation plants in the rural-urban fringe of Chaoyang District, Beijing. The cluster analysis was adopted to classify their CFOR capacities, and the CFOR benefits evaluated quantitatively. The results indicated that the diurnal change curve of net photosynthesis rates of 17 experimental species has one or two peaks. The daily carbon fixation and oxygen release per unit leaf area was respectively 2.92-13.81 g/(m2·d) and 2.12-10.05 g/(m2·d). The daily carbon fixation and oxygen release per unit land area was respectively 11.00-92.71 g/(m2·d)and 8.00-67.42 g/(m2·d). According to cluster analysis results, the CFOR capabilities per unit leaf area of 9 arbors are divided into two levels, 5 shrubs divided into two levels, and 3 herbs divided into two levels. The CFOR capabilities per unit land area of 9 arbors are divided into two levels, 5 shrubs divided into three levels, and 3 herbs divided into two levels. Therefore, in order to enhance the CFOR capabilities of the vegetation system in the rural-urban fringe, not only should the plants which have higher capabilities of CFOR be chosen, but also they should be configured properly through composite model.
Dynamic Analysis on Ecological Carrying Capacity of Dantu District, Zhenjiang City in 2000-2010
JIN Xia, XIANG Bao, YIN Shan, FANG Guang-ling, HU Yu, ZHANG Li-kun
2014, 4(3): 256-262. doi: 10.3969/j.issn.1674-991X.2014.03.042
Abstract(1940) PDF(398KB)(863)
Abstract:
The traditional ecological footprint model only considers the demand of human to resources and the basic function of land and neglects the service function of land ecosystem. The ecosystem service function theory was referred to improve the ecological footprint model, and the value equivalent factor of ecosystem service function introduced in the calculation of equilibrium factor and yield factor in the model, so as to embody the integrity of the ecosystem. The improved model was used to calculate the ecological footprint per capita, the ecological carrying capacity per capita and the ecological deficit per capita of Dantu district from 2000 to 2010 based on its statistic data, and to analyse the ecological footprint per unit GDP. Results showed that the ecological footprint per capita of the district was increased from 6.870 2 hm2 in 2000 to 7.576 7 hm2 in 2010, the ecological carrying capacity per capita was decreased from 5.296 8 hm2 in 2000 to 4.998 3 hm2 in 2010. There existed ecological deficit and it increased from 1.573 4 hm2 in 2000 to 2.578 3 hm2 in 2010, which meant the regional developmental pattern was unsustainable. Besides, according to the GM(1,1) model, it was predicted that the ecological footprint per capita would expand to 8.117 0 hm2 in 2015 and 11.019 3 hm2 in 2020, the ecological deficit per capita would be 4.671 4 hm2 in 2015 and 7.567 5 hm2 in 2020, the ecological footprint per ten thousands Yuan GDP would be 0.702 3 hm2 in 2015 and 0.336 2 hm2 in 2020. Finally, the sustainable development measures were proposed from the viewpoint of ecological capacity and combined with the actual situation of Dantu district.