2015 Vol. 5, No. 5

Environmental Risk Assessment and Management Technology
Technological Innovation Progress of Risk Sources Identification and Monitoring of Sudden Environmental Pollution Accidents:(I) Risk Sources Identification Technologies and Applications
SONG Yong-hui, YUAN Peng, PENG Jian-feng, HAN Lu, ZHANG Mo-li
2015, 5(5): 347-352. doi: 10.3969/j.issn.1674-991X.2015.05.055
Abstract(2272) PDF(3697KB)(1544)
Abstract:
Environmental risk prevention and control and environmental risk source management is one of the important tasks of environmental management in China. In order to prevent and control major environmental pollution accidents, and to carry out efficient management of environmental risk sources and make scientific decision, the risk source identification, monitoring and management technologies for major environmental pollution accidents were developed. International experiences on environmental risk source management were summarized. Based on the principle of environmental risk source management “by type, by grade and by region”, the methods for environmental risk source classification, identification and quantitative-grading were developed. The methods could be used for environmental risk source classification on the typical chemical industrial park, mega-city and countrywide scale. A list of national key risk enterprises of petrochemical chemical industry was put forward. The environmental risk source integrated management system was developed, which could provide technical support for the key environmental risk sources supervision and the environmental risk control.
Technological Innovation Progress of Risk Sources Identification and Monitoring of Sudden Environmental Pollution Accidents:(II) Risk Sources Monitoring Technology and Case Study
SONG Yong-hui, HAN Lu, WEN Li-li, YUAN Peng, PENG Jian-feng
2015, 5(5): 353-360. doi: 10.3969/j.issn.1674-991X.2015.05.056
Abstract(1763) PDF(4034KB)(1130)
Abstract:
The advanced experience of the environmental risk source monitoring techniques in foreign and domestic countries was summarized, and the characteristics of China’s environmental risk source monitoring techniques analyzed. It was pointed out that compared with the developed countries, there existed many problems in the environmental risk source monitoring techniques in China. The basic information of environmental risk sources was not clear, the monitoring indicators could not meet the environmental management needs and the monitoring and management mode of environmental risk sources was relatively backward. Based on the user requirement analysis, the design principles of the environmental risk source monitoring technique system were put forward, i.e. the principles of supreme, reliability, integrity and economic interest. According to the technical line of information process of “data acquisition, transmission, processing and application”, the environmental risk source monitoring technique system was constructed from five aspects, i.e. the monitoring scheme design, the monitoring equipment technology, the monitoring data acquisition and transmission, the monitoring network structure, and the monitoring management system, etc. Finally, the environmental risk source monitoring techniques were applied and demonstrated in Minhang District of Shanghai, Gaoqiao Petrochemical Area of Shanghai and Zhangjiakou City.
Classification Method of Urban Industrial Environmental Risk Sources and Its Application
YUAN Peng, XU Wei-ning, WANG Ye-yao, PENG Jian-feng, SONG Yong-hui
2015, 5(5): 361-367. doi: 10.3969/j.issn.1674-991X.2015.05.057
Abstract(1877) PDF(716KB)(1220)
Abstract:
In recent years, urban environmental risk problems caused by high-risk industries have been widely concerned. Urban environmental risk source classification is an important issue for urban environmental emergency management and guarantee of urban environmental safety. According to the environmental risk system theory and comprehensively considering the risk source, the accident spreading, the controlling ways and the environmental receptors, a classification evaluation index system based on the amount of environmental risk substances, the production process and risk control technical levels, and the sensitivity of environmental risk receptors was set up. The grade evaluation matrix of risk sources was established. The urban environmental risk sources were classified into 3 grades, i.e. high risk sources, ordinary risk sources and low risk sources. With Shanghai city as the case study area, the identification and classification of the environmental risk sources were conducted in 882 key enterprises in 17 districts. The results showed that there were 151 high risk sources and 161 ordinary risk sources, accounting for 17.1% and 18.3% of all the evaluated enterprises, respectively. Finally, the risk prevention and control countermeasures were proposed for the main districts, such as Jinshan District, Baoshan District and Minhang District.
Study on Environmental Risk Management Technology of Enterprises and Tailing Ponds
HAN Lu, SONG Yong-hui, YUAN Peng, XU Wei-ning, YU Bo-fan
2015, 5(5): 368-373. doi: 10.3969/j.issn.1674-991X.2015.05.058
Abstract(2010) PDF(847KB)(1204)
Abstract:
The city under research possesses rich mineral resources and is located at the upper stream of the drinking water source of one megacity. With the development of the mining and chemical industries, sudden environmental pollution accidents occurred frequently, and thus the environmental risk problems have attracted more and more attention. Based on the evaluation method of the national enterprise environment risk grading, and in combination with the hazard of tailings and sensitivity of environmental receptors, the risk level of 67 enterprises and more than 500 tailing ponds in the city were analyzed, and the risk grades of the enterprises and tailing ponds were classified. The results showed that there were 12 major risk source enterprises, accounting for 18% of all the investigated enterprises, and 17 general risk source, accounting for 25% of the total. For tailings pond result, there were 32 major risk sources, 78 general risk sources and 410 non-environmental risk sources. Subsequently, the substances, objectives, sites and indexes for monitoring the environmental risk in the area were discussed, and the optimized monitoring technical scheme for enterprises and tailing ponds was put forward. The scheme involves risk evaluation and monitoring of different levels with regard of both regular indexes and typical pollutants indexes, which should effectively improve the risk management level.
Regional Environmental Risk Assessment of Petrochemical Plants under Domino Accident Scenarios
ZHANG Jun-ming, YUAN Peng, XU Wei-ning, HAN Lu, SONG Yong-hui, GUO Ji-xiang
2015, 5(5): 374-379. doi: 10.3969/j.issn.1674-991X.2015.05.059
Abstract(2078) PDF(1420KB)(1238)
Abstract:
In recent years, the regional environmental risk caused by centralization of various kinds of petrochemical plants is increasingly significant, which urgently needs to be addressed to ensure the regional environmental safety. Based on the analysis of domino accidents risk among the installations at the regional scale, and integrated with the logical operation expressions for domino effect and the accident possibility calculation methods, the regional environmental risk assessment method was obtained in combination with the information diffusion method. In the case study, the method was used to assess the regional environmental risk of a city and the assessment results were visualized by the application of ArcGIS software. The results showed that the risk management departments should pay high attentions to three areas with extremely high risk, give high priorities when allocating management resources, and adopt mandatory measure to reduce the risks in these areas.
Design of Monitoring Technology Library for Key Environmental Risk Sources
HAN Lu, YU Bo-fan, SONG Yong-hui
2015, 5(5): 380-385. doi: 10.3969/j.issn.1674-991X.2015.05.060
Abstract(1744) PDF(1299KB)(1170)
Abstract:
The major environmental pollution accidents have occurred frequently in China and there is an increasingly urgent demand of environmental risk management. Aiming at the current status of lacking systematic analysis and classification of environmental monitoring technologies for risk sources, the monitoring technology library of key environmental risk sources was systematically studied. Based on the collection of data and the analysis of existing pollutant monitoring technologies and principles, and combined with the mature equipment information, the technology library was designed in terms of monitoring technology indicators, parameters, principles, technical methods and equipment selection, etc. This library can provide sound technical support for China's environmental risk management.
Development of Establishing Technology of Abrupt Environment Accident Case Library for Emergency Management Based on Case-based Reasoning
ZHANG Mo-li, YUAN Peng, SONG Yong-hui, ZHANG Hui-liang, JIANG Shi-hui
2015, 5(5): 386-392. doi: 10.3969/j.issn.1674-991X.2015.05.061
Abstract(1539) PDF(2368KB)(1284)
Abstract:
In recent years, abrupt environmental pollution accidents occurred frequently in China, having resulted in huge hazards on socio-economic development. Through structured hierarchical storage and searching technology based on case reasoning, the emergency management application case library can be established, with which historical matching cases can be found by quick search, and then relatively optimal solution tools can be provided for the policy makers. The realization approaches of information database based on case-reasoning retrieval technology were explored. The contents of the case library were researched, the structure was designed and the system developed. Finally the case retrieval system of abrupt environmental pollution accidents based on Web technology was established, which included more than 500 cases. The system takes the nearest neighbor decoding to search similar fitting cases, possessing retrieving, correcting, studying and statistical analysis functions and so on. It can provide references for the emergency response to the newly happened abrupt environmental accidents.
Research Progress of Cumulative Environmental Risk Assessment at Home and Abroad
YUAN Peng, LI Wen-xiu, PENG Jian-feng, SONG Yong-hui, XU Wei-ning
2015, 5(5): 393-400. doi: 10.3969/j.issn.1674-991X.2015.05.062
Abstract(2312) PDF(2070KB)(2400)
Abstract:
With the focuses of environmental risk assessment gradually evolving from assessment of single source or stressor, single exposure route and single risk receptor toward integrated assessment involving several sources or stressors, multiple exposure routes and multiple receptors in recent years, the cumulative risk assessment has become a study hot spot. Through concepts discrimination and literatures search, the development history and assessment procedure in the US, and the methods and practices of cumulative risk assessment both at home and abroad were reviewed. It was pointed out that there were several problems in conducting cumulative risk assessment in China, such as lack of assessment methods, lack of basic scientific data and urgent need of reinforcement of macro-environmental management policy and so on. It was suggests that the concept and management requirements of cumulative environmental risk assessment should be defined, the evaluation process, framework and technical guide be formulated, and the construction of foundational databases and practical explorations be reinforced as soon as possible,which can provide the decision support for the long-term effective environmental management.
Air Pollution Control Technology
Research on Urban Management Strategy to Improve Air Quality in Beijing
CHEN Jian-hua, XUE Wen-bo, ZHOU Yang-sheng
2015, 5(5): 401-406. doi: 10.3969/j.issn.1674-991X.2015.05.063
Abstract(1822) PDF(714KB)(1012)
Abstract:
The problem of air pollution in Beijing has been generally focused on by the government and the public in recent years. The effect achieved in controlling the air pollution in Beijing was summarized, and the challenge faced and the key problems and causes existing in the urban management analyzed. The suggestions on controlling the air pollution were put forward, including optimizing the urban function and spatial framework, controlling strictly the total consumption of coal, giving play to the function of the environmental impact assessment system, accelerating the reduction of vehicle emissions, speeding up the construction of ecological environmental system, and improving the construction of regional air pollution control system.
Research of NOx Emission Test Method for In-use Diesel Vehicles
WANG Jun-fang, YIN Hang, DING Yan, WANG Hong-li, XIAO Han, TENG Qi, YUAN Cai-hong, YIN Bao-hui
2015, 5(5): 407-410. doi: 10.3969/j.issn.1674-991X.2015.05.064
Abstract(2012) PDF(1356KB)(1327)
Abstract:
The test for NOx emission from in-use diesel vehicles were conducted based on the lug-down test method regulated in GB3847-2005. The results showed that the concentration of NOx cannot be easily tested by the lug-down test method due to high fluctuation of pollutant concentration and the limit of instrument response time. Therefore, the lug-down test method was not able to obtain stable emission concentration of NOx. The test scheme design was adjusted, and the engine dynamometer test was performed. The 100% and 80% of the rated speed were adopted as the test modes of NOx emission for in-use diesel vehicles. By comparison of three test schemes, Scheme 3 which set two different test modes was reasonable to test the NOx emission for in-use diesel vehicles. The two test modes were under 100% and 80% of the rated speed respectively, with the operating time of 12 seconds for both modes.
Watershed Pollution Control Technology
Investigation on Growth Situation and Soil Property of Grass-forest System in Lake Buffer Zone of Zhushan Bay, Lake Taihu
YE Bin, HUANG Lan-ying, LI Chun-hua, LI Chun-jiang
2015, 5(5): 411-417. doi: 10.3969/j.issn.1674-991X.2015.05.065
Abstract(1573) PDF(1492KB)(919)
Abstract:
The sample plot survey and analysis methods were applied to investigate four typical grass-forest systems in lake buffer zone of Zhushan Bay of Lake Taihu, including wetland grass-forest system, poplar protection forest, nearby tributary grass-forest system and taxodiumascendens protection forest. The soil nutrient contents of organic matter, nitrogen and phosphorus, the plant growth situation including biodiversity, canopy density and grass coverage, the bacterial population and soil physical properties were studied in detail. The results showed that the organic matter contents of surface soil was between 15.1 g/kg and 40.3 g/kg (level 1 to 4), overall at rich level; the total nitrogen content of soil was between 0.76 g/kg and 1.13 g/kg (level 3 to 4), overall at medium or slightly low level; while the total phosphate content was between 0.09 g/kg and 0.17 g/kg, all at level 6 (extremely low level). Compared with the soils in China and other countries, the organic matter, total nitrogen, ammonium nitrogen and nitrate nitrogen contents in Zhushan Bay were totally at a medium level, while the total phosphate content was at a low grade. The soil nutrient index calculated from bacterial population indicated that the nutrient levels of the four grass-forest systems were very low, only between 0.003 and 0.014. The evaluation on plant growth situation showed that the grass-forest system was relatively good, but all the four grass-forest systems had very low biodiversity. Therefore, it is difficult to recommend a good grass-forest system example only from the present four systems.
Biological Metabolic Transformation of Polybrominated Diphenyl Ethers and Tetrabromobisphenol A
SHEN Meng-nan, GAO Shi-xiang
2015, 5(5): 418-423. doi: 10.3969/j.issn.1674-991X.2015.05.066
Abstract(1799) PDF(867KB)(1816)
Abstract:
The distributions and sources of PBDEs and TBBPA in organism were analyzed, and the research progresses of reduction and oxidation metabolism of PBDEs and TBBPA in organisms were reviewed. The metabolism, pathways, and key enzymes involved in the biotransformation of them both in vivo and in vitro were explored. Directions for further studies on the bioaccumulation and biotransformation of PBDEs and TBBPA were proposed.
Soil Pollution Control Technology
Spatial Distribution of Heavy Metals in Soils during Urban Development of Beijing
GUO Guang-hui, LEI Mei, QIAO Peng-wei
2015, 5(5): 424-428. doi: 10.3969/j.issn.1674-991X.2015.05.067
Abstract(1594) PDF(1695KB)(1246)
Abstract:
The concentrations and distribution characteristics of heavy metals in Beijing city soils in 2005-2014 were collected and analyzed systematically, in order to explore the variations of soil quality generated by urban expansion and the space-time changes of soil environment under the urban development. The results indicated that the mean concentrations of Cu, Pb, Zn and Cr in soils in Beijing were 31.39, 31.76, 87.88 and 57.90 mg/kg, respectively, which were significantly higher than the corresponding background values (P=0.00). There was no significant difference between mean concentration and background value for Cd in soils in Beijing (P=0.464). The concentrations of heavy metals in loop lines of Beijing showed a decreasing trend from inside to outside. Accumulations of Cu, Zn, and Pb were found in 2nd Ring Road, while Cu, Zn, and Cr in 3rd, 4th, and 5th Ring Roads. As for functional zones, the highest synthetical pollution index was 2.27 in soils from parks, followed by residential area (1.96), traffic area (1.90) and institutes area (1.87). High concentrations of Cu and Pb were found in soils from Park, with higher Zn and Pb in resident area, and Zn and Cu in traffic area and institutes area. Therefore, accumulations of Cu, Zn, Pb and Cr in soils were urgent concerns in management of soil quality, and more attentions should be paid to the accumulations of heavy metals in soils from parks in Beijing.
Industry pollution control technology
Study on Chemical Stripping Characteristics of Polarizer from Waste LCD
SHE Ling-ling, RUAN Jiu-li, GUO Yu-wen, QIAO Qi
2015, 5(5): 429-434. doi: 10.3969/j.issn.1674-991X.2015.05.068
Abstract(1921) PDF(2078KB)(1456)
Abstract:
The recycling process of waste LCD panel should take into consideration of the removal of the polarizer. With the aid of ultrasonic wave and heating, the polarizer was stripped by alkali solution. The influences of the temperature, concentration of alkali and ultrasonic frequency on the separation of the polarizer were analyzed. And then the glass substrate was extracted by concentrated sulfuric acid and aqua regia successively. The leaching characteristics of indium were also analyzed. The result showed that in the presence of ultrasonic wave and under the temperature range of 50-80 ℃, the polarizer could be separated efficiently from waste LCD panel by sodium hydroxide solution. Besides, the separation of the polarizer only took 37 min with the temperature of 70 ℃, ultrasonic frequency of 45 kHz and NaOH concentration of 0.1 mol/L. The transfer of the indium did not occur during the process of the chemical stripping when the concentration of NaOH was 0.1 and 0.3 mol/L.
Research on Modification of Heavy Metal Generation Coefficients in Lead-acid Battery Manufacture
BAI Wei-nan, SUN Qi-hong, QIAO Qi, YAO Yang, ZHAO Ruo-nan
2015, 5(5): 435-441. doi: 10.3969/j.issn.1674-991X.2015.05.069
Abstract(1683) PDF(1629KB)(1168)
Abstract:
Combined with the main manufacturing processes in typical industries related to heavy metals, key links and nodes generating the heavy metals were analyzed, and the critical nodes apart from “the four same factors”(i.e. the same raw material, the same product, the same scale, the same process) which were significantly correlated with the generation intensity of the heavy metals were screened. Then, the comprehensive evaluation indicators system for heavy metal generation intensity was constructed by the Experts Grading Method and the Analytic Hierarchy Process (AHP), and the comprehensive evaluation index was acquired. Finally, the fitting model was constructed to modify the original lead generation coefficients. The modified model for a specified “the four same factors” in lead-acid battery manufacture was obtained, namely ηlead=0.017 6G3-2.76G2+148G+813.
Analysis on Ultrafiltration Membrane Fouling and the Prevention Measures
MA Zhi-jing, SONG Ying-hao, ZHANG Zhan-mei, LIU Xiu-juan
2015, 5(5): 442-446. doi: 10.3969/j.issn.1674-991X.2015.05.070
Abstract(2650) PDF(1182KB)(1539)
Abstract:
The problem of membrane fouling of ultrafiltration caused by the municipal middle water running in the boiler feed water system of one thermal power plant of Shenhua Guoneng Energy Group Co., Ltd. was studied. The running data of ultrafiltration, the municipal middle water quality index and the fouling matter from ultrafiltration were comprehensively analyzed. It is found that the main reason for the membrane fouling of ultrafiltration is the over-standard of CODCr and NH3-N in the middle water from the wastewater treatment plant. The adjustment of the running conditions can be an effective measure to reduce the membrane fouling of ultrafiltration. Through the adjustment of the condition parameters, the trans-membrane pressure and the water inflow of ultrafiltration membrane can meet the operation requirements of the thermal power plant, indicating that this measure can effectively reduce the membrane fouling of ultrafiltration.