Volume 9 Issue 3
May  2019
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Article Navigation >  Journal of Environmental Engineering Technology  > 2019  >  9(3): 275-281
LI Yanan, TAN Yu, WU Changyong, LIU Hengming, ZHOU Yuexi. Application and problems of catalytic ozonation in advanced treatment of petrochemical wastewater[J]. Journal of Environmental Engineering Technology, 2019, 9(3): 275-281. doi: 10.12153/j.issn.1674-991X.2019.02.280
Citation: LI Yanan, TAN Yu, WU Changyong, LIU Hengming, ZHOU Yuexi. Application and problems of catalytic ozonation in advanced treatment of petrochemical wastewater[J]. Journal of Environmental Engineering Technology, 2019, 9(3): 275-281. doi: 10.12153/j.issn.1674-991X.2019.02.280
shu

Application and problems of catalytic ozonation in advanced treatment of petrochemical wastewater

doi: 10.12153/j.issn.1674-991X.2019.02.280

  • 1. School of Marine Science and Technology and Environment, Dalian Ocean University, Dalian 116023, China

  • 2. Research Center of Water Pollution Control Technology, Chinese Research Academy of Environmental Sciences, Beijing 100012, China

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  • Corresponding author: Yuexi ZHOU E-mail: zhouyuexi@263.net
  • Received Date: 2018-12-30
  • Publish Date: 2019-05-20
    Abstract
  • Biological effluent of petrochemical wastewater treatment plant contains toxic and refractory organic compounds, which is difficult to be furtherly treated by biological process. However, with the implementation of Emission Standard of Pollutants for Petroleum Chemistry Industry (GB 31571-2015) after July 1, 2015, the petrochemical wastewater treatment plants had experienced great centralized technology improvement. Meanwhile, most of the advanced treatment units have been built by ozone/catalytic ozonation process to achieve the discharge standard. At present, most of these advanced treatment units have been in operation for more than two years. With the actual operation, a series of problems which were not taken into account at the beginning of the design have arisen. Due to low ozone utilization rate and continuous deterioration, the treatment costs continuously increased. In order to solve these problems, combined with practical conditions, four aspects of the flocs, colloidal macromolecule organic compounds, ozone mass transfer and catalysts were analyzed. In the meantime, the development trend of ozone catalytic oxidation technology in secondary effluent treatment of petrochemical industry was put forward.

     

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  • [1]
    BING J S, HU C, NIE Y L , et al. Mechanism of catalytic ozonation in Fe2O3/Al2O3@SBA-15 aqueous suspension for destruction of ibuprofen[J]. Environmental Science & Technology, 2015,49(3):1690-1697.
    [2]
    ZUCKER I, LESTER Y, AVISAR D , et al. Influence of wastewater particles on ozone degradation of trace organic contaminants[J]. Environmental Science & Technology, 2015,49(1):301-308.
    doi: 10.1021/es504314t pmid: 25471841
    [3]
    国家环境保护局. 石油化学工业污染物排放标准:GB 31571—2015[S].北京: 中国环境科学出版社, 2015.
    [4]
    WU C Y, LI Y N, ZHOU Y X , et al. Upgrading the Chinese biggest petrochemical wastewater treatment plant:technologies research and full scale application[J]. Science of the Total Environment, 2018,633:189-197.
    doi: 10.1016/j.scitotenv.2018.03.164 pmid: 29573685
    [5]
    张斯宇, 吴昌永, 周岳溪 , 等. 生物絮体对臭氧催化氧化深度处理石化二级出水的影响[ C]//中国环境科学学会学术年会论文集, 2017: 2869-2877.
    [6]
    WU C Y, WANG Y N, ZHOUY X , et al. Pretreatment of petrochemical secondary effluent by micro-flocculation and dynasand filtration:performance and DOM removal characteristics[J]. Water Air & Soil Pollution, 2016,227(11):415.
    doi: 10.1007/s11270-016-3118-2
    [7]
    王雅宁 . 臭氧催化氧化处理石化二级出水研究[D]. 大连:大连海洋大学, 2017.
    [8]
    ZHANG S Y, WU C Y, ZHOU Y X , et al. Effect of wastewater particles on catalytic ozonation in the advanced treatment of petrochemical secondary effluent[J]. Chemical Engineering Journal, 2018,345:280-289.
    doi: 10.1016/j.cej.2018.03.184
    [9]
    周琪, 林涛, 谢丽 . 污水处理生物絮体絮凝沉淀机理分析的综述[J]. 同济大学学报(自然科学版), 2009,37(1):78-83.

    ZHOU Q, LIN T, XIE L . Review of mechanism of bioflocculation and settleability of activated sludge bioflocs[J]. Journal of Tongji University(Natural Science), 2009,37(1):78-83.
    [10]
    STUMM W, MORGAN J J, BLACKA P . Chemical aspects of coagulation[J]. American Water Works Association, 1962,54(8):971-994.
    doi: 10.1002/j.1551-8833.1962.tb00922.x
    [11]
    STUMM W, O'MELIAC R .Stoichiometry of coagulation[J]. American Water Works Association, 1968,60(5):514-539.
    doi: 10.1002/j.1551-8833.1968.tb03579.x
    [12]
    RICKERTKERT D A, HUNTER J V . Colloidal matter in wastewaters and secondary effluents[J]. Journal Water Pollution Control Federation, 1972,44(1):134-139.
    doi: 10.1080/01944367208977642 pmid: 5009202
    [13]
    WERT E C, GONZALES S, DONG M M , et al. Evaluation of enhanced coagulation pretreatment to improve ozone oxidation efficiency in wastewater[J]. Water Research, 2011,45(16):5191-5199.
    doi: 10.1016/j.watres.2011.07.021 pmid: 21855954
    [14]
    SINGER P C, ARLOTTA C, SNIDER-SALDAK N , et al. Effectiveness of pre-and intermediate ozonation on the enhanced coagulation of disinfection by-product precursors in drinking water[J]. Ozone:Science & Engineering, 2003,25(6):453-471.
    doi: 10.1080/01919510390481775
    [15]
    JIN X, JIN P, HOU R , et al. Enhanced WWTP effluent organic matter removal in hybrid ozonation-coagulation(HOC)process catalyzed by Al-based coagulant[J]. Journal of Hazardous Materials, 2017,327:216-224.
    doi: 10.1016/j.jhazmat.2016.12.043
    [16]
    秦月娇, 焦纬洲, 杨鹏飞 , 等. 强化臭氧传质的研究进展[J]. 过程工程学报, 2017,17(2):420-426.
    doi: 10.12034/j.issn.1009-606X.216292

    QIN Y J, JIAO W Z, YANG P F , et al. Research progress of enhancement of ozone mass transfer[J]. Chinese Journal of Process Engineering, 2017,17(2):420-426. doi: 10.12034/j.issn.1009-606X.216292
    [17]
    李晓伟, 林诚, 蒋友华 , 等. 微孔分布器对光催化臭氧氧化反应器传质的影响[J]. 环境工程学报, 2011,5(5):1101-1105.

    LI X W, LIN C, JIANG Y H , et al. Effect of titanium porous plates on mass transfer performance of photocatalytic ozonation reactors[J]. Chinese Journal of Environmental Engineering, 2011,5(5):1101-1105.
    [18]
    储金宇, 吴春笃, 陈万金 , 等. 臭氧技术及应用[M]. 北京: 化学工业出版社, 2002.
    [19]
    REN J, HE S, YE C , et al. The ozone mass transfer characteristics and ozonation of pentachlorophenol in a novel microchannel reactor[J]. Chemical Engineering Journal, 2012,210(6):374-384.
    doi: 10.1016/j.cej.2012.09.011
    [20]
    张勇, 王军, 侯得印 , 等. 膜接触反应器臭氧传质及其对模拟印染废水的降解[J]. 环境工程学报, 2017,11(8):4453-4458.
    doi: 10.12030/j.cjee.201607215

    ZHANG Y, WANG J, HOU D Y , et al. Using a membrane contactor for ozone mass transfer study and model dye wastewater treatment[J]. Chinese Journal of Environmental Engineering, 2017,11(8):4453-4458. doi: 10.12030/j.cjee.201607215
    [21]
    ZHOU H, SMITH D W . Ozone mass transfer in water and wastewater treatment:experimental observations using a 2D laser particle dynamics analyzer[J]. Water Research, 2000,34(3):909-921.
    doi: 10.1016/S0043-1354(99)00196-7
    [22]
    BAIG S, LIECHTI P . Ozone treatment for biorefractory COD removal[J]. Water Science and Technology, 2001,43(2):197-204.
    doi: 10.1029/2000WR900288 pmid: 11380180
    [23]
    NAWROCKI J, KASPREZYK-HORDERN B . The efficiency and mechanisms of catalytic ozonation[J]. Applied Catalysis B Environmental, 2010,99(1):27-42.
    doi: 10.1016/j.apcatb.2010.06.033
    [24]
    ZHUANG H F, HAN H J, HOU B L , et al. Heterogeneous catalytic ozonation of biologically pretreated Lurgi coal gasification wastewater using sewage sludge based activated carbon supported manganese and ferric oxides as catalysts[J]. Bioresource Technology, 2014,166:178-186.
    doi: 10.1016/j.biortech.2014.05.056 pmid: 24907577
    [25]
    YANGY X, MA J, QIN Q D , et al. Degradation of nitrobenzene by nano-TiO2,catalyzed ozonation[J]. Journal of Molecular Catalysis A:Chemical, 2007,267(1):41-48.
    doi: 10.1016/j.molcata.2006.09.010
    [26]
    VITTENET J, ABOUSSAOUD W, MENDRET J , et al. Catalytic ozonation with γ-Al2O3 to enhance the degradation of refractory organics in water[J]. Applied Catalysis A:General, 2014: S0926860X14006607.
    doi: 10.1016/j.apcata.2014.10.037
    [27]
    KASPRZYKHORDERN B, ZIOLEK M, NAWROCKI J . Catalytic ozonation and methods of enhancing molecular ozone reactions in water treatment[J]. Applied Catalysis B:Environmental, 2003,46(4):639-669.
    doi: 10.1016/S0926-3373(03)00326-6
    [28]
    PINES D S, RECKHOW D A . Effect of dissolved cobalt(Ⅱ) on the ozonation of oxalic acid[J]. Environmental Science & Technology, 2002,36(19):4046.
    doi: 10.1021/es011230w pmid: 12380073
    [29]
    BELTRAN, FEMANDO J, RIVAS F J , et al. Ozone-enhanced oxidation of oxalic acid in water with cobalt catalysts:1.homogeneous catalytic ozonation[J]. Industrial & Engineering Chemistry Research, 2003,42(14):3210-3217.
    doi: 10.1021/ie0209982
    [30]
    PI Y C, EMST M, SCHROTTER J C . Effect of phosphate buffer upon CuO/Al2O3 and Cu(Ⅱ)catalyzed ozonation of oxalic acid solution[J]. Ozone Science & Engineering, 2003,25(5):393-397.
    doi: 10.1080/01919510390481711
    [31]
    MA J, GRAHAM N J D .Degradation of atrazine by manganese-catalysed ozonation:influence of humic substances[J]. Water Research, 1999,33(3):785-793.
    doi: 10.1016/S0043-1354(98)00266-8
    [32]
    SANCHEZ-POLO M, RIVERA-UTRILLA J . Ozonation of 1,3,6-naphthalenetrisulfonic acid in presence of heavy metals[J]. Journal of Chemical Technology & Biotechnology, 2004,79(8):902-909.
    doi: 10.1002/jctb.1077
    [33]
    MA J, GRAHAM N J D .Preliminary investigation of manganese-catalyzed ozonation for the destruction of atrazine[J]. Ozone Science & Engineering, 1997,19(3):227-240.
    doi: 10.1080/01919519708547303
    [34]
    ANDREOZZI R, CASALE M S L,MAROTTA R ,et al.N-methyl-p-aminophenol (metol)ozonation in aqueous solution:kinetics,mechanism and toxicological characterization of ozonized samples[J]. Water Research, 2000,34(18):4419-4429.
    doi: 10.1016/S0043-1354(00)00220-7
    [35]
    ANDREZZI R, INSOLA A, CAPRIO V , et al. The use of manganese dioxide as a heterogeneous catalyst for oxalic acid ozonation in aqueous solution[J]. Applied Catalysis A:General, 1996,138(1):75-81.
    doi: 10.1016/0926-860X(95)00247-2
    [36]
    BELTRAN F J, RIVAS F J, MONTERO-DE-ESPINOSA R .Iron type catalysts for the ozonation of oxalic acid in water[J]. Water Research, 2005,39(15):3553-3564.
    doi: 10.1016/j.watres.2005.06.018 pmid: 16095660
    [37]
    MA J, SUI M H, CHEN Z L , et al. Degradation of refractory organic pollutants by catalytic ozonation-activated carbon and Mn-loaded activated carbon as catalysts[J]. Ozone Science & Engineering, 2004,26(1):3-10.
    doi: 10.1080/01919510490426027
    [38]
    DONGY M, YANG H X, HE K , et al. β-MnO2 nanowires:a novel ozonation catalyst for water treatment[J]. Applied Catalysis B:Environmental, 2009,85(3):155-161.
    doi: 10.1016/j.apcatb.2008.07.007
    [39]
    FARIA P C C, MONTEIRO D C M, ÁRFAO J J M , et al. Cerium,manganese and cobalt oxides as catalysts for the ozonation of selected organic compounds[J]. Chemosphere, 2009,74(6):818-824.
    doi: 10.1016/j.chemosphere.2008.10.016 pmid: 19027138
    [40]
    YANG L, HU C, NIE Y L , et al. Catalytic ozonation of selected pharmaceuticals over mesoporous alumina-supported manganese oxide[J]. Environmental Science & Technology, 2009,43(7):2525-2529.
    doi: 10.1021/es803253c pmid: 19452911
    [41]
    COOPER C, BURCH R . Mesoporous materials for water treatment processes[J]. Water Research, 1999,33(18):3689-3694.
    doi: 10.1016/S0043-1354(99)00095-0
    [42]
    KASPRZK-HORDERN B, RACZYK-STANISLAWIAK U, SWICTLIK J , et al.Catalytic ozonation of natural organic matter on alumina [J]. Applied Catalysis B:Environmental, 2006,62(3):345-358.
    doi: 10.1016/j.apcatb.2005.09.002
    [43]
    EMST M, LUROT F, SCHROTTER J C . Catalytic ozonation of refractory organic model compounds in aqueous solution by aluminum oxide[J]. Applied Catalysis B:Environmental, 2004,47(1):15-25.
    doi: 10.1016/S0926-3373(03)00290-X
    [44]
    YUN R Z, WAN P Z, FU D L , et al. Catalytic activity of Ru/Al2O3 for ozonation of dimethyl phthalate in aqueous solution[J]. Chemosphere, 2007,66(1):145-150.
    doi: 10.1016/j.chemosphere.2006.04.087 pmid: 16793113
    [45]
    NI C H, CHEN J N . Heterogeneous catalytic ozonation of 2-chlorophenol aqueous solution with alumina as a catalyst[J]. Water Science & Technology A Journal of the International Association on Water Pollution Research, 2001,43(2):213.
    doi: 10.1029/2000WR900288 pmid: 11380182
    [46]
    TRAPIDO M, VERESSININA Y, MUNTER R , et al. Catalytic ozonation of m-dinitrobenzene[J]. Ozone Science & Engineering, 2005,27(5):359-363.
    [47]
    CHEN Z L, QI F, XU B B , et al. Mechanism discussion of γ-alumina catalyzed ozonation for 2-methylisoborneol removal[J]. Environmental Science, 2007,28(3):563-568.
    [48]
    BELTRAN F J, RIVAS F J, MONTERO-DE-ESPINOSA R .Catalytic ozonation of oxalic acid in an aqueous TiO2 slurry reactor[J]. Applied Catalysis B Environmental, 2002,39(3):221-231.
    doi: 10.1016/S0926-3373(02)00102-9
    [49]
    ROSALR,RODRIGUEZ A, GONZALO M S , et al. Catalytic ozonation of naproxen and carbamazepine on titanium dioxide[J]. Applied Catalysis B:Environmental, 2008,84(1):48-57.
    doi: 10.1016/j.apcatb.2008.03.003
    [50]
    ROSAL R, GONZALO M S, RODRIGUEZ A , et al. Ozonation of clofibric acid catalyzed by titanium dioxide[J]. Journal of Hazardous Materials, 2009,169(1):411-418.
    doi: 10.1016/j.jhazmat.2009.03.111 pmid: 19395159
    [51]
    ROSAL R, GONZALO M S, BOLTES K , et al. Identification of intermediates and assessment of ecotoxicity in the oxidation products generated during the ozonation of clofibric acid[J]. Journal of Hazardous Materials, 2009,172(2/3):1061-1068.
    doi: 10.1016/j.jhazmat.2009.07.110 pmid: 19709806
    [52]
    GRACIA R, CORTES S, SARASA J , et al. Heterogeneous catalytic ozonation with supported titanium dioxide in model and natural waters[J]. Ozone Science & Engineering, 2000,22(5):461-471.
    doi: 10.1080/01919510009408790
    [53]
    GRACIA R, CORTES S, SARASA J , et al. Catalytic ozonation with supported titanium dioxide:the stability of catalyst in water[J]. Ozone Science & Engineering, 2000,22(2):185-193.
    doi: 10.1080/01919510008547219
    [54]
    GRACIA R, CORTES S, SARASA J , et al. TiO2-catalysed ozonation of raw Ebro river water[J]. Water Research, 2000,34(5):1525-1532.
    doi: 10.1016/S0043-1354(99)00297-3
    [55]
    VOLK C, ROCHE P, JORET J C , et al. Comparison of the effect of ozone,ozone-hydrogen peroxide system and catalytic ozone on the biodegradable organic matter of a fulvic acid solution[J]. Water Research, 1997,31(3):650-656.
    doi: 10.1016/S0043-1354(96)00302-8
    [56]
    BELTRAN F J, RIVAS F J , MONTERO-DE-ESPINOSA R.A TiO/AlO catalyst to improve the ozonation of oxalic acid in water[J]. Applied Catalysis B:Environmental, 2004,47(2):101-109.
    doi: 10.1016/j.apcatb.2003.07.007
    [57]
    ZHANG T, LU J F, MA J , et al. Fluorescence spectroscopic characterization of DOM fractions isolated from a filtered river water after ozonation and catalytic ozonation[J]. Chemosphere, 2008,71(5):911-921.
    doi: 10.1016/j.chemosphere.2007.11.030 pmid: 18190948
    [58]
    PARKJ S, CHOI H, AHN K H . The reaction mechanism of catalytic oxidation with hydrogen peroxide and ozone in aqueous solution[J]. Water Science & Technology A Journal of the International Association on Water Pollution Research, 2003,47(1):179.
    doi: 10.1016/S0043-1354(02)00272-5 pmid: 12578192
    [59]
    PARKJ S, CHOI H, AHN K H , et al. Removal mechanism of natural organic matter and organic acid by ozone in the presence of goethite[J]. Ozone Science & Engineering, 2004,26(2):141-151.
    doi: 10.1080/01919510490439285
    [60]
    PARKJ S, CHOI H, CHO J . Kinetic decomposition of ozone and para-chlorobenzoic acid(CBA)during catalytic ozonation[J]. Water Research, 2004,38(9):2285-2292.
    doi: 10.1016/S0043-1354(04)00018-1 pmid: 15142789
    [61]
    ZHANG T, LU J F, MA J , et al. Comparative study of ozonation and synthetic goethite-catalyzed ozonation of individual NOM fractions isolated and fractionated from a filtered river water[J]. Water Research, 2008,42(6):1563-1570.
    doi: 10.1016/j.watres.2007.11.005 pmid: 18048076
    [62]
    JIE Z, LEE K H, CUI L , et al. Degradation of methylene blue in aqueous solution by ozone-based processes[J]. Journal of Industrial & Engineering Chemistry, 2009,15(2):185-189.
    doi: 10.1016/j.jiec.2008.09.014
    [63]
    MURUGANANGHAM M, WU J J . Synjournal,characterization and catalytic activity of easily recyclable zinc oxide nanobundles[J]. Applied Catalysis B:Environmental, 2008,80(1):32-41.
    doi: 10.1016/j.apcatb.2007.11.006
    [64]
    QU J H, LI H Y, LIU H J , et al. Ozonation of alachlor catalyzed by Cu/AlO in water[J]. Catalysis Today, 2004,89(3):291-296.
    doi: 10.1016/j.cattod.2004.04.032
    [65]
    PI Y, EMST M, SCHROTTER J C . Effect of phosphate buffer upon CuO/Al2O3 and Cu(Ⅱ) catalyzed ozonation of oxalic acidsolution[J]. Ozone Science & Engineering, 2003,25(5):393-397.
    doi: 10.1080/01919510390481711
    [66]
    UDREA I, BRADU C . Ozonation of substituted phenols in aqueous solutions over CuO-Al2O3 catalyst[J]. Ozone Science & Engineering, 2003,25(4):335-343.
    doi: 10.1080/01919510390481658
    [67]
    ÁLVAREZ P M, BELTRAN F J, POCOSTALES J P , et al. Preparation and structural characterization of Co/Al2O3 catalysts for the ozonation of pyruvic acid[J]. Applied Catalysis B:Environmental, 2007,72(3):322-330.
    doi: 10.1016/j.apcatb.2006.11.009
    [68]
    AVRAMESCU S M, BRADU C, UDREA I , et al. Degradation of oxalic acid from aqueous solutions by ozonation in presence of Ni/Al2O3 catalysts[J]. Catalysis Communications, 2008,9(14):2386-2391.
    doi: 10.1016/j.catcom.2008.06.001
    [69]
    FARIA P C C, ÓRFAO J J M, PEREIRA M F R . Activated carbon and ceria catalysts applied to the catalytic ozonation of dyes and textile effluents[J]. Applied Catalysis B:Environmental, 2009,88(3):341-350.
    doi: 10.1016/j.apcatb.2008.11.002
    [70]
    MOUSSAVI G, MAHMONDI M . Degradation and biodegradability improvement of the reactive red 198 azo dye using catalytic ozonation with MgO nanocrystals[J]. Chemical Engineering Journal, 2009,152(1):1-7.
    doi: 10.1016/j.cej.2009.03.014
    [71]
    QI F, XU B B, CHEN Z L , et al. Catalytic ozonation for degradation of 2,4,6-trichloroanisole in drinking water in the presence of gamma-AlOOH[J]. Water Environment Research:A Research Publication of the Water Environment Federation, 2009,81(6):592.
    doi: 10.2175/106143008X370412 pmid: 19601425
    [72]
    XU Z Z, CHEN Z L, JOLL C , et al. Catalytic efficiency and stability of cobalt hydroxide for decomposition of ozone and chloronitrobenzene in water[J]. Catalysis Communications, 2009,10(8):1221-1225.
    doi: 10.1016/j.catcom.2009.01.021
    [73]
    QIN W, LI X, QI J Y . Experimental and theoretical investigation of the catalytic ozonation on the surface of nio-cuo nanoparticles[J]. Langmuir: the ACS Journal of Surfaces & Colloids, 2009,25(14):8001-8011.
    doi: 10.1021/la900476m pmid: 19466811
    [74]
    HU C, XING S T, QU J H , et al. Catalytic ozonation of herbicide 2,4-D over cobalt oxide supported on mesoporous zirconia[J]. Journal of Physical Chemistry C, 2008,112(15):5978-5983.
    doi: 10.1021/jp711463e
    [75]
    SUI M H, SHENG L, LU K , et al. FeOOH catalytic ozonation of oxalic acid and the effect of phosphate binding on its catalytic activity[J]. Applied Catalysis B:Environmental, 2010,96(1):94-100.
    doi: 10.1016/j.apcatb.2010.02.005
    [76]
    RUI C M, QUINTA-FERRIRA R M .Catalytic ozonation of phenolic acids over a Mn-Ce-O catalyst[J]. Applied Catalysis B:Environmental, 2009,90(1):268-277.
    doi: 10.1016/j.apcatb.2009.03.023
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