Volume 10 Issue 5
Sep.  2020
Turn off MathJax
Article Contents
Article Navigation >  Journal of Environmental Engineering Technology  > 2020  >  10(5): 823-830
CHENG Xiang, ZHAO Jifeng, XIAO Yang, LI Siyuan, SUN Youmin, YANG Xue, ZHANG Guiqin. Composition characteristics of atmospheric VOCs and the influence on ozone formation in an industrial cluster area[J]. Journal of Environmental Engineering Technology, 2020, 10(5): 823-830. doi: 10.12153/j.issn.1674-991X.20190209
Citation: CHENG Xiang, ZHAO Jifeng, XIAO Yang, LI Siyuan, SUN Youmin, YANG Xue, ZHANG Guiqin. Composition characteristics of atmospheric VOCs and the influence on ozone formation in an industrial cluster area[J]. Journal of Environmental Engineering Technology, 2020, 10(5): 823-830. doi: 10.12153/j.issn.1674-991X.20190209
shu

Composition characteristics of atmospheric VOCs and the influence on ozone formation in an industrial cluster area

doi: 10.12153/j.issn.1674-991X.20190209
  • 1.

    Zibo Ecological Environmental Monitoring Station, Shandong Province

  • 2.

    School of Municipal and Environmental Engineering, Shandong Jianzhu University

More Information
  • Corresponding author: ZHANG Guiqin E-mail: zhangguiqin320@163.com
  • Received Date: 2019-12-11
  • Publish Date: 2020-09-20
    Abstract
  • The concentrations of 59 VOCs species in the atmosphere of industrial cluster area in Zibo City was detected using VOCs online rapid continuous automatic monitoring system. The results indicated that the average VOCs concentration was (130.74±63.42)×10-9(volume fraction, the same all the article) during the observation period. The order of volume fraction of each VOCs species was alkanes (41.17%±17.67%),alkenes (34.22%±23.79%),sulphur-containing VOCs (12.20%±20.83%),aromatics (6.70%±10.39%),alkyne (5.75%±6.49%). Alkenes VOCs, especially ethylene, cis-2-butene and propylene, had the highest activity, and had the highest photochemical reactivity. Two typical periods with different VOCs and O3 concentrations were selected to estimate the frontier orbital energy difference between the detected sulphur-containing VOCs and ·OH by quantum chemical molecular simulation. Sulfur-containing VOCs(methyl mercaptan, methyl sulfide, dimethyl disulfide) were more likely to cause chain reactions with ·OH. The effects of VOCs components on ozone formation were analyzed in the two periods, which showed that when the concentrations of alkenes and aromatics were not high, ozone was still at a high level due to the increase of sulphur-containing VOCs concentration, and sulphur-containing VOCs became the main contributors of ozone in the atmosphere. According to the sensitivity of VOCs/NOx, it was found that ozone formation in Zibo City was sensitive to VOCs during the observation period, and Zibo City belonged to VOCs control area.

     

    • FullText(HTML)
  • loading
    • References(33)
  • [1]
    XUE L K, WANG T, GAO J, et al. Ground-level ozone in four Chinese cities:precursors,regional transport and heterogeneous processes[J]. Atmospheric Chemistry and Physics, 2014,14(23):13175-13188.
    [2]
    唐永銮. 大气环境化学[M]. 广州: 中山大学出版社, 1992.
    [3]
    李如梅, 武媛媛, 彭林, 等. 朔州市夏季环境空气中VOCs的污染特征及来源解析[J]. 环境化学, 2017,36(5):984-993.

    LI R M, WU Y Y, PENG L, et al. Characteristics and sources apportionment of ambient volatile organic compounds (VOCs) in summer in Shuozhou[J]. Environmental Chemistry, 2017,36(5):984-993.
    [4]
    李雷, 李红, 王学中, 等. 广州市中心城区环境空气中挥发性有机物的污染特征与健康风险评价[J]. 环境科学, 2013,34(12):4558-4564.

    LI L, LI H, WANG X Z, et al. Pollution characteristics and health risk assessment of atmospheric VOCs in the Downtown Area of Guangzhou,China[J]. Environmental Science, 2013,34(12):4558-4564.
    [5]
    杨笑笑, 汤莉莉, 张运江, 等. 南京夏季市区VOCs特征及O3生成潜势的相关性分析[J]. 环境科学. 2016,37(2):43-51.

    YANG X X, TANG L L, ZHANG Y J, et al. Correlation analysis between characteristics of VOCs and ozone formation potential in summer in Nanjing Urban District[J]. Environmental Science, 2016,37(2):443-451.
    [6]
    马永亮, 谭吉华, 贺克斌, 等. 佛山灰霾期挥发性有机物的污染特征[J]. 环境科学, 2011,32(12):3549-3554.

    MA Y L, TAN J H, HE K B, et al. Characteristics of volatile organic compounds during haze episode in Foshan City[J]. Environmental Science, 2011,32(12):3549-3554.
    [7]
    XUE L, GU R R, WANG T, et al. Oxidative capacity and radical chemistry in the polluted atmosphere of Hong Kong and Pearl River Delta region:analysis of a severe photochemical smog episode[J]. Atmospheric Chemistry & Physics, 2016,16(15):9891-9903.
    [8]
    CAI C J, GENG F H, TIE X X, et al. Characteristics of ambient volatile organic compounds(VOCs) measured in Shanghai,China[J]. Sensors, 2010,10(8):7843-7862.
    doi: 10.3390/s100807843 pmid: 22163629
    [9]
    王红丽. 上海市大气挥发性有机物化学消耗与臭氧生成的关系[J]. 环境科学, 2015,36(9):3159-3167.

    WANG H L. Chemical loss of volatile organic compounds and its impact on the formation of ozone in Shanghai[J]. Environmental Science, 2015,36(9):3159-3167.
    [10]
    高爽, 张坤, 高松, 等. 上海城郊地区冬季霾污染事件反应性VOCs物种特征[J]. 环境科学, 2017,38(3):855-866.

    GAO S, ZHANG K, GAO S, et al. Characteristics of reactive VOCs Species during high haze-pollution events in suburban area of Shanghai in winter[J]. Environmental Science, 2017,38(3):855-866.
    [11]
    WEI W, CHENG S Y, LI G H, et al. Characteristics of volatile organic compounds(VOCs) emitted from a petroleum refinery in Beijing,China[J]. Atmospheric Environment, 2014,89(2):358-366.
    [12]
    LI L, LI H, ZHANG X M, et al. Pollution characteristics and health risk assessment of benzene homologues in ambient air in the northeastern urban area of Beijing,China[J]. Journal of Environmental Sciences, 2014,26(1):214-223.
    [13]
    ZHANG Y, MU Y, LIU J, et al. Levels,sources and health risks of carbonyls and BTEX in the ambient air of Beijing,China[J]. Journal of Environmental Sciences, 2012,24(1):124-130.
    [14]
    吴方堃, 王跃思, 安俊琳, 等. 北京奥运时段VOCs浓度变化、臭氧产生潜势及来源分析研究[J]. 环境科学, 2010,31(1):10-16.

    WU F K, WANG Y S, AN J L, et al. Study on concentration, ozone production potential and sources of VOCs in the atmosphere of Beijing during Olympics period[J]. Environmental Science, 2010,31(1):10-16.
    [15]
    卢学强, 韩萌, 冉靓, 等. 天津中心城区夏季非甲烷有机化合物组成特征及其臭氧产生潜力分析[J]. 环境科学学报, 2011,31(2):373-380.

    LU X Q, HAN M, RAN L, et al. Characteristics of nonmethane organic compounds and their ozone formation potentials in downtown Tiajin in summer[J]. Acta Scientiae Circumstantiae, 2011,31(2):373-380.
    [16]
    武蕾丹, 王秀艳, 杨文. 某工业园区VOCs臭氧生成潜势及优控物种[J]. 环境科学, 2018,39(2):511-516.

    WU L D, WANG X Y, YANG W. ozone formation potential and priority species of VOCs in an industrial park[J]. Environmental science, 2018,39(2):511-516.
    [17]
    刘泽常, 李娜, 侯鲁健, 等. 济南市环境空气VOCs污染特征及来源识别[J]. 中国环境监测. 2014,30(6):83-88.

    LIU Z C, LI N, HOU L J, et al. Pollution characteristics and source identification of VOCs in ambient air of Ji’nan[J]. China Environmental Monitoring, 2014,30(6):83-88.
    [18]
    王占山, 李云婷, 陈添, 等. 北京城区臭氧日变化特征及与前体物的相关性分析[J]. 中国环境科学, 2014,34(12):3001-3008.

    WANG Z S, LI Y T, CHEN T, et al. Analysis on diurnal variation characteristics of ozone and correlations with its precursors in urban atmosphere of Beijing[J]. China Environmental Science, 2014,34(12):3001-3008.
    [19]
    SILLMAN S. The relation between ozone,NOx and hydrocarbons in urban and polluted rural environments[J]. Atmospheric Environment, 1999,12(33):1821-1845.
    [20]
    CAI C J, GENG F H, TIE X X, et al. Characteristics of ambient volatile organic compounds (VOCs) measured in Shanghai,China[J]. Sensors, 2010,10(8):7843-7862.
    pmid: 22163629
    [21]
    ROGER A, JANET A. Atmospheric degradation of volatile organic compounds[J]. Chemical Reviews, 2003,103(12):4605-4638.
    doi: 10.1021/cr0206420 pmid: 14664626
    [22]
    李友平, 唐娅, 范忠雨, 等. 成都市大气环境VOCs污染特征及其健康风险评价[J]. 环境科学, 2018,39(2):576-584.

    LI Y P, TANG Y, FAN Z Y, et al. Pollution characteristics and health risk assessment of atmospheric VOCs in Chengdu[J]. Environmental Science, 2018,39(2):576-584.
    [23]
    裴冰, 刘娟, 刘焱婧. 某化学工业区挥发性有机物组成特征及大气化学反应活性[J]. 环境监测管理与技术, 2011(增刊):1-6.

    PEI B, LIU J, LIU Y J. The Composition and chemical Reactivity of volatile organic Compounds (VOCs) in a certain chemical industry Park[J]. Environmental Monitoring Management and Technology, 2011(Suppl 1):1-6.
    [24]
    PING S, AN J, XIN J, et al. Source apportionment of VOCs and the contribution to photochemical ozone formation during summer in the typical industrial area in the Yangtze River Delta,China[J]. Atmospheric Research, 2016, 176/177:64-74.
    [25]
    LEUCHNER M, RAPPENGLÜCK B. VOC source-receptor relationships in Houston during TexAQS-II[J]. Atmos pheric Environment, 2010,44(33):4056-4067.
    [26]
    YURDAKUL S, CIVAN M, TUNCEL G. Volatile organic compounds in suburban Ankara atmosphere,Turkey:sources and variability[J]. Atmospheric Research, 2013, 120/121:298-311.
    [27]
    胡天鹏, 李刚, 毛瑶, 等. 某石油化工园区秋季VOCs污染特征及来源解析[J]. 环境科学, 2018,39(2):517-524.

    HU T P, LI G, MAO Y, et al. Characteristics and source apportionment of VOCs of a petrochemical industrial park during autumn in China[J]. Environmental Science, 2018,39(2):517-524.
    [28]
    张桂芹, 李思远, 潘光, 等. 化工企业优控VOCs污染物分析及生成机理[J]. 中国环境科学, 2019,39(4):1380-1389.

    ZHANG G Q, LI S Y, PAN G, et al. Determination and formation mechanism of precedence-controlled VOCs pollutants in chemical plant[J]. China Environmental Science, 2019,39(4):1380-1389.
    [29]
    林梦海. 量子化学计算方法与应用[M]. 北京: 科学出版社, 2004.
    [30]
    FUKUI K. Theory of orientation and stereoselection[M]. Berlin:Springer, 1970: 1-85.
    [31]
    吴润润. 典型芳香类化合物大气氧化机理的理论研究[D]. 广州:华南理工大学, 2016.
    [32]
    王占山, 李云婷, 安欣欣, 等. 2006—2015年北京市不同地区O3浓度变化[J]. 环境科学, 2018,39(1):1-8.

    WANG Z S, LI Y T, AN X X, et al. Variation of O3 concentration in different areas of Beijing from 2006 to 2015[J]. Environmental Science, 2018,39(1):1-8.
    [33]
    李磊, 赵玉梅, 王旭光, 等. 廊坊市夏季臭氧体积分数影响因素及生成敏感性[J]. 环境科学, 2017,38(10):4100-4107.

    LI L, ZHAO Y M, WANG X G, et al. Influence factors and sensitivity of ozone formation in Langfang in the summer[J]. Environmental Science, 2017,38(10):4100-4107.
    • Relative Articles
    • Supplements(0)
    • Cited By
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索
    Get Citation
    PDF
    XML

    Article Metrics

    Article Views(549) PDF Downloads(160) Cited by()
    Proportional views
    Related

    Copyright © Editorial Department of Journal of Environmental Engineering Technology

    京ICP备05031605号-2

    Supported by: Beijing Renhe Information Technology Co., Ltd.  

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return