Volume 10 Issue 4
Jul.  2020
Turn off MathJax
Article Contents
Article Navigation >  Journal of Environmental Engineering Technology  > 2020  >  10(4): 661-670
CAO Jing, WANG Pengfei, CHEN Junyi, WANG Shuhang, YANG Guoli. Study on the effect of modified biochar materials on in situ remediation of contaminated sediments[J]. Journal of Environmental Engineering Technology, 2020, 10(4): 661-670. doi: 10.12153/j.issn.1674-991X.20200021
Citation: CAO Jing, WANG Pengfei, CHEN Junyi, WANG Shuhang, YANG Guoli. Study on the effect of modified biochar materials on in situ remediation of contaminated sediments[J]. Journal of Environmental Engineering Technology, 2020, 10(4): 661-670. doi: 10.12153/j.issn.1674-991X.20200021
shu

Study on the effect of modified biochar materials on in situ remediation of contaminated sediments

doi: 10.12153/j.issn.1674-991X.20200021
  • 1.

    School of Municipal and Environmental Engineering, Hebei University of Architectural Engineering

  • 2.

    Institute of Lake Environment, Chinese Research Academy of Environmental Sciences

  • 3.

    National Engineering Laboratory for Lake Pollution Control and Ecological Restoration

More Information
  • Corresponding author: WANG Pengfei E-mail: wangpf01@craes.org.cn
  • Received Date: 2020-02-17
  • Publish Date: 2020-07-20
    Abstract
  • To study the control effect of biochar material on the release of nitrogen, phosphorus and heavy metal pollutants, two kinds of polluted sediment samples were collected from the river network and lake in Jiaxing City. Four kinds of modified biochars were produced using reed as the biomass feedstock and FeCl3, AlCl3, MgCl2 and KMnO4 as modifiers, while unmodified biochar, activated carbon and Phoslock were used as reference materials. The control effects of the seven kinds of remediation materials on the release of ammonia nitrogen (NH3-N), nitrate nitrogen ( NO 　 3 - -N) and total soluble nitrogen (DTN), orthophosphate ( P O 4 3 - -P), total soluble phosphorus (DTP) and heavy metal ions into the water from the two kinds of polluted sediments were analyzed. The results showed that after adding AlCl3 modified biochar to the sediments, the concentrations of NH3-N, DTN, P O 4 3 - -P, DTP, Ni, As released into the water from the two sediments could be reduced by 17.42%, 18.61%, 91.23%, 77.04%, 72.13%, 46.21%, respectively, at the most. After adding FeCl3 modified biochar, the concentrations of P O 4 3 - -P, DTP and As released into the water from the two sediments could be decreased by 91.23%, 92.59% and 95.80%, respectively, but the concentrations of DTN and Ni in the water increased. After adding MgCl2 and KMnO4 modified biochar, the concentrations of nitrogen, phosphorus, Ni and As pollutants released into the water from the two sediments increased rather than decreased. In conclusion, AlCl3 modified biochar could effectively fix phosphorus, Ni and As in sediments and thus be considered as a material for in situ remediation of contaminated sediment.

     

    • FullText(HTML)
  • loading
    • References(45)
  • [1]
    SØNDERGAARD M, JENSEN J P, JEPPESEN E. Internal phosphorus loading in shallow Danish lakes[J]. Hydrobiologia, 1999,15(6):145-152.
    [2]
    QIN B Q, YANG L Y, CHEN F Z. Mechanism and control of lake eutrophication[J]. Chinese Science Bulletin, 2006,51(19):2401-2412.
    doi: 10.1007/s11434-006-2096-y
    [3]
    唐艳, 胡小贞, 卢少勇. 污染底泥原位覆盖技术综述[J]. 生态学杂志, 2007,26(7):1125-1128.

    TANG Y, HU X Z, LU S Y. In situ capping technology for remediation of contaminated sediment[J]. Chinese Journal of Ecology, 2007,26(7):1125-1128.
    [4]
    胡小贞, 金相灿, 卢少勇, 等. 湖泊底泥污染控制技术及其适用性探讨[J]. 中国工程科学, 2009,11(9):28-33.

    HU X Z, JIN X C, LU S Y, et al. Techniques for sediment pollution control and discussion on the applicability in lakes of China[J]. Strategic Study of CAE, 2009,11(9):28-33.
    [5]
    宁寻安, 陈文松, 李萍, 等. 污染底泥修复治理技术研究进展[J]. 环境科学与技术, 2006,29(9):100-102.

    NING X A, CHEN W S, LI P, et al. Review on remediation technique for polluted sediment[J]. Environmental Science & Technology, 2006,29(9):100-102.
    [6]
    YU J, DING S, ZHONG J, et al. Evaluation of simulated dredging to control internal phosphorus release from sediments:focused on phosphorus transfer and resupply across the sediment-water interface[J]. Science of the Total Environment, 2017,592:662-673.
    doi: 10.1016/j.scitotenv.2017.02.219 pmid: 28318691
    [7]
    苏青青, 胡志华, 罗玉红, 等. 原位覆盖层厚度对污染底泥氮磷释放的影响[J]. 安徽农业科学, 2012,40(27):329-330.

    SU Q Q, HU Z H, LUO Y H, et al. Influence of the in situ capping layer thickness on nitrogen and phosphorus release of the contaminated sediment[J]. Journal of Anhui Agricultural Sciences, 2012,40(27):329-330.
    [8]
    于翔霏, 程宪伟, 祝惠, 等. 长春西湖沉积物氮、磷营养盐释放通量及原位覆盖控释效果模拟研究[J]. 湿地科学, 2017,15(4):595-600.

    YU X F, CHENG X W, ZHU H, et al. Simulation study on release fluxes of nitrogen and phosphorus from sediments in Xihu Lakes,Changchun and sustained-release effect of in-situ capping[J]. Wetland Science, 2017,15(4):595-600.
    [9]
    夏蕾, 刘国, 陈春梅, 等. 稳定剂增强的土壤原位覆盖抑制河流底泥氮磷释放研究[J]. 环境工程, 2016,34(9):114-118.

    XIA L, LIU G, CHEN C M, et al. Efficiency of in-situ capping with stabilizers-added soil on nitrogen and phosphorus release control in river sediment[J]. Environmental Engineering, 2016,34(9):114-118.
    [10]
    朱兰保, 盛蒂, 朱攀. 原位覆盖法对底泥中磷释放的影响[J]. 江苏农业科学, 2014,42(2):301-303.
    [11]
    周岩梅, 任传华, 孟晓东, 等. 生物质活性炭原位修复有机物污染底泥技术研究与应用[J]. 环境科学研究, 2019,32(1):43-51.

    ZHOU Y M, REN C H, MENG X D, et al. Research and application of in-situ activated biochar amendment for organic contaminated sediment remediation[J]. Research of Environmental Sciences, 2019,32(1):43-51.
    [12]
    杨海燕, 师路远, 卢少勇, 等. 不同覆盖材料对沉积物P、N释放的抑制效果[J]. 环境工程学报, 2015,9(5):2084-2090.

    YANG H Y, SHI L Y, LU S Y, et al. Effect of various inactivation agents on phosphorus and nitrogen release from sediments[J]. Chinese Journal of Environmental Engineering, 2015,9(5):2084-2090.
    [13]
    SINGH B P, COWIE A L, SMEMIK R J. Biochar carbon stability in a clayey soil as a function of feedstock and pyrolysis temperature[J]. Environmental Science & Technology, 2012,46(21):11770-11778.
    doi: 10.1021/es302545b pmid: 23013285
    [14]
    吕宏虹, 宫艳艳, 唐景春, 等. 生物炭及其复合材料的制备与应用研究进展[J]. 农业环境科学学报, 2015,34(8):1429-1440.

    LÜ H H, GONG Y Y, TANG J C, et al. Advances in preparation and applications of biochar and its composites[J]. Journal of Agro-Environment Science, 2015,34(8):1429-1440.
    [15]
    孔丝纺, 姚兴成, 张江勇, 等. 生物质炭的特性及其应用的研究进展[J]. 生态环境学报, 2015,24(4):716-723.

    KONG S F, YAO X C, ZHANG J Y, et al. Review of characteristics of biochar and research progress of its applications[J]. Ecology and Environmental Sciences, 2015,24(4):716-723.
    [16]
    祝天宇, 卢泽玲, 刘月娥, 等. 镁改性生物炭制备条件对其氮、磷去除性能的影响[J]. 环境工程, 2018,36(1):37-41.

    ZHU T Y, LU Z L, LIU Y E, et al. Effects of preparation conditions of Mg-modified biochar on the removal of ammonium and phosphate in wastewater[J]. Environmental Engineering, 2018,36(1):37-41.
    [17]
    丁文川, 曾晓岚, 王永芳, 等. 生物炭载体的表面特征和挂膜性能研究[J]. 中国环境科学, 2011,31(9):1451-1455.

    DING W C, ZENG X L, WANG Y F, et al. Characteristics and performances of biofilm carrier prepared from agro-based biochar[J]. China Environmental Science, 2011,31(9):1451-1455.
    [18]
    WANG M, ZHU Y, CHENG L, et al. Review on utilization of biochar for metal-contaminated soil and sediment remediation[J]. Journal of Environmental Sciences, 2017,63(1):156-173.
    doi: 10.1016/j.jes.2017.08.004
    [19]
    李扬, 李锋民, 张修稳, 等. 生物炭覆盖对底泥污染物释放的影响[J]. 环境科学, 2013,34(8):3071-3078.

    LI Y, LI F M, ZHANG X W, et al. Effects of biochar covering on the release of pollutants from sediment[J]. Environmental Science, 2013,34(8):3071-3078.
    [20]
    郅蒙蒙, 王鹏飞, 侯泽英, 等. N H 4 + 对镁改性生物炭除磷效果的影响 [J]. 环境科学, 2019,40(2):669-676.

    ZHI M M, WANG P F, HOU Z Y, et al. Effect of nitrogen to magnesium modified biochar adsorption to phosphorus[J]. Environmental Science, 2019,40(2):669-676.
    [21]
    CUI X, HAO H, ZHANG C, et al. Capacity and mechanisms of ammonium and cadmium sorption on different wetland-plant derived biochars[J]. Science of the Total Environment, 2016,539:566-575.
    doi: 10.1016/j.scitotenv.2015.09.022 pmid: 26386447
    [22]
    王秀朵, 张大群, 刘瑶, 等. 锁磷剂用于富营养化水体除磷的研究[J]. 中国给水排水, 2010,26(23):88-90.

    WANG X D, ZHANG D Q, LIU Y, et al. Study on removal of phosphorus from eutrophic water using Phoslock[J]. China Water & Wastewater, 2010,26(23):88-90.
    [23]
    GUNN I D M, MEUS S, MABERLY S C, et al. Assessing the responses of aquatic macrophytes to the application of a lanthanum modified bentonite clay,at Loch Flemington,Scotland,UK[J]. Hydrobiologia, 2013,737(1):309-320.
    doi: 10.1007/s10750-013-1765-5
    [24]
    MIQUEL L, OOSTERHOUT F V. Case study on the efficacy of a lanthanum-enriched clay (Phoslock?) in controlling eutrophication in Lake Het Groene Eiland (The Netherlands)[J]. Hydrobiologia, 2013,710(1):253-263.
    doi: 10.1007/s10750-012-1141-x
    [25]
    张路, 范成新, 秦伯强, 等. 模拟扰动条件下太湖表层沉积物磷行为的研究[J]. 湖泊科学, 2001,13(1):35-42.
    doi: 10.18307/20010106

    ZHANG L, FAN C X, QIN B Q, et al. Phosphorus release and absorption of surficial sediments in Taihu Lake under simulative disturbing conditions[J]. Journal of Lake Sciences, 2001,13(1):35-42. doi: 10.18307/20010106
    [26]
    ZHANG S, TIAN K, JIANG S F, et al. Preventing the release of Cu 2+ and 4-CP from the contaminated sediments by employing a biochar capping treatment [J]. Industrial & Engineering Chemistry Research, 2017,56(27):7730-7738.
    [27]
    US EPA. Data quality assessment:statistical methods for practitioners:EPA/240/B-06/003[S]. Washington DC:United States Environmental Protection Agency,Office of Environmental Information, 2006.
    [28]
    韩晓霞, 朱广伟, 李兆富, 等. 天目湖沙河水库尿素含量及其时空分布特征分析[J]. 环境化学, 2015,34(2):377-383.

    HAN X X, ZHU G W, LI Z F, et al. The abundance and spatial-temporal distribution of urea in Shahe Reservoir,Liyang,China[J]. Environmental Chemistry, 2015,34(2):377-383.
    [29]
    陈佼, 张建强, 陆一新, 等. 玉米芯生物炭对含盐污水中氨氮的吸附特性[J]. 安全与环境学报, 2017,17(3):1088-1093.

    CHEN J, ZHANG J Q, LU Y X, et al. Study on the adsorption feature of ammonium nitrogen in the salt-laden sewage by the corn cob biochar[J]. Journal of Safety and Environment, 2017,17(3):1088-1093.
    [30]
    陶大钧, 龚娴芙. 废水和地表水中磷的形态分析[J]. 环境监测管理与技术, 1994,6(3):21-24.
    [31]
    JIANG Y B, REN C, GUO H Y, et al. Speciation transformation of phosphorus in poultry litter during pyrolysis:insights from X-ray diffraction,fourier transform infrared,and solid-state NMR spectroscopy[J]. Environmental Science & Technology, 2019,53(23):13841-13849.
    doi: 10.1021/acs.est.9b03261 pmid: 31684726
    [32]
    周成. 湖泊受污底泥营养物释放机理及水质影响试验研究[D]. 武汉:武汉大学, 2017.
    [33]
    李际会. 改性生物炭吸附硝酸盐和磷酸盐研究[D]. 北京:中国农业科学院, 2012.
    [34]
    DEMIRAL H, GUNDUZOGLU G. Removal of nitrate from aqueous solutions by activated carbon prepared from sugar beet bagasse[J]. Bioresource Technology, 2010,101:1675-1680.
    doi: 10.1016/j.biortech.2009.09.087 pmid: 19854640
    [35]
    OEZTURK N, BEKTA T E. Nitrate removal from aqueous solution by adsorption onto various materials[J]. Journal of Hazardous Materials, 2004,112(1/2):155-162.
    doi: 10.1016/j.jhazmat.2004.05.001
    [36]
    陈靖. Fe/Mg改性生物炭去除水中氮磷的研究[D]. 重庆:重庆大学, 2015.
    [37]
    李寿泉. 浅析环境因子对城市缓流水体底泥磷释放的影响[J]. 江苏环境科技, 2007,20(6):13-16.
    [38]
    王茹静, 赵旭, 曹瑞钰. 富营养化水体中底泥释磷的影响因素及其释放机理[J]. 新疆环境保护, 2005,18(4):47-49.

    WANG R J, ZHAO X, CAO R Y. Study on the affecting factors and its mechanism of interal phosphorus release in eutrophic water[J]. Environmental Protection of Xinjiang, 2005,18(4):47-49.
    [39]
    席银, 王圣瑞, 赵海超, 等. 覆盖不同材料对湖泊沉积物磷释放影响机制[J]. 环境化学, 2017,36(3):532-541.

    XI Y, WANG S R, ZHAO H C, et al. Impact of different capping materials on the phosphorus release from lake sediment[J]. Environmental Chemistry, 2017,36(3):532-541.
    [40]
    孔明, 尹洪斌, 晁建颖, 等. 凹凸棒黏土覆盖对沉积物磷赋存形态的影响[J]. 中国环境科学, 2015,35(7):2192-2199.

    KONG M, YIN H B, CHAO J Y, et al. Influence of attapulgite clay capping on phosphorus forms in the sediment[J]. China Environmental Science, 2015,35(7):2192-2199.
    [41]
    SAHA B, BAINGS R, GREENWOOD F. Physicochemical characterization of granular ferric hydroxide (GFH) for Arsenic(V) sorption from water[J]. Separation Science and Technology, 2005,40:2909-2932.
    doi: 10.1080/01496390500333202
    [42]
    何菁, 尹光彩, 李莲芳, 等. 骨炭/纳米铁对污染红壤中砷形态和有效性的影响研究[J]. 农业环境科学学报, 2014,33(8):1511-1518.

    HE J, YIN G C, LI L F, et al. Effects of bone char and nano-iron on fractions and availability of arsenic in contaminated red soils[J]. Journal of Agro-Environment Science, 2014,33(8):1511-1518.
    [43]
    BOLAN N, MAHIMAIRAJA S, KUNHIKRISHNAN A, et al. Sorptionbioavailability nexus of arsenic and cadmium in variable charge soils[J]. Journal of Hazardous Materials, 2013,261:725-732.
    doi: 10.1016/j.jhazmat.2012.09.074
    [44]
    JACKSON B P, MILLER W P. Effectiveness of phosphate and hydroxide for desorption of arsenic and selenium species from iron oxides[J]. Soil Science Society of America Journal, 2000,64(5):1616-1622.
    doi: 10.2136/sssaj2000.6451616x
    [45]
    韦璐阳. 钙、镁、铁对土壤砷污染的治理研究[D]. 南宁:广西大学, 2005.
    • Relative Articles
    • Supplements(0)
    • Cited By
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索
    Get Citation
    PDF
    XML

    Article Metrics

    Article Views(699) PDF Downloads(123) Cited by()
    Proportional views
    Related

    Copyright © Editorial Department of Journal of Environmental Engineering Technology

    京ICP备05031605号-2

    Supported by: Beijing Renhe Information Technology Co., Ltd.  

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return