Volume 12 Issue 5
Sep.  2022
Turn off MathJax
Article Contents
MENG T,WANG X W,WANG S F,et al.Pollution characteristic analysis of parabens compounds in typical lakes in Beijing[J].Journal of Environmental Engineering Technology,2022,12(5):1389-1394 doi: 10.12153/j.issn.1674-991X.20210383
Citation: MENG T,WANG X W,WANG S F,et al.Pollution characteristic analysis of parabens compounds in typical lakes in Beijing[J].Journal of Environmental Engineering Technology,2022,12(5):1389-1394 doi: 10.12153/j.issn.1674-991X.20210383

Pollution characteristic analysis of parabens compounds in typical lakes in Beijing

doi: 10.12153/j.issn.1674-991X.20210383
  • Received Date: 2021-08-05
  • In order to study the pollution level and distribution characteristics of parabens (PBs) in lakes, the pollution status of 14 PBs in typical lakes in Beijing was investigated and analyzed. The water samples of a lake in Beijing were collected in both winter and summer, and detected by solid-phase extraction and liquid chromatography-triple quadrupole tandem mass spectrometry. The results showed that ten kinds of PBs were detected with high level in the lake, among which methylparaben (MeP, 24.8 ng/L) and propylparaben (PrP, 44.8 ng/L) were the dominant compounds. The concentrations of the target compounds detected at the same sampling site changed seasonally, and the concentrations of chlorinated parabens in spring were lower than those in winter. However, in the winter near the outlet of the wastewater treatment plant, the concentrations of chlorinated parabens were higher than those at other sampling sites. The external sewage was the main source of PBs in the lake water, and the concentration of MeP at the sampling site of the outlet of the power plant in spring (24.8 ng/L) was higher than that in winter (1.30 ng/L). The survey results showed that the species and concentration level of PBs in the lake were medium comparing with those reported in the researches of other nations. The pollution of PBs in the lake mainly came from the surrounding sewage discharge, and the concentration of PBs varied greatly in different seasons.

     

  • loading
  • [1]
    LEE H B, PEART T E, SVOBODA M L. Determination of endocrine-disrupting phenols, acidic pharmaceuticals, and personal-care products in sewage by solid-phase extraction and gas chromatography-mass spectrometry[J]. Journal of Chromatography A,2005,1094(1/2):122-129.
    [2]
    Final amended report on the safety assessment of methylparaben, ethylparaben, propylparaben, isopropylparaben, butylparaben, isobutylparaben, and benzylparaben as used in cosmetic products[M/OL]. [2021-08-10].https://journals.sagepub.com/doi/10.1177/109158180802704s01.
    [3]
    林忠洋, 马万里, 齐迹, 等.对羟基苯甲酸酯类防腐剂的人体暴露[J]. 化学进展,2015,27(5):614-622.

    LIN Z Y, MA W L, QI J, et al. Human exposure to parabens[J]. Progress in Chemistry,2015,27(5):614-622.
    [4]
    蔺远, 傅建捷, 高常安, 等.对羟基苯甲酸酯雌激素活性物种差异的理论研究[J]. 环境化学,2011,30(2):399-404.

    LIN Y, FU J J, GAO C A, et al. Insight into specie difference in estrogenic activities of selected parabens by computer modeling[J]. Environmental Chemistry,2011,30(2):399-404.
    [5]
    GUO Y, KANNAN K. A survey of phthalates and parabens in personal care products from the United States and its implications for human exposure[J]. Environmental Science & Technology,2013,47(24):14442-14449.
    [6]
    王亮, 毛茜慧, 袁守军, 等.气相色谱-质谱联用法同时测定污水中对羟基苯甲酸酯和甾体雌激素[J]. 环境化学,2016,35(1):49-56. doi: 10.7524/j.issn.0254-6108.2016.01.2015081901

    WANG L, MAO Q H, YUAN S J, et al. Simultaneous determination of parabens and steroid estrogens in sewage water using gas chromatography-mass spectrometry[J]. Environmental Chemistry,2016,35(1):49-56. doi: 10.7524/j.issn.0254-6108.2016.01.2015081901
    [7]
    林贞贤, 汝少国.环境内分泌干扰物促进乳腺细胞增殖的分子机制研究进展[J]. 环境科学研究,2018,31(5):796-804. doi: 10.13198/j.issn.1001-6929.2018.03.03

    LIN Z X, RU S G. Research advances on the molecular mechanism of environmental endocrine disrupting chemicals on promoting breast cell proliferation[J]. Research of Environmental Sciences,2018,31(5):796-804. doi: 10.13198/j.issn.1001-6929.2018.03.03
    [8]
    SONI M G, CARABIN I G, BURDOCK G A. Safety assessment of esters of p-hydroxybenzoic acid (parabens)[J]. Food and Chemical Toxicology,2005,43(7):985-1015. doi: 10.1016/j.fct.2005.01.020
    [9]
    岳强.对羟基苯甲酸酯在人体中的暴露研究进展[J]. 北方环境,2011,23(3):161-165.

    YUE Q. Advances in human exposure of parabens[J]. Northern Environment,2011,23(3):161-165.
    [10]
    金相灿, 王圣瑞, 席海燕.湖泊生态安全及其评估方法框架[J]. 环境科学研究,2012,25(4):357-362. doi: 10.13198/j.res.2012.04.4.jinxc.005

    JIN X C, WANG S R, XI H Y. Lake ecological security and assessment methodology framework[J]. Research of Environmental Sciences,2012,25(4):357-362. doi: 10.13198/j.res.2012.04.4.jinxc.005
    [11]
    BENIJTS T, LAMBERT W, de LEENHEER A. Analysis of multiple endocrine disruptors in environmental waters via wide-spectrum solid-phase extraction and dual-polarity ionization LC-ion trap-MS/MS[J]. Analytical Chemistry,2004,76(3):704-711. doi: 10.1021/ac035062x
    [12]
    GORGA M, PETROVIC M, BARCELÓ D. Multi-residue analytical method for the determination of endocrine disruptors and related compounds in river and waste water using dual column liquid chromatography switching system coupled to mass spectrometry[J]. Journal of Chromatography A,2013,1295:57-66. doi: 10.1016/j.chroma.2013.04.028
    [13]
    PENG X Z, YU Y Y, TANG C M, et al. Occurrence of steroid estrogens, endocrine-disrupting phenols, and acid pharmaceutical residues in urban riverine water of the Pearl River Delta, South China[J]. Science of the Total Environment,2008,397(1/2/3):158-166.
    [14]
    WEI F, MORTIMER M, CHENG H F, et al. Parabens as chemicals of emerging concern in the environment and humans: a review[J]. Science of the Total Environment,2021,778:146150. doi: 10.1016/j.scitotenv.2021.146150
    [15]
    姜琦, 席海燕, 焦立新, 等.我国湖泊管理的思考[J]. 环境工程技术学报,2012,2(1):44-50. doi: 10.3969/j.issn.1674-991X.2012.01.008

    JIANG Q, XI H Y, JIAO L X, et al. Some thinkings on lake management in China[J]. Journal of Environmental Engineering Technology,2012,2(1):44-50. doi: 10.3969/j.issn.1674-991X.2012.01.008
    [16]
    YAMAMOTO H, TAMURA I, HIRATA Y, et al. Aquatic toxicity and ecological risk assessment of seven parabens: individual and additive approach[J]. Science of the Total Environment,2011,410/411:102-111. doi: 10.1016/j.scitotenv.2011.09.040
    [17]
    WANG L, KANNAN K. Alkyl protocatechuates as novel urinary biomarkers of exposure to p-hydroxybenzoic acid esters (parabens)[J]. Environment International,2013,59:27-32. doi: 10.1016/j.envint.2013.05.001
    [18]
    CRISTINA JARDIM V, de PAULA MELO L, SOARES DOMINGUES D, et al. Determination of parabens in urine samples by microextraction using packed sorbent and ultra-performance liquid chromatography coupled to tandem mass spectrometry[J]. Journal of Chromatography B,2015,974:35-41. doi: 10.1016/j.jchromb.2014.10.026
    [19]
    赵佳慧, 冯精兰, 席楠楠, 等.超高效液相色谱-三重四极杆质谱测定沉积物中6种对羟基苯甲酸酯及其代谢产物[J]. 分析化学,2018,46(2):260-264. doi: 10.11895/j.issn.0253-3820.170330

    ZHAO J H, FENG J L, XI N N, et al. Determination of paraben and its metabolite in sediments by ultra performance liquid chromatography-triple quadrupole tandem mass spectrometry[J]. Chinese Journal of Analytical Chemistry,2018,46(2):260-264. doi: 10.11895/j.issn.0253-3820.170330
    [20]
    李闯修, 赵晓丽, 高立红, 等.高效液相色谱-串联质谱法测定地表水样品中5种有机磷酸酯代谢物[J]. 分析测试学报,2016,35(2):194-199. doi: 10.3969/j.issn.1004-4957.2016.02.010

    LI C X, ZHAO X L, GAO L H, et al. Determination of five organophosphate ester metabolites in surface water samples by LC-MS/MS[J]. Journal of Instrumental Analysis,2016,35(2):194-199. doi: 10.3969/j.issn.1004-4957.2016.02.010
    [21]
    GONZÁLEZ-MARIÑO I, QUINTANA J B, RODRÍGUEZ I, et al. Simultaneous determination of parabens, triclosan and triclocarban in water by liquid chromatography/electrospray ionisation tandem mass spectrometry[J]. Rapid Communications in Mass Spectrometry,2009,23(12):1756-1766. doi: 10.1002/rcm.4069
    [22]
    TERASAKI M, TAKEMURA Y, MAKINO M. Paraben-chlorinated derivatives in river waters[J]. Environmental Chemistry Letters,2012,10(4):401-406. doi: 10.1007/s10311-012-0367-1
    [23]
    JONKERS N, KOHLER H P E, DAMMSHÄUSER A, et al. Mass flows of endocrine disruptors in the Glatt River during varying weather conditions[J]. Environmental Pollution,2009,157(3):714-723. ◇ doi: 10.1016/j.envpol.2008.11.029
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Figures(4)  / Tables(5)

    Article Metrics

    Article Views(258) PDF Downloads(34) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return