Citation: | HUANG Z Y,ZHANG Y H,CAO J L,et al.Distribution and risk assessment of semi-volatile organic compounds in water and sediment of Ulansuhai Nur[J].Journal of Environmental Engineering Technology,2023,13(2):607-616 doi: 10.12153/j.issn.1674-991X.20220376 |
In order to study the pollution characteristics and risk level of semi-volatile organic compounds (SVOCs) in water and surface sediments of Ulansuhai Nur, water and sediment samples from 7 sites were detected and analyzed. The total concentration of SVOCs in water and sedimentary species ranged from 449.7 to 691.0 ng/L and 144.4 to 587.5 µg/kg, respectively. Polycyclic aromatic hydrocarbons (PAHs) and phthalate esters (PAEs) were the main contaminant compounds found in all samples. Other SVOCs were not detected or only trace. PAHs pollution in water and sediment mainly came from petroleum source and mixed source of coal and biomass fuel combustion. PAEs pollution mainly came from plastics and chemical industry and domestic wastes. The ecological risk of the main contaminants in water and sediment of Ulansuhai Nur was at a low level in general, and the health risk also presented a low level in terms of drinking water and exposure.
[1] |
马妍, 董彬彬, 徐东耀, 等.VOCs/SVOCs污染土壤常用修复技术及其在美国超级基金污染场地中的应用[J]. 环境工程技术学报,2016,6(4):391-396.
MA Y, DONG B B, XU D Y, et al. Common used remediation technologies for volatile and semivolatile organic compounds contaminated soils and their application in us superfund sites[J]. Journal of Environmental Engineering Technology,2016,6(4):391-396.
|
[2] |
LI G Y, SUN H W, ZHANG Z Y, et al. Distribution profile, health risk and elimination of model atmospheric SVOCs associated with a typical municipal garbage compressing station in Guangzhou, South China[J]. Atmospheric Environment,2013,76:173-180. doi: 10.1016/j.atmosenv.2012.06.027
|
[3] |
员晓燕, 杨玉义, 李庆孝, 等.中国淡水环境中典型持久性有机污染物(POPs)的污染现状与分布特征[J]. 环境化学,2013,32(11):2072-2081.
YUN X Y, YANG Y Y, LI Q X, et al. Present situation and distribution characteristics of persistent organic pollutants in freshwater in China[J]. Environmental Chemistry,2013,32(11):2072-2081.
|
[4] |
SHI P, ZHOU S C, XIAO H X, et al. Toxicological and chemical insights into representative source and drinking water in Eastern China[J]. Environmental Pollution,2018,233:35-44. doi: 10.1016/j.envpol.2017.10.033
|
[5] |
徐海霞, 陶文铨.我国室内空气中半挥发性有机化合物的来源和污染现状[J]. 环境与健康杂志,2013,30(11):1030-1033.
XU H X, TAO W Q. Source and pollution status of semi-volatile organic compounds in indoor air in China: a review of recent studies[J]. Journal of Environment and Health,2013,30(11):1030-1033.
|
[6] |
葛祥, 吴健, 高松, 等.典型化工集中区环境空气SVOCs污染特征及来源解析[J]. 环境科学,2021,42(12):5663-5672.
GE X, WU J, GAO S, et al. Characteristics and source apportionment of atmospheric SVOCs around typical chemical industry zones[J]. Environmental Science,2021,42(12):5663-5672.
|
[7] |
吉贵祥, 顾杰, 郭敏, 等.南京市典型地区大气多环芳烃污染特征及健康风险评价[J]. 环境监控与预警,2021(5):87-92. doi: 10.3969/j.issn.1674-6732.2021.05.016
JI G X, GU J, GUO M, et al. Pollution characteristics and health risk assessment of atmospheric PAHs in typical areas in Nanjing City[J]. Environmental Monitoring and Forewarning,2021(5):87-92. doi: 10.3969/j.issn.1674-6732.2021.05.016
|
[8] |
杨飞. 济南市大气颗粒物PM2.5中多环芳烃(PAHs)的污染特征及来源解析[D]. 济南: 山东大学, 2014.
|
[9] |
SHAO H Y, ZHANG Z C, CHAI J F, et al. Pollution characteristics and underlying ecological risks of primary semi-volatile organic compounds (SVOCs) in urban watersheds of Shanghai, China[J]. Environmental Science and Pollution Research International,2020,27(22):27708-27720. doi: 10.1007/s11356-020-08528-3
|
[10] |
TANG J, AN T C, LI G Y, et al. Spatial distributions, source apportionment and ecological risk of SVOCs in water and sediment from Xijiang River, Pearl River Delta[J]. Environmental Geochemistry and Health,2018,40(5):1853-1865. doi: 10.1007/s10653-017-9929-2
|
[11] |
HE X R, PANG Y, SONG X J, et al. Distribution, sources and ecological risk assessment of PAHs in surface sediments from Guan River Estuary, China[J]. Marine Pollution Bulletin,2014,80(1/2):52-58.
|
[12] |
LU M, ZENG D C, LIAO Y, et al. Distribution and characterization of organochlorine pesticides and polycyclic aromatic hydrocarbons in surface sediment from Poyang Lake, China[J]. Science of the Total Environment,2012,433:491-497. doi: 10.1016/j.scitotenv.2012.06.108
|
[13] |
何连生, 席北斗, 雷宏军, 等. 乌梁素海综合治理规划研究[M]. 北京: 中国环境出版社, 2013.
|
[14] |
邓晓红, 张巧丽, 刘文强, 等.乌梁素海水生生物多样性调查及分析[J]. 内蒙古林业,2020(10):37-38.
|
[15] |
邵海洋. 上海市水体和沉积物中半挥发性有机物污染水平、来源分析和风险评估[D]. 上海: 上海大学, 2018.
|
[16] |
张映映, 冯流, 刘征涛.长江口区域水体半挥发性有机污染物健康风险评价[J]. 环境科学研究,2007,20(1):18-23. doi: 10.3321/j.issn:1001-6929.2007.01.004
ZHANG Y Y, FENG L, LIU Z T. Health risk assessment on semivolatile organic compounds in water of Yangtze Estuary area[J]. Research of Environmental Sciences,2007,20(1):18-23. doi: 10.3321/j.issn:1001-6929.2007.01.004
|
[17] |
环境保护部. 中国人群暴露参数手册: 成人卷[M]. 北京: 中国环境出版社, 2013.
|
[18] |
LONG E R, MACDONALD D D, SMITH S L, et al. Incidence of adverse biological effects within ranges of chemical concentrations in marine and estuarine sediments[J]. Environmental Management,1995,19(1):81-97. doi: 10.1007/BF02472006
|
[19] |
李婷. 珠江河口水体和沉积物中6种邻苯二甲酸酯污染及初步风险评价[D]. 广州: 暨南大学, 2014.
|
[20] |
YAO C X, CHEN Z L, XU S Y, et al. Pollution characteristics of the rivers in suburban Shanghai[J]. Journal of Geographical Sciences,2005,15(1):29-36. doi: 10.1007/BF02873104
|
[21] |
US EPA. EPA822-Z-99-001 National recommended water quality criteria correction[S]. Washongton DC: United States Environmental Protection Agency, Office of Water, 1999
|
[22] |
国家环境保护总局, 国家质量监督检验检疫总局. 地表水环境质量标准: GB 3838—2002[S]. 北京: 中国环境科学出版社, 2002.
|
[23] |
建设部.城市供水水质标准: CJ/T 206—2005[S]. 2005.
|
[24] |
ZHAO Z H, GONG X H, ZHANG L, et al. Riverine transport and water-sediment exchange of polycyclic aromatic hydrocarbons (PAHs) along the middle-Lower Yangtze River, China[J]. Journal of Hazardous Materials,2021,403:123973. doi: 10.1016/j.jhazmat.2020.123973
|
[25] |
ZHAO Y L, LI J S, QI Y, et al. Distribution, sources, and ecological risk assessment of polycyclic aromatic hydrocarbons (PAHs) in the tidal creek water of coastal tidal Flats in the Yellow River Delta, China[J]. Marine Pollution Bulletin,2021,173:113110. doi: 10.1016/j.marpolbul.2021.113110
|
[26] |
吴兴让, 尹平河, 赵玲, 等.珠江广州段水体微表层与次表层中多环芳烃的分布与组成[J]. 环境科学学报,2010,30(4):868-873.
WU X R, YIN P H, ZHAO L, et al. Distribution and composition of polycyclic aromatic hydrocarbons in the surface microlayer and the subsurface microlayer from the Guangzhou Section of the Pearl River[J]. Acta Scientiae Circumstantiae,2010,30(4):868-873.
|
[27] |
KAFILZADEH F. Distribution and sources of polycyclic aromatic hydrocarbons in water and sediments of the Soltan Abad River, Iran[J]. Egyptian Journal of Aquatic Research,2015,41(3):227-231. doi: 10.1016/j.ejar.2015.06.004
|
[28] |
MONTUORI P, AURINO S, GARZONIO F, et al. Distribution, sources and ecological risk assessment of polycyclic aromatic hydrocarbons in water and sediments from Tiber River and estuary, Italy[J]. Science of the Total Environment,2016,566/567:1254-1267. doi: 10.1016/j.scitotenv.2016.05.183
|
[29] |
SUN J H, WANG G L, CHAI Y, et al. Distribution of polycyclic aromatic hydrocarbons (PAHs) in Henan reach of the Yellow River, middle China[J]. Ecotoxicology and Environmental Safety,2009,72(5):1614-1624. doi: 10.1016/j.ecoenv.2008.05.010
|
[30] |
LI H Y, LAI Z N, ZENG Y Y, et al. Occurrence, source identification, and ecological risk assessment of polycyclic aromatic hydrocarbons in sediments of the Pearl River Delta, China[J]. Marine Pollution Bulletin,2021,170:112666. doi: 10.1016/j.marpolbul.2021.112666
|
[31] |
胡文, 张海婷, 张永敏, 等.马鞍山市内河沉积物中多环芳烃分布特征、来源及生态风险[J]. 环境科技,2018,31(3):50-56.
HU W, ZHANG H T, ZHANG Y M, et al. Distribution characteristics, sources and ecological risk of polycyclic aromatic hydrocarbons in urban rivers of Maanshan City[J]. Environmental Science and Technology,2018,31(3):50-56.
|
[32] |
杜士林, 丁婷婷, 董淮晋, 等.沙颍河流域水环境中多环芳烃污染及风险评价[J]. 农业环境科学学报,2020,39(3):601-611. doi: 10.11654/jaes.2019-1211
DU S L, DING T T, DONG H J, et al. Pollution and ecological risk assessment of polycyclic aromatic hydrocarbons in the water environment of Shaying River Basin, China[J]. Journal of Agro-Environment Science,2020,39(3):601-611. doi: 10.11654/jaes.2019-1211
|
[33] |
郑涛, 卢怡清, 陆志波, 等.太湖流域典型水系中多环芳烃的分布、来源及风险评价: 以湖州市德清县乾元镇为例[J]. 环境保护科学,2021,47(5):89-94.
ZHENG T, LU Y Q, LU Z B, et al. Distribution, sources and risk assessment of polycyclic aromatic hydrocarbons(PAHs) in typical water systems of Taihu Lake Basin: a case study of Qianyuan Town, Deqing, Huzhou[J]. Environmental Protection Science,2021,47(5):89-94.
|
[34] |
朱冰清, 高占啟, 胡冠九, 等.太湖重点区域水环境中邻苯二甲酸酯的污染水平及生态风险评价[J]. 环境科学,2018,39(8):3614-3621.
ZHU B Q, GAO Z Q, HU G J, et al. Contamination levels and ecological risk assessment of phthalate esters(PAEs) in the aquatic environment of key areas of Taihu Lake[J]. Environmental Science,2018,39(8):3614-3621.
|
[35] |
SN A, SRA B, RBSA C, et al.Distribution of phthalates, pesticides and drug residues in the dissolved, particulate and sedimentary phases from transboundary rivers (france–belgium)[J]. 刊名缺失,2015,15(521):152-159.
|
[36] |
艾舜豪. 鄱阳湖邻苯二甲酸酯的水质基准研究与风险评价[D]. 南昌: 南昌大学, 2020.
|
[37] |
杨文韬. 巢湖流域邻苯二甲酸酯的污染水平及生态风险评价[D]. 合肥: 合肥工业大学, 2021.
|
[38] |
胡卫星. 渭河流域西安段水体中PAEs的污染特征及生态风险评价[D]. 西安: 长安大学, 2019.
|
[39] |
SCHMIDT N, CASTRO-JIMÉNEZ J, OURSEL B, et al. Phthalates and organophosphate esters in surface water, sediments and zooplankton of the NW Mediterranean Sea: exploring links with microplastic abundance and accumulation in the marine food web[J]. Environmental Pollution,2021,272:115970. doi: 10.1016/j.envpol.2020.115970
|
[40] |
卓丽, 石运刚, 蔡凤珊, 等.长江干流、嘉陵江和乌江重庆段邻苯二甲酸酯污染特征及生态风险评估[J]. 生态毒理学报,2020,15(3):158-170.
ZHUO L, SHI Y G, CAI F S, et al. Pollution characteristics and ecological risk assessment of phthalate esters in the Yangtze River, Jialing River and Wujiang River in Chongqing, China[J]. Asian Journal of Ecotoxicology,2020,15(3):158-170.
|
[41] |
PUIG D, BARCELÓ D. Comparative study of on-line solid phase extraction followed by UV and electrochemical detection in liquid chromatography for the determination of priority phenols in river water samples[J]. Analytica Chimica Acta,1995,311(1):63-69. doi: 10.1016/0003-2670(95)00188-6
|
[42] |
高飞, 张文斌, 秦容, 等.g-C3N4/Fe-Cu的制备以及对4-硝基苯酚光催化降解性能研究[J]. 化学研究与应用,2021,33(10):1991-1998. doi: 10.3969/j.issn.1004-1656.2021.10.018
GAO F, ZHANG W B, QIN R, et al. Preparation of g-C3N4/Fe-Cu and research on the photocatalytic degradation properties of 4-nitrophenol[J]. Chemical Research and Application,2021,33(10):1991-1998. doi: 10.3969/j.issn.1004-1656.2021.10.018
|
[43] |
SELVARAJ K K, SUNDARAMOORTHY G, RAVICHANDRAN P K, et al. Phthalate esters in water and sediments of the Kaveri River, India: environmental levels and ecotoxicological evaluations[J]. Environmental Geochemistry and Health,2015,37(1):83-96. doi: 10.1007/s10653-014-9632-5
|
[44] |
王飞, 竺琴, 谢倩红, 等.废水中硝基苯类化合物的测量不确定度评定[J]. 环境科学与技术,2014,37(增刊 2):342-346.
WANG F, ZHU Q, XIE Q H, et al. Uncertainty evaluation for determining nitroaromatics in wastewater[J]. Environmental Science & Technology,2014,37(Suppl 2):342-346.
|
[45] |
贺小敏, 施敏芳.梁子湖水体和沉积物中邻苯二甲酸酯分布特征及生态健康风险评价[J]. 中国环境监测,2021,37(2):115-127.
HE X M, SHI M F. Distribution characteristics and ecological and health risk assessment of phthalic acid esters in surface water and sediment of liangzi lake, China[J]. Environmental Monitoring in China,2021,37(2):115-127.
|
[46] |
杨延梅, 赵航晨, 孟睿, 等.嘉兴市城市河网区多环芳烃污染源解析及生态风险评价[J]. 环境科学,2020,41(11):4989-4998.
YANG Y M, ZHAO H C, MENG R, et al. Sources and ecological risk assessment of polycyclic aromatic hydrocarbons in the Jiaxing River network[J]. Environmental Science,2020,41(11):4989-4998.
|
[47] |
GOCHT T, BARTH J A C, EPP M, et al. Indications for pedogenic formation of perylene in a terrestrial soil profile: depth distribution and first results from stable carbon isotope ratios[J]. Applied Geochemistry,2007,22(12):2652-2663. doi: 10.1016/j.apgeochem.2007.06.004
|
[48] |
CHRISTENSEN E R, BZDUSEK P A. PAHs in sediments of the Black River and the Ashtabula River, Ohio: source apportionment by factor analysis[J]. Water Research,2005,39(4):511-524. doi: 10.1016/j.watres.2004.11.016
|
[49] |
梁柳玲, 邓超冰, 廖平德, 等.南宁城市内河水体和表层沉积物中多环芳烃分布特征[J]. 中国环境监测,2012,28(5):67-70.
LIANG L L, DENG C B, LIAO P D, et al. Distribution characteristics of PAHs in water and surface sediments from the rivers of Nanning City[J]. Environmental Monitoring in China,2012,28(5):67-70.
|
[50] |
侯德坤. 内蒙古西部地区持久性有毒物质的分布特征及生态效应研究[D]. 呼和浩特: 内蒙古大学, 2014.
|
[51] |
李泽文, 王海燕, 孔秀琴, 等.松花江表层沉积物中16种多环芳烃空间分布特征及生态风险评价[J]. 环境科学研究,2020,33(1):163-173.
LI Z W, WANG H Y, KONG X Q, et al. Spatial distribution characteristics and ecological risk assessment of 16 PAHs in surface sediment of Songhua River[J]. Research of Environmental Sciences,2020,33(1):163-173.
|
[52] |
ROMERO-FRANCO M, HERNÁNDEZ-RAMÍREZ R U, CALAFAT A M, et al. Personal care product use and urinary levels of phthalate metabolites in Mexican women[J]. Environment International,2011,37(5):867-871. doi: 10.1016/j.envint.2011.02.014
|
[53] |
董磊, 汤显强, 林莉, 等.长江武汉段丰水期水体和沉积物中多环芳烃及邻苯二甲酸酯类有机污染物污染特征及来源分析[J]. 环境科学,2018,39(6):2588-2599.
DONG L, TANG X Q, LIN L, et al. Pollution characteristics and source identification of polycyclic aromatic hydrocarbons and phthalic acid esters during high water level periods in the Wuhan section of the Yangtze River, China[J]. Environmental Science,2018,39(6):2588-2599.
|
[54] |
HE Y, WANG Q M, HE W, et al. The occurrence, composition and partitioning of phthalate esters (PAEs) in the water-suspended particulate matter (SPM) system of Lake Chaohu, China[J]. Science of the Total Environment,2019,661:285-293. doi: 10.1016/j.scitotenv.2019.01.161
|
[55] |
NET S, SEMPÉRÉ R, DELMONT A, et al. Occurrence, fate, behavior and ecotoxicological state of phthalates in different environmental matrices[J]. Environmental Science & Technology,2015,49(7):4019-4035.
|
[56] |
ZHNAG C Y, TONG W. Social and economic impact assessment of Wuliangsuhai Watershed Mongolia, China[J]. Inner Mongolia Water Resources,2017(12):64-66.
|
[57] |
耿梦娇, 昌盛, 刘琰, 等.滹沱河冲洪积扇深层孔隙水中多环芳烃和酞酸酯的污染水平与饮水健康风险评估[J]. 中国环境科学,2016,36(12):7. doi: 10.3969/j.issn.1000-6923.2016.12.038
GENG M J, CHANG S, LIU Y, et al. Pollution status of and health risk assessment of drinking water of the polycyclic aromatic hydrocarbons and phthalate esters in the deep shallow pore water of Hutuo River Piuvial Fan[J]. China Environmental Science,2016,36(12):7. ⊕ doi: 10.3969/j.issn.1000-6923.2016.12.038
|