| Citation: | LI H,ZHENG L G,ZHANG Y H,et al.Distribution characteristics, source analysis and ecological risk of polycyclic aromatic hydrocarbons in surface water of Guoyang Coal Mine Area, Anhui Province[J].Journal of Environmental Engineering Technology，2024，14（4）：1299-1310 doi: 10.12153/j.issn.1674-991X.20230913
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In order to study the spatial distribution, source and ecological risk of polycyclic aromatic hydrocarbons (PAHs) in surface water of Guoyang mining area, gas chromatography-mass spectrometry (GC-MS) was used to detect and analyze the concentration of 16 kinds of priority control PAHs in surface water of the study area. The results showed that the concentration range of ∑PAHs in the surface water of Guoyang mining area was 93.59-1 701.77 ng/L, with an average content of 674.16 ng/L. The concentration range of monomer PAHs was nd-362.44 ng/L. Among monomer PAHs, the proportion of 2-ring, 3-ring and 4-ring PAHs was relatively high, while that of 6-ring PAHs was relatively low. Compared with the surface water in other regions of China, the concentration of PAHs in the surface water of the research area was at a moderate to high level. In terms of spatial distribution, there was a significant difference in the concentration of PAHs in the surface water of the study area. The closer to the mining area, the higher the concentration of PAHs. The molecular diagnostic ratio (MDR), positive matrix factorization (PMF) and principal component analysis (PCA) methods obtained similar source apportionment results. The results showed that PAHs in surface water mainly came from transportation sources, coal combustion sources and petroleum sources. The contribution rates of each pollution source obtained from PCA were 37.32% for coal combustion sources, 35.51% for transportation sources and 13.92% for petroleum sources, respectively. The contribution rates of each pollution source obtained from PMF model were 42.66% for transportation sources, 30.85% for coal combustion sources, and 26.49% for petroleum sources, respectively. The ecological risk assessment results indicate that BaA, BbF and BkF are at a high risk level, while the remaining monomer PAHs are at a moderate risk level. Among the 22 sampling points, only 6 are at the medium ecological risk level, and the rest are at the high ecological risk level. In general, the overall ecological risk of surface water in Guoyang mining area is at the medium to high risk level, which is potentially harmful to organisms, and ecological risk prevention needs to be strengthened.
| [1] |
ZHAO X, QIU H R, ZHAO Y L, et al. Distribution of polycyclic aromatic hydrocarbons in surface water from the upper reach of the Yellow River, Northwestern China[J]. Environmental Science and Pollution Research International,2015,22(9):6950-6956. doi: 10.1007/s11356-014-3846-z
|
| [2] |
TARAFDAR A, SINHA A. Health risk assessment and source study of PAHs from roadside soil dust of a heavy mining area in India[J]. Archives of Environmental & Occupational Health,2019,74(5):252-262.
|
| [3] |
花洁, 王健媛, 陈运帷, 等. 煤矿矿区土壤重金属及多环芳烃污染治理修复技术综述[J]. 环境工程技术学报,2024,14(1):139-147. doi: 10.12153/j.issn.1674-991X.20230524
HUA J, WANG J Y, CHEN Y W, et al. A review of heavy metal and polycyclic aromatic hydrocarbon pollution treatment and remediation technologies in coal mine soils[J]. Journal of Environmental Engineering Technology,2024,14(1):139-147. doi: 10.12153/j.issn.1674-991X.20230524
|
| [4] |
SHI R G, LI X H, YANG Y Y, et al. Contamination and human health risks of polycyclic aromatic hydrocarbons in surface soils from Tianjin coastal new region, China[J]. Environmental Pollution, 2021, 268(Part B): 115938.
|
| [5] |
QISHLAQI A, BEIRAMALI F. Potential sources and health risk assessment of polycyclic aromatic hydrocarbons in street dusts of Karaj urban area, northern Iran[J]. Journal of Environmental Health Science & Engineering,2019,17(2):1029-1044.
|
| [6] |
KANG M, KIM K, CHOI N, et al. Recent occurrence of PAHs and n-alkanes in PM2.5 in Seoul, Korea and characteristics of their sources and toxicity[J]. International Journal of Environmental Research and Public Health,2020,17(4):1397. doi: 10.3390/ijerph17041397
|
| [7] |
ZHENG H, QU C K, ZHANG J Q, et al. Polycyclic aromatic hydrocarbons (PAHs) in agricultural soils from Ningde, China: levels, sources, and human health risk assessment[J]. Environmental Geochemistry and Health,2019,41(2):907-919. doi: 10.1007/s10653-018-0188-7
|
| [8] |
史敬文, 张瑞杰, 韩民伟, 等. 北部湾涠洲岛珊瑚礁区多环芳烃污染特征研究[J]. 中国环境科学,2023,43(4):1802-1811.
SHI J W, ZHANG R J, HAN M W, et al. Pollution characteristics of polycyclic aromatic hydrocarbons in the coral reef regions of Weizhou Island, Beibu Gulf[J]. China Environmental Science,2023,43(4):1802-1811.
|
| [9] |
CHEN W, PENG B, HUANG H F, et al. Distribution and potential sources of OCPs and PAHs in waters from the Danshui River Basin in Yichang, China[J]. International Journal of Environmental Research and Public Health,2021,19(1):263. doi: 10.3390/ijerph19010263
|
| [10] |
杨梦茹, 徐雄, 王东红, 等. 长江典型江段水体PAHs的分布特征、来源及其生态风险[J]. 中国环境科学,2022,42(11):5308-5317. doi: 10.3969/j.issn.1000-6923.2022.11.037
YANG M R, XU X, WANG D H, et al. Distribution characteristics, source and ecological risks assessment of PAHs in water bodies of typical sections of the Yangtze River[J]. China Environmental Science,2022,42(11):5308-5317. doi: 10.3969/j.issn.1000-6923.2022.11.037
|
| [11] |
LI W W, ZHANG Z M, ZHANG R R, et al. Spatiotemporal occurrence, sources and risk assessment of polycyclic aromatic hydrocarbons in a typical mariculture ecosystem[J]. Water Research,2021,204:117632. doi: 10.1016/j.watres.2021.117632
|
| [12] |
吴喜军, 董颖, 赵健, 等. 陕北矿区典型河流多环芳烃的赋存特征、来源及毒性风险分析[J]. 环境科学,2023,44(4):2040-2051.
WU X J, DONG Y, ZHAO J, et al. Occurrence characteristics, sources, and toxicity risk analysis of polycyclic aromatic hydrocarbons in typical rivers of northern Shaanxi mining area, China[J]. Environmental Science,2023,44(4):2040-2051.
|
| [13] |
BAO K S, ZACCONE C, TAO Y Q, et al. Source apportionment of priority PAHs in 11 lake sediment cores from Songnen Plain, Northeast China[J]. Water Research,2020,168:115158. doi: 10.1016/j.watres.2019.115158
|
| [14] |
WANG C H, WU S H, ZHOU S L, et al. Characteristics and source identification of polycyclic aromatic hydrocarbons (PAHs) in urban soils: a review[J]. Pedosphere,2017,27(1):17-26. doi: 10.1016/S1002-0160(17)60293-5
|
| [15] |
杨延梅, 赵航晨, 孟睿, 等. 嘉兴市城市河网区多环芳烃污染源解析及生态风险评价[J]. 环境科学,2020,41(11):4989-4998.
YANG Y M, ZHAO H C, MENG R, et al. Sources and ecological risk assessment of polycyclic aromatic hydrocarbons in the Jiaxing River network[J]. Environmental Science,2020,41(11):4989-4998.
|
| [16] |
PAATERO P, TAPPER U. Positive matrix factorization: a non-negative factor model with optimal utilization of error estimates of data values[J]. Environmetrics,1994,5(2):111-126. doi: 10.1002/env.3170050203
|
| [17] |
PAATERO P. Least squares formulation of robust non-negative factor analysis[J]. Chemometrics and Intelligent Laboratory Systems,1997,37(1):23-35. doi: 10.1016/S0169-7439(96)00044-5
|
| [18] |
CAO Z G, LIU J L, LUAN Y, et al. Distribution and ecosystem risk assessment of polycyclic aromatic hydrocarbons in the Luan River, China[J]. Ecotoxicology,2010,19(5):827-837. doi: 10.1007/s10646-010-0464-5
|
| [19] |
ZHANG Y F, YIN J, QV Z, et al. Deriving freshwater sediment quality guidelines of polycyclic aromatic hydrocarbons using method of species sensitivity distribution and application for risk assessment[J]. Water Research,2022,225:119139. doi: 10.1016/j.watres.2022.119139
|
| [20] |
ZHENG B H, WANG L P, LEI K, et al. Distribution and ecological risk assessment of polycyclic aromatic hydrocarbons in water, suspended particulate matter and sediment from Daliao River Estuary and the adjacent area, China[J]. Chemosphere,2016,149:91-100. doi: 10.1016/j.chemosphere.2016.01.039
|
| [21] |
CHEN C F, JU Y R, SU Y C, et al. Distribution, sources, and behavior of PAHs in estuarine water systems exemplified by Salt River, Taiwan[J]. Marine Pollution Bulletin,2020,154:111029. doi: 10.1016/j.marpolbul.2020.111029
|
| [22] |
高晓奇, 王学霞, 汪浩, 等. 黄河三角洲丰水期上覆水中PAHs分布、来源及生态风险研究[J]. 生态环境学报,2017,26(5):831-836.
GAO X Q, WANG X X, WANG H, et al. Distribution, source and ecological risk assessment of polycyclic aromatic hydrocarbons in overlying water during flood seasons from the Yellow River Delta, China[J]. Ecology and Environmental Sciences,2017,26(5):831-836.
|
| [23] |
LIANG X X, JUNAID M, WANG Z F, et al. Spatiotemporal distribution, source apportionment and ecological risk assessment of PBDEs and PAHs in the Guanlan River from rapidly urbanizing areas of Shenzhen, China[J]. Environmental Pollution,2019,250:695-707. doi: 10.1016/j.envpol.2019.04.107
|
| [24] |
NA M L, ZHAO Y M, SU R N, et al. Residues, potential source and ecological risk assessment of polycyclic aromatic hydrocarbons (PAHs) in surface water of the East Liao River, Jilin Province, China[J]. Science of the Total Environment,2023,886:163977. doi: 10.1016/j.scitotenv.2023.163977
|
| [25] |
HUANG H F, XING X L, ZHANG Z Z, et al. Polycyclic aromatic hydrocarbons (PAHs) in multimedia environment of Heshan coal district, Guangxi: distribution, source diagnosis and health risk assessment[J]. Environmental Geochemistry and Health,2016,38(5):1169-1181. doi: 10.1007/s10653-015-9781-1
|
| [26] |
CHEN D, FENG Q Y, LIANG H Q, et al. Distribution characteristics and ecological risk assessment of polycyclic aromatic hydrocarbons (PAHs) in underground coal mining environment of Xuzhou[J]. Human and Ecological Risk Assessment,2019,25(6):1564-1578. doi: 10.1080/10807039.2018.1489715
|
| [27] |
贾天琪, 雷荣荣, 武小琳, 等. 长江下游支流水体中多环芳烃的分布及生态风险评估[J]. 环境科学,2020,41(5):2221-2228.
JIA T Q, LEI R R, WU X L, et al. Distribution, sources, and risk assessment of polycyclic aromatic hydrocarbons (PAHs) in tributary waters of the lower reaches of the Yangtze River, China[J]. Environmental Science,2020,41(5):2221-2228.
|
| [28] |
US EPA. National recommended water quality criteria[S/OL]. [2023-12-20]. http://www. epa.gov/ost/pc/revcom.pdf.
|
| [29] |
马赛炎, 魏海英, 马瑾, 等. 基于BP神经网络预测北京市加油站周边土壤多环芳烃含量[J]. 环境科学,2023,44(4):2215-2222.
MA S Y, WEI H Y, MA J, et al. Prediction of PAHs content in soil around gas stations in Beijing based on BP neural network[J]. Environmental Science,2023,44(4):2215-2222.
|
| [30] |
徐振鹏, 钱雅慧, 洪秀萍, 等. 淮北孙疃矿区地表尘中多环芳烃类化合物的污染特征及致癌风险评价[J]. 环境科学,2023,44(7):3809-3819.
XU Z P, QIAN Y H, HONG X P, et al. Contamination characteristics and risk assessment of polycyclic aromatic compounds in surface dust of Suntuan mining area in Huaibei[J]. Environmental Science,2023,44(7):3809-3819.
|
| [31] |
齐静文, 张瑞芹, 姜楠, 等. 洛阳市秋冬季PM2.5中多环芳烃的污染特征、来源解析及健康风险评价[J]. 环境科学,2021,42(2):595-603.
QI J W, ZHANG R Q, JIANG N, et al. Characterization, sources, and health risks of PM2.5-bound PAHs during autumn and winter in Luoyang City[J]. Environmental Science,2021,42(2):595-603.
|
| [32] |
RIAZ R, ALI U, LI J, et al. Assessing the level and sources of polycyclic aromatic hydrocarbons (PAHs) in soil and sediments along Jhelum riverine system of lesser Himalayan Region of Pakistan[J]. Chemosphere,2019,216:640-652. doi: 10.1016/j.chemosphere.2018.10.139
|
| [33] |
WU J, LI K K, MA D, et al. Contamination, source identification, and risk assessment of polycyclic aromatic hydrocarbons in agricultural soils around a typical coking plant in Shandong, China[J]. Human and Ecological Risk Assessment,2018,24(1):225-241. doi: 10.1080/10807039.2017.1377595
|
| [34] |
WANG F W, LIN T, FENG J L, et al. Source apportionment of polycyclic aromatic hydrocarbons in PM2.5 using positive matrix factorization modeling in Shanghai, China[J]. Environmental Science Processes & Impacts,2015,17(1):197-205.
|
| [35] |
ZHENG B H, MA Y Q, QIN Y W, et al. Distribution, sources, and risk assessment of polycyclic aromatic hydrocarbons (PAHs) in surface water in industrial affected areas of the Three Gorges Reservoir, China[J]. Environmental Science and Pollution Research,2016,23(23):23485-23495. doi: 10.1007/s11356-016-7524-1
|
| [36] |
LI R F, HUA P, ZHANG J, et al. Effect of anthropogenic activities on the occurrence of polycyclic aromatic hydrocarbons in aquatic suspended particulate matter: evidence from Rhine and Elbe Rivers[J]. Water Research,2020,179:115901. doi: 10.1016/j.watres.2020.115901
|
| [37] |
REN C B, ZHANG Q Q, WANG H W, et al. Characteristics and source apportionment of polycyclic aromatic hydrocarbons of groundwater in Hutuo River alluvial-pluvial fan, China, based on PMF model[J]. Environmental Science and Pollution Research International,2021,28(8):9647-9656. doi: 10.1007/s11356-020-11485-6
|
| [38] |
何卓识, 李超灿, 张靖天, 等. 受体模型在湖泊沉积物中PAHs、PFASs和OCPs源解析比较[J]. 环境工程技术学报,2018,8(3):231-240. doi: 10.3969/j.issn.1674-991X.2018.03.031
HE Z S, LI C C, ZHANG J T, et al. Analysis and comparison of PAHs, PFASs and OCPs sources in lake sediments by receptor model[J]. Journal of Environmental Engineering Technology,2018,8(3):231-240. ⊕ doi: 10.3969/j.issn.1674-991X.2018.03.031
|
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