Volume 7 Issue 3
May  2017
Turn off MathJax
Article Contents
YANG Dongyuan, HU Guangfa, QI Yonghong, WANG Yan, YAO Bin. Chlorine element migration in gasification process of oily sludge-coal water slurry[J]. Journal of Environmental Engineering Technology, 2017, 7(3): 318-322. doi: 10.3969/j.issn.1674-991X.2017.03.045
Citation: YANG Dongyuan, HU Guangfa, QI Yonghong, WANG Yan, YAO Bin. Chlorine element migration in gasification process of oily sludge-coal water slurry[J]. Journal of Environmental Engineering Technology, 2017, 7(3): 318-322. doi: 10.3969/j.issn.1674-991X.2017.03.045

Chlorine element migration in gasification process of oily sludge-coal water slurry

doi: 10.3969/j.issn.1674-991X.2017.03.045
More Information
  • Corresponding author: Guangfa HU E-mail: 286025013@qq.com
  • Received Date: 2016-08-22
  • Publish Date: 2017-05-20
  • Based on an analysis of the chemical composition and characteristics of oily sludge produced from Ordos basin oilfield and the gasification ash & ash water after mixing with coal water slurry, the chlorine migration in the gasification process of oily sludge-coal water slurry was studied. The results showed that the oily sludge mix ratio is 5% (wt) in the whole slurry, and the ash water composition is basically identical with common coal water slurry. The chlorine in oil sludge-coal water slurry is mainly migrated into ash water during gasification process, with little into the coarse slag and fine dregs. By gasification reaction the chlorine in oily sludge mainly transfers into hydrochloric acid, and no dioxins are formed in the gaseous phase.

     

  • loading
  • [1]
    李建柱, 李晓鸥, 封瑞江 , 等. 油泥及其处理工艺发展现状[J]. 炼油技术与工程, 2003,39(12):1-4.

    LI J Z, LI X O, FENG R J , et al. Oily sludge and the development of oily sludge treatment technologies[J]. Petroleum Refinery Engineering, 2003,39(12):1-4.
    [2]
    VASUDEVAN N, RAJARAM P . Bioremediation of oil sludge-contaminated soil[J]. Environment International, 2001,26(5/6):409-411.
    [3]
    MAKADIA T H, ADETUTU E M, SIMONS K L , et al. Re-use of remediated soils for the bioremediation of waste oil sludge[J]. Journal of Environmental Management, 2011,92(3):866-871.
    [4]
    LIU J, JIANG X, ZHOU L . Co-firing of oil sludge with coal-water slurry in an industrial internal circulating fluidized bed boiler[J]. Journal of Hazardous Materials, 2009,167(1/2/3):817-823.
    [5]
    朱虹, 杨跃兰, 汪九新 , 等. 油泥处理技术研究[J]. 油气田环境保护, 2010(3):27-31.

    ZHU H, YANG Y L, WANG J X , et al. A study on oily sludge (sand) treatment technology[J]. Environmental Protection of Oil & Gag Fields, 2010(3):27-31.
    [6]
    全翠, 李爱民, 高宁博 , 等. 采用热解方法回收油泥中原油[J]. 石油学报, 2010,26(5):742-746.

    QUAN C, LI A M, GAO N B , et al. Oil recovety from oily-sludge by pyrolysis method[J]. Acta Petrolei Sinica, 2010,26(5):742-746.
    [7]
    樊玉清, 王秀海, 洪波 , 等. 油田高含油泥砂提油-固化综合处理及利用[J]. 中国海洋大学学报, 2013,43(9):96-101.

    FAN Y Q, WANG X H, HONG B , et al. Comprehensive treatment and utilization technology of oil-extraction & solidization of high-oil-content sludge in the oil field[J]. Periodical of Ocean University of China, 2013,43(9):96-101.
    [8]
    李安 . 水煤浆技术发展现状及其新进展[J]. 煤炭科学技术, 2007,35(5):97-100.

    LI A . Development status and new development of coal water mixture technology[J]. Coal Science and Technology, 2007,35(5):97-100.
    [9]
    喻建, 韩永林, 凌升阶 . 鄂尔多斯盆地三叠系延长组油田成藏地质特征及油藏类型[J]. 中国石油勘探, 2001(4):13-19.
    [10]
    谢志海, 张旭, 赵莉 , 等. 延长油田油泥组分分析[J]. 应用化工, 2011,40(2):353-354.

    XIE Z H, ZHANG X, ZHAO L , et al. Study on the composition of oil sludge of Yanchang oilfield[J]. Applied Chemical Industry, 2011,40(2):353-354.
    [11]
    国家质量监督检验检疫总局, 国家标准化管理委员会. 煤中氯的测定方法:GB/T 3558—2014[S]. 北京: 中国标准出版社, 2014.
    [12]
    代正华, 胡敏, 李超 , 等. 气流床煤气化过程中氯元素的迁移特性[J]. 煤炭学报, 2014,38(11):2048-2053.

    DAI Z H, HU M, LI C , et al. Chlorine migration in entrained-flow coal gasification process[J]. Journal of China Coal Society, 2014,38(11):2048-2053.
    [13]
    徐旭, 蒋旭光 . 煤中氯的赋存形态与释放特性的研究进展[J]. 煤炭转化, 2001,24(2):1-5.

    XU X, JIANG X G . A review on existence and release of chlorine in coal[J]. Coal Conversion, 2001,24(2):1-5.
    [14]
    李震, 刘泽常, 赵莹 , 等. 煤在热解过程中氯的释放特性研究和煤中氯的吸附模型的建立[J]. 洁净煤技术, 2005,11(4):51-55.

    LI Z, LIU Z C, ZHAO Y , et al. Study on chlorine emission character in coal pyrolysis process and absorption model establishment of chlorine occurrence[J]. Clean Coal Technology, 2005,11(4):51-55.
    [15]
    凤海元, 苏庆平, 龙小玲 , 等. 煤中低氯的测定及其赋存形态研究[J]. 煤, 2010,19(1):32-33.

    FENG H Y, SU Q P, LONG X L , et al. The studies on the determination of low-chlorine content and its form in coal[J]. Coal, 2010,19(1):32-33.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Article Metrics

    Article Views(1054) PDF Downloads(963) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return