Analysis of ozone pollution characteristics and meteorological parameters in Nanyang City from 2015 to 2019
-
摘要:
基于2015—2019年南阳市5个国控空气质量监测站点常规污染六参数逐时观测资料,结合国家基准站南阳站地面气象要素数据,识别南阳市O3污染的时空分布特征及气象因素影响。结果表明:2015—2019年南阳市O3污染日趋严重,O3日最大8 h滑动浓度平均值(MDA8)从2015年的145 μg/m3增至2019年的181 μg/m3,增幅超过25%;O3污染呈显著季节性差异,峰值出现在夏季;从空间分布来看,O3污染呈现明显的块状分布特征,其高值出现在城区中部区域;气象要素是影响南阳市O3浓度的重要因子,高温、低湿和高能见度条件下易出现O3污染,且随着风速的增加,O3浓度表现出先升后降的趋势。2019年6月,南阳市O3污染严重,超标频率为63%,期间共经历3次O3污染过程,污染事件与不利的气象条件和强污染排放强度有关。
Abstract:Based on the hourly observation data of six conventional pollution parameters provided by five state-controlled environmental monitoring sites in Nanyang City from 2015 to 2019, and combined with the surface meteorological elements data of Nanyang Station, the national benchmark station, the temporal and spatial distribution characteristics of ozone pollution and the influence of meteorological factors were investigated. The results showed that the ozone pollution in Nanyang City became serious from 2015 to 2019, and the average daily maximum 8 h sliding concentration (MDA8) of O3 increased from 145 μg/m3 in 2015 to 181 μg/m3 in 2019, with an increase of more than 25%. O3 pollution displayed a distinct seasonality, where the maximum values occurred in summer. As for spatial distribution, the O3 pollution presented obvious block distribution characteristics, and its high value appeared in the central area of the city. Meteorological conditions were important factors affecting the concentration of O3 in Nanyang City. Under high temperature, low humidity and high visibility conditions, it was easy to form serious ozone pollution. With the increase of wind speed, the O3 concentration increased first and then decreased. In June 2019, the O3 pollution in Nanyang City was serious, and the O3 exceedance rate was more than 63%. During this period, there were three ozone pollution processes. The pollution events were related to favorable meteorological conditions and strong pollution emission intensity.
-
表 1 O3污染日和非污染日气象要素和污染物浓度统计
Table 1. Statistical results of meteorological elements and pollutant concentrations during clean days and O3 pollution days
项目 非污染日 污染日 温度/℃ 25.13±3.13 27.65±4.24 降水量/mm 71.8 3.1 气压/hPa 983.81±2.95 983.98±2.68 风速/(m/s) 2.61±1.49 2.66±1.53 相对湿度/% 70±17 53±19 能见度/km 15.40±9.17 16.78±8.39 O3浓度/(µg/m3) 105.12±32.75 130.03±49.67 NO2浓度/(µg/m3) 15.79±10.71 20.69±13.54 PM2.5浓度/(µg/m3) 22.36±10.94 30.96±9.96 PM10浓度/(µg/m3) 43.5±20.88 59.93±20.48 SO2浓度/(µg/m3) 5.11±1.6 6.08±1.84 CO浓度/(mg/m3) 0.69±0.13 0.68±0.15 -
[1] WU R S, SONG X M, CHEN D H, et al. Health benefit of air quality improvement in Guangzhou, China: results from a long time-series analysis (2006-2016)[J]. Environment International,2019,126:552-559. doi: 10.1016/j.envint.2019.02.064 [2] XIE Y, DAI H C, ZHANG Y X, et al. Comparison of health and economic impacts of PM2.5 and ozone pollution in China[J]. Environment International,2019,130:104881. doi: 10.1016/j.envint.2019.05.075 [3] DEBAJE S B. Estimated crop yield losses due to surface ozone exposure and economic damage in India[J]. Environmental Science and Pollution Research International,2014,21(12):7329-7338. doi: 10.1007/s11356-014-2657-6 [4] 李娜, 周涛, 刘小雪, 等.廊坊市臭氧污染特征及其与气象因素的关系[J]. 环境工程技术学报,2021,11(2):217-225. doi: 10.12153/j.issn.1674-991X.20200147LI N, ZHOU T, LIU X X, et al. Characteristics of ozone pollution and its relationship with meteorological factors in Langfang City[J]. Journal of Environmental Engineering Technology,2021,11(2):217-225. doi: 10.12153/j.issn.1674-991X.20200147 [5] YIN C Q, DENG X J, ZOU Y, et al. Trend analysis of surface ozone at suburban Guangzhou, China[J]. Science of the Total Environment,2019,695:133880. doi: 10.1016/j.scitotenv.2019.133880 [6] 孙国金, 朱绍东, 李优楠, 等.绍兴市臭氧污染特征及气象因素分析[J]. 环境污染与防治,2020,42(5):608-613.SUN G J, ZHU S D, LI Y N, et al. Analysis of ozone pollution characteristics and meteorological factors in Shaoxing[J]. Environmental Pollution & Control,2020,42(5):608-613. [7] 汪宇, 彭钰雯, 陈多宏, 等.珠三角城市近地面臭氧污染分布特征及变化趋势[J]. 环境污染与防治,2019,41(9):1103-1107.WANG Y, PENG Y W, CHEN D H, et al. Distribution and trends of ground level O3 pollution in the Pearl River Delta cities[J]. Environmental Pollution & Control,2019,41(9):1103-1107. [8] 刘芮伶, 李礼, 余家燕, 等.重庆市夏秋季VOCs对臭氧和二次有机气溶胶生成潜势的估算[J]. 环境科学研究,2017,30(8):1193-1200.LIU R L, LI L, YU J Y, et al. Estimation of the formation potential of ozone and secondary organic aerosols in summer and autumn in Chongqing[J]. Research of Environmental Sciences,2017,30(8):1193-1200. [9] 陈超, 严仁嫦, 叶辉, 等.杭州市臭氧污染特征研究[J]. 环境污染与防治,2019,41(3):339-342.CHEN C, YAN R C, YE H, et al. Research on the characteristics of ozone pollution in Hangzhou[J]. Environmental Pollution & Control,2019,41(3):339-342. [10] 沈劲, 陈皓, 钟流举.珠三角秋季臭氧污染来源解析[J]. 环境污染与防治,2015,37(1):25-30.SHEN J, CHEN H, ZHONG L J. Ozone source apportionment in the Pearl River Delta in autumn[J]. Environmental Pollution & Control,2015,37(1):25-30. [11] 杨显玉, 易家俊, 吕雅琼, 等.成都市及周边地区严重臭氧污染过程成因分析[J]. 中国环境科学,2020,40(5):2000-2009. doi: 10.3969/j.issn.1000-6923.2020.05.017YANG X Y, YI J J, LU Y Q, et al. Characteristics and formation mechanism of a severe O3 episode in Chengdu and surrounding areas[J]. China Environmental Science,2020,40(5):2000-2009. doi: 10.3969/j.issn.1000-6923.2020.05.017 [12] 程麟钧, 王帅, 宫正宇, 等.京津冀区域臭氧污染趋势及时空分布特征[J]. 中国环境监测,2017,33(1):14-21.CHENG L J, WANG S, GONG Z Y, et al. Pollution trends of ozone and its characteristics of temporal and spatial distribution in Beijing-Tianjin-Hebei region[J]. Environmental Monitoring in China,2017,33(1):14-21. [13] TANG G, LI X, WANG Y, et al. Surface ozone trend details and interpretations in Beijing, 2001–2006[J]. Atmospheric Chemistry and Physics,2009,9(22):8813-8823. doi: 10.5194/acp-9-8813-2009 [14] 严仁嫦, 叶辉, 林旭, 等.杭州市臭氧污染特征及影响因素分析[J]. 环境科学学报,2018,38(3):1128-1136.YAN R C, YE H, LIN X, et al. Characteristics and influence factors of ozone pollution in Hangzhou[J]. Acta Scientiae Circumstantiae,2018,38(3):1128-1136. [15] WANG T, WEI X L, DING A J, et al. Increasing surface ozone concentrations in the background atmosphere of Southern China, 1994-2007[J]. Atmospheric Chemistry and Physics,2009,9(16):6217-6227. doi: 10.5194/acp-9-6217-2009 [16] 曹庭伟, 吴锴, 康平, 等.成渝城市群臭氧污染特征及影响因素分析[J]. 环境科学学报,2018,38(4):1275-1284.CAO T W, WU K, KANG P, et al. Study on ozone pollution characteristics and meteorological cause of Chengdu-Chongqing urban agglomeration[J]. Acta Scientiae Circumstantiae,2018,38(4):1275-1284. [17] 齐艳杰, 于世杰, 杨健, 等.河南省臭氧污染特征与气象因子影响分析[J]. 环境科学,2020,41(2):587-599.QI Y J, YU S J, YANG J, et al. Analysis of characteristics and meteorological influence factors of ozone pollution in Henan Province[J]. Environmental Science,2020,41(2):587-599. [18] 吕瑞鹤, 张进生, 薛艳龙, 等.承德市臭氧污染特征及其与气象因子的相关性研究[J]. 南开大学学报(自然科学版),2020,53(6):85-91.LÜ R H, ZHANG J S, XUE Y L, et al. The relevance between the polluton characteristics of O3 and meteorological factors in Chengde[J]. Acta Scientiarum Naturalium Universitatis Nankaiensis,2020,53(6):85-91. [19] 杨健, 尹沙沙, 于世杰, 等.安阳市近地面臭氧污染特征及气象影响因素分析[J]. 环境科学,2020,41(1):115-124.YANG J, YIN S S, YU S J, et al. Characteristic of surface ozone and meteorological parameters analysis in Anyang City[J]. Environmental Science,2020,41(1):115-124. [20] 于世杰, 尹沙沙, 张瑞芹, 等.郑州市近地面臭氧污染特征及气象因素分析[J]. 中国环境监测,2017,33(4):140-149.YU S J, YIN S S, ZHANG R Q, et al. Analysis on the characteristics of surface ozone pollution and meteorological factors in Zhengzhou[J]. Environmental Monitoring in China,2017,33(4):140-149. [21] CHENG N L, LI R Y, XU C X, et al. Ground ozone variations at an urban and a rural station in Beijing from 2006 to 2017: trend, meteorological influences and formation regimes[J]. Journal of Cleaner Production,2019,235:11-20. doi: 10.1016/j.jclepro.2019.06.204 [22] ZOU Y, CHARLESWORTH E, YIN C Q, et al. The weekday/weekend ozone differences induced by the emissions change during summer and autumn in Guangzhou, China[J]. Atmospheric Environment,2019,199:114-126. doi: 10.1016/j.atmosenv.2018.11.019 [23] 阿多, 熊凯, 赵文吉, 等.1960—2013年华北平原气候变化时空特征及其对太阳活动和大气环境变化的响应[J]. 地理科学,2016,36(10):1555-1564.A D, XIONG K, ZHAO W J, et al. Temporal trend of climate change and mutation analysis of North China plain during 1960 to 2013[J]. Scientia Geographica Sinica,2016,36(10):1555-1564. [24] TANG W Y, ZHAO C S, GENG F H, et al. Study of ozone "weekend effect" in Shanghai[J]. Science in China Series D:Earth Sciences,2008,51(9):1354-1360. □ doi: 10.1007/s11430-008-0088-2