我国农药工业危险废物产生和污染特性研究

迭庆杞; 黄泽春; 杨玉飞; 黄启飞; 郝雅琼

doi:10.12153/j.issn.1674-991X.20210394

我国农药工业危险废物产生和污染特性研究

doi: 10.12153/j.issn.1674-991X.20210394

国家环境保护危险废物鉴别与风险控制重点实验室, 中国环境科学研究院

详细信息

作者简介:
迭庆杞(1988—),男,博士,主要从事固体废物环境风险评价研究,die. qingqi@craes.org.cn

通讯作者:
郝雅琼 E-mail: yqhao2010@aliyun.com

中图分类号: X705
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出版历程
- 收稿日期: 2021-08-11
- 刊出日期: 2021-11-20

Research on the generation and pollution characteristics of pesticide industrial hazardous wastes in China

State Environmental Protection Key Laboratory of Hazardous Waste Identification and Risk Control, Chinese Research Academy of Environmental Sciences

More Information

Corresponding author: HAO Yaqiong E-mail: yqhao2010@aliyun.com

摘要

摘要: 我国是农药的生产和使用大国,农药工业的危险废物因产量大、毒性强、处理处置困难等问题引起了公众和管理者的广泛关注。梳理和阐明农药工业危险废物的产生来源、污染特性及环境风险关键节点对于我国农药工业危险废物的管理具有重要的支撑作用。母液、废酸、废盐和污泥是农药工业中产生量最大的几类危险废物。农药工业危险废物中所含的污染物种类繁多,主要为残留的反应原料、副反应产物和农药有效成分。目前,农药工业副产物的利用环节是农药工业危险废物处理处置过程中环境风险的关键节点。针对农药工业危险废物利用处置过程中存在的问题,建议生态环境管理部门制定完善的污染控制标准,并采取针对性政策鼓励和引导企业研发先进工艺,开展源头减量,提高资源化利用水平,全面提升农药工业固体废物的环境风险防治水平。
- 农药工业 /
- 危险废物 /
- 污染特性 /
- 处理处置
Abstract: Pesticides are widely produced and used in China. The hazardous wastes of pesticide industry has attracted extensive attention of the public and managers due to its large output, high toxicity and difficulty in disposal. The combing and clarification of the generation sources, pollution characteristics, and environmental risk key nodes of hazardous wastes in pesticide industry plays an important supporting role in the management of hazardous wastes in pesticide industry in China. Mother liquor, waste acid, waste salt and sludge are several types of hazardous wastes with the largest production in pesticide industry. There are many kinds of pollutants contained in hazardous wastes of pesticide industry, mainly including reaction raw material residues, side reaction products and effective components of pesticide. At present, the key environmental risk in the treatment and disposal of pesticide hazardous wastes lies in the utilization of by-products of pesticide industry. In view of the problems existing in the process of utilization and disposal, it was suggested that the ecological environment management department formulate perfect pollution control standards, adopt targeted policies, encourage and guide enterprises to develop advanced processes, carry out source reduction, improve the level of resource utilization, and comprehensively improve the level of environmental risk prevention and control of solid wastes in pesticide industry.
- pesticide industry /
- hazardous waste /
- pollution characteristics /
- treatment and disposal

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参考文献(23)

[1]	褚福友. 清洁生产视角下农药企业污染防治精细化管理分析[J]. 中国资源综合利用, 2019, 37(8):164-166. CHU F Y. Analysis on fine management of pollution prevention and control of pesticide enterprises from the perspective of clean production[J]. China Resources Comprehensive Utilization, 2019, 37(8):164-166.
[2]	陈晓明, 王程龙, 薄瑞. 中国农药使用现状及对策建议[J]. 农药科学与管理, 2016, 37(2):4-8. CHEN X M, WANG C L, BO R. Current situation of Chinese pesticide application and policy suggestions[J]. Pesticide Science and Administration, 2016, 37(2):4-8.
[3]	SHA L, YU X Y, LIU X X, et al. Electro-dewatering pretreatment of sludge to improve the bio-drying process[J]. RSC Advances, 2019, 9(47):27190-27198. doi: 10.1039/C9RA02920F
[4]	LIN C Q, CHI Y, JIN Y Q, et al. Molten salt oxidation of organic hazardous waste with high salt content[J]. Waste Management & Research, 2018, 36(2):140-148.
[5]	GUPTA V K, GUPTA B, RASTOGI A, et al. Pesticides removal from waste water by activated carbon prepared from waste rubber tire[J]. Water Research, 2011, 45(13):4047-4055. doi: 10.1016/j.watres.2011.05.016
[6]	王韧. 我国农药行业清洁生产现状、存在的问题和建议[J]. 世界农药, 2016, 38(4):35-40. WANG R. Current situation,problems and suggestion of cleaning product in Chinese pesticide industry[J]. World Pesticides, 2016, 38(4):35-40.
[7]	GERECKE A C, SCHÄRER M, SINGER H P, et al. Sources of pesticides in surface waters in Switzerland:pesticide load through waste water treatment plants:current situation and reduction potential[J]. Chemosphere, 2002, 48(3):307-315. doi: 10.1016/S0045-6535(02)00080-2
[8]	LE T D H, SCHARMÜLLER A, KATTWINKEL M, et al. Contribution of waste water treatment plants to pesticide toxicity in agriculture catchments[J]. Ecotoxicology and Environmental Safety, 2017, 145:135-141. doi: 10.1016/j.ecoenv.2017.07.027
[9]	迮晓慧, 王娜, 苑文凯, 等. 农药草铵膦产污系数研究[J]. 农业环境科学学报, 2020, 39(2):437-444. ZE X H, WANG N, YUAN W K, et al. Study on pollutants producing coefficient of pesticide glufosinate[J]. Journal of Agro-Environment Science, 2020, 39(2):437-444.
[10]	XU X B, ZHANG Z Y, KUANG Y J, et al. Waste pesticide bottles disposal in rural China:policy constraints and smallholder farmers’ behavior[J]. Journal of Cleaner Production, 2021, 316:128385. doi: 10.1016/j.jclepro.2021.128385
[11]	张海滨, 张小宏, 范新华, 等. 采用膜技术资源化回收草甘膦母液废水研究[J]. 农药科学与管理, 2011, 32(2):31-34. ZHANG H B, ZHANG X H, FAN X H, et al. Resource utilization research of the glyphosate mother liquid by membrane technology[J]. Pesticide Science and Administration, 2011, 32(2):31-34.
[12]	杨成林, 王纯, 李博, 等. 农药副产稀盐酸的综合利用[J]. 中国石油和化工标准与质量, 2020, 40(13):171-172.
[13]	刘劭农, 陆宗盛. 草甘膦生产碱循环利用新工艺[J]. 江西化工, 2019(6):78-80. LIU S N, LU Z S. A new process for alkali recycling from glyphosate production[J]. Jiangxi Chemical Industry, 2019(6):78-80.
[14]	李唯实, 徐亚, 雷国元, 等. 典型农药废盐热处理特性及适用性[J]. 环境科学研究, 2018, 31(10):1779-1786. LI W S, XU Y, LEI G Y, et al. Thermal treatment characteristics and adaptability of typical pesticide waste salts[J]. Research of Environmental Sciences, 2018, 31(10):1779-1786.
[15]	郝雅琼, 刘宏博, 迭庆杞, 等. 农药行业废盐产生和利用处置现状及对策建议[J]. 环境工程, 2021,1-8.
[16]	陈志忠, 何小强. 3,5,6-三氯吡啶-2-醇钠的合成[J]. 农药, 2017, 56(10):718-720. CHEN Z Z, HE X Q. Synjournal of sodium 3,5,6-trichloropyridin-2-ol[J]. Agrochemicals, 2017, 56(10):718-720.
[17]	周玉花. 间苯二甲腈生产技术改进初探[J]. 山东化工, 2020, 49(6):107,111.
[18]	郝祥忠, 徐晓莉. 草甘膦生产废酸的循环利用[J]. 安徽化工, 2009, 35(5):57-58. HAO X Z, XU X L. Cycling utilization of the wasted acid from the producing of glyphosate[J]. Anhui Chemical Industry, 2009, 35(5):57-58.
[19]	LI W S, HUANG Z C, LIU Y Q, et al. Evaluation of low-medium temperature pretreatment on the removal efficiency of organic toxic pollutants from pesticide waste salts:characteristics,regularity,and key factors[J]. Journal of Cleaner Production, 2021, 316:128118. doi: 10.1016/j.jclepro.2021.128118
[20]	胡卫平, 贺周初, 朱文新, 等. 农药副产废盐渣的无害化处理及利用[J]. 精细化工中间体, 2013, 43(3):48-50. HU W P, HE Z C, ZHU W X, et al. Innocuous treatment and recycling of waste salts formed in pesticides production[J]. Fine Chemical Intermediates, 2013, 43(3):48-50.
[21]	林建, 薛晓康, 丁卯. 高效液相色谱法测定草甘膦副产盐渣中草甘膦和双甘膦[J]. 浙江农业科学, 2016, 57(1):116-118.
[22]	张玉皖, 王建龙. 固体草甘膦钾盐的醇析分离工艺研究[J]. 现代农药, 2019, 18(2):24-26. ZHANG Y W, WANG J L. Study on the seperation process for solid glyphosate potassium salt by alcohol precipitation[J]. Modern Agrochemicals, 2019, 18(2):24-26.
[23]	张宁, 吴贤斌, 宋文玲. 江苏省农药生产企业危险废物污染防治存在问题及对策建议[J]. 污染防治技术, 2018, 31(5):6-9.