Volume 8 Issue 1
Jan.  2018
Turn off MathJax
Article Contents
GUO Qiusong, LIU Zhiqiang, ZHU Wei, ZHANG Kuifang. Research on cobalt and vanadium leaching toxicity reduction of dumped sludge from heterogenite hydrometallurgy process[J]. Journal of Environmental Engineering Technology, 2018, 8(1): 98-103. doi: 10.3969/j.issn.1674-991X.2018.01.013
Citation: GUO Qiusong, LIU Zhiqiang, ZHU Wei, ZHANG Kuifang. Research on cobalt and vanadium leaching toxicity reduction of dumped sludge from heterogenite hydrometallurgy process[J]. Journal of Environmental Engineering Technology, 2018, 8(1): 98-103. doi: 10.3969/j.issn.1674-991X.2018.01.013

Research on cobalt and vanadium leaching toxicity reduction of dumped sludge from heterogenite hydrometallurgy process

doi: 10.3969/j.issn.1674-991X.2018.01.013
  • Received Date: 2017-07-12
  • Publish Date: 2018-01-20
  • In order to reduced cobalt and vanadium leaching toxicity of dumped sludge in heterogenite hydrometallurgy process, the electric-assistant acid leaching process was investigated. The influence of the electric-assistant acid leaching time, liquid-solid ratio, sulfuric acid concentration and electric current density on decreasing leaching toxicity was studied intensively. The results shows that under the condition of electric-assistant leaching time 120 min, sulfuric acid concentration 600 mg/L, liquid-solid ratio 10:1(mL/g) and electric current density 200 A/m 2, the leaching toxicity of heavy metals such as cobalt, vanadium, copper, manganese and nickel has reduced obviously. After treatment by horizontal vibration method and sulphuric acid and nitric acid method, the cobalt leaching toxicity decreased by 99.1% and 98.8%, while the vanadium leaching toxicity decreased by 91.7% and 95.1% respectively. Therefore, the leaching toxicity of dumped sludge from heterogenite hydrometallurgy process was reduced efficiently, and the valuable elements were recovered and utilized successfully.

     

  • loading
  • [1]
    UK Environment Agency . Guidance on the use of stabilization/solidification for the treatment of contaminatedsoil[M]. London:Environment Agency, 2004.
    [2]
    孙娜, 商和平, 茹淑华 , 等. 连续施用污泥堆肥土壤剖面中重金属积累迁移特征及对小麦吸收重金属的影响[J]. 环境科学, 2017,38(2):815-824.
    doi: 10.13227/j.hjkx.201608031

    SUN N, SHANG H P, RU S H , et al. Effects of continuous application of sewage sludge compost on heavy metals accumulation and mobility characteristics in soil profile and on heavy metals uptake of wheat[J]. Environmental Science, 2017,38(2):815-824. doi: 10.13227/j.hjkx.201608031
    [3]
    谷庆宝, 马福俊, 张倩 , 等. 污染场地固化/稳定化修复的评价方法与标准[J]. 环境科学研究, 2017,30(5):755-764.
    doi: 10.13198/j.issn.1001-6929.2017.01.94

    GU Q B, MA F J, ZHANG Q , et al. Remediation of contaminated sites by solidification/stabilization:testing and performance criteria[J]. Research of Environmental Sciences, 2017,30(5):755-764. doi: 10.13198/j.issn.1001-6929.2017.01.94
    [4]
    廖天鹏, 祝星, 祁先进 , 等. 铜污泥中重金属形态分布及浸出毒性分析[J]. 化工进展, 2014,33(3):762-768.
    doi: 10.3969/j.issn.1000-6613.2014.03.51

    LIAO T P, ZHU X, QI X J , et al. Chemical speciation of heavy metals and leaching toxicity analysis of sludge in copper metallurgy plant[J]. Chemical Industry and Engineering Progress, 2014,33(3):762-768. doi: 10.3969/j.issn.1000-6613.2014.03.51
    [5]
    TIPPING E , LOFTS S.Metal mixture toxicity to aquatic biota in laboratory experiments:application of the WHAM-FTOX model[J].Aquatic Toxicology, 2013, 142/143:114-122.
    doi: 10.1016/j.aquatox.2013.08.003 pmid: 23994673
    [6]
    李秋言, 赵秀兰 . 紫色水稻土颗粒有机质对重金属的富集特征[J]. 环境科学, 2017,38(5):2146-2153.
    doi: 10.13227/j.hjkx.201609143

    LI Q Y, ZHAO X L . Enrichment characteristics of heavy metals in particulate organic matter of purple paddy soil[J]. Environmental Science, 2017,38(5):2146-2153. doi: 10.13227/j.hjkx.201609143
    [7]
    SAFARZADEH M S, DHAWAN N, BIRINCI M , et al. Reductive leaching of cobalt from zinc plant purification residues[J]. Hydrometallurgy, 2011,106:51-57.
    doi: 10.1016/j.hydromet.2010.11.017
    [8]
    LUTANDULA M S, MALOBA B . Recovery of cobalt and copper through reprocessing of tailings from flotation of oxidised ores[J].Journal of Environmental Chemical Engineering,2013(1):1085-1090.
    doi: 10.1016/j.jece.2013.08.025
    [9]
    APUA M C ,MULABA-BAFUBIANDI A F.Dissolution of oxidised Co-Cu ores using hydrochloric acid in the presence of ferrous chloride[J]. Hydrometallurgy, 2011,108:233-236.
    doi: 10.1016/j.hydromet.2011.04.012
    [10]
    刘俊, 李林艳, 徐盛明 , 等. 还原酸浸法从低品位水钴矿中提取铜和钴[J]. 中国有色金属学报, 2012,22(1):304-309.

    LIU J, LI L Y, XU S M , et al. Recovery of copper and cobalt from low-grade heterogenite with reductive acid leaching method[J]. The Chinese Journal of Nonferrous Metals, 2012,22(1):304-309.
    [11]
    郭秋松, 朱薇, 刘志强 .刚果 ( 金)水钴矿高压酸浸实验研究[J]. 矿冶工程, 2015,35(5):107-109.

    GUO Q S, ZHU W, LIU Z Q . Test of high-pressure acid leaching of Congo(Kinshasa) heterogenite[J]. Mining and Metallurgical Engineering, 2015,35(5):107-109.
    [12]
    马文强, 徐盛明, 李林艳 , 等. 用Lix984萃取分离水钴矿浸出液中的铜钴[J]. 矿物学报, 2011,31(3):560-565.

    MA W Q, XU S M, LI L Y , et al. Extractive separation of copper and cobalt from acid leaching solution of heterogenite by using Lix984[J]. Acta Mineralogica Sinica, 2011,31(3):560-565.
    [13]
    刘建华, 张焕然, 王瑞祥 , 等. 氨法加压浸出钴铜氧化矿工艺[J]. 稀有金属, 2012,36(1):149-153.
    doi: 10.3969/j.issn.0258-7076.2012.01.026

    LIU J H, ZHANG H R, WANG R X , et al. Process of ammonium leaching oxidation ore of cobalt and copper at high pressure[J]. The Chinese Journal of Rare Metals, 2012,36(1):149-153. doi: 10.3969/j.issn.0258-7076.2012.01.026
    [14]
    郭学益, 姚标, 李晓静 , 等. 水钴矿中选择性提取铜和钴的新工艺[J]. 中国有色金属学报, 2012,22(6):1778-1784.

    GUO X Y, YAO B, LI X J , et al. Novel process of selective extraction of copper and cobalt from heterogenite[J]. The Chinese Journal of Nonferrous Metals, 2012,22(6):1778-1784.
    [15]
    钱力, 张超, 齐鹏 , 等. 永康城市土壤重金属污染评价及来源分析[J]. 浙江农林大学学报, 2016,33(3):427-433.

    QIAN L, ZHANG C, QI P , et al. Sourcing and evaluating heavy metal pollution in the urban topsoil of Yongkang City[J]. Journal of Zhejiang A & F University, 2016,33(3):427-433.
    [16]
    固体废物浸出毒性浸出方法水平振荡法:HJ/T 557—2010[S] 北京:中国环境科学出版社, 2010.
    [17]
    固体废物浸出毒性浸出方法硫酸硝酸法:HJ/T 299—2007[S] 体废物浸出毒性浸出方法硫酸硝酸法: HJ/T 299—2007[S].北京:中国环境科学出版社, 2007.
    [18]
    王蓉, 陈梦君, 黄金秀 , 等. 电动力学技术回收废旧印刷线路板中的铜[J]. 中南大学学报(自然科学版), 2016,47(4):1436-1440.

    WANG R, CHEN M J, HUANG J X , et al. Copper recycling from waste printed circuit boards by electrokinetics[J]. Journal of Central South University(Science and Technology), 2016,47(4):1436-1440.
  • 加载中

Catalog

    通讯作者: 陈斌, bchen63@163.com
    • 1. 

      沈阳化工大学材料科学与工程学院 沈阳 110142

    1. 本站搜索
    2. 百度学术搜索
    3. 万方数据库搜索
    4. CNKI搜索

    Article Metrics

    Article Views(773) PDF Downloads(405) Cited by()
    Proportional views
    Related

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return