CO2催化转化催化剂研究现状

Research status on catalyst of CO2 catalytic conversion

  • 摘要: 将CO2通过催化反应转化为甲烷、甲醇、一氧化碳、甲酸、低碳烯烃和芳香烃等有价值化工原料是实现碳达峰和碳中和的重要手段。催化剂是转化过程的决定因素之一,开发高转化率和高选择性的催化剂仍是当前CO2催化转化研究的重点内容。目前,采用的催化剂主要为贵金属催化剂和部分过渡态金属催化剂,同时部分非金属催化剂、新型催化剂和本体催化剂也具有良好的催化活性。转化产物分子结构的复杂化和非均相化程度越高,则CO2催化转化的转化率和选择性越低。催化反应以热催化和光催化为主,反应条件的差异导致不同催化剂的性能可比性较差。因此,除开发高效催化剂外,建立规范化的CO2催化转化评价方法也是未来研究的重点。

     

    Abstract: The catalytic conversion of CO2 to valuable chemical materials such as methane, methanol, carbon monoxide, methanoic acid, light olefins, arene, and so on is an important way for the carbon peak and carbon neutrality. Catalyst is one of the decisive factors in the conversion process, so the development of new catalysts with high conversion rate and selectivity is still the focus of CO2 catalytic conversion research. The catalysts currently used are mainly noble metal catalysts, with some parts being transition metal catalysts. Moreover, some nonmetal catalysts, new catalysts and bulk catalysts are also proven to have good catalytic performance. With the complexity and heterogeneity of converted products increasing, the conversion rate and selectivity of CO2 catalytic conversion turns lower. The catalytic reaction mainly contains thermocatalytic and photocatalytic, and the differences of catalytic conditions lead to the poor comparability of the performance of different kinds of catalysts. As a result, establishing standardized evaluation methods for CO2 catalytic conversion will also be the key research area besides developing high-performance catalysts.

     

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