气溶胶吸湿性的影响因素及其对光学特性的影响

Factors influencing the hygroscopicity of aerosols and the effects of hygroscopicity on aerosol optical properties

  • 摘要: 吸湿性是气溶胶重要的理化性质之一,气溶胶吸湿增长不仅会通过大气辐射效应影响气候,还对大气能见度有重要影响。介绍了气溶胶粒径吸湿增长与散射吸湿增长的概念,总结了测量气溶胶吸湿增长的方法,分析了粒径、化学组分、污染条件和混合状态对吸湿性的影响。结果表明:气溶胶的吸湿增长会使颗粒物含水量增多,改变气溶胶消光能力,从而对大气能见度以及气溶胶辐射强迫造成影响。未来,建议着重关注高相对湿度(相对湿度大于95%)下的气溶胶吸湿增长,加强气溶胶吸湿增长的垂直观测研究,并广泛开展吸湿和脱水2种环境下的气溶胶散射吸湿增长的测量和研究。

     

    Abstract: The hygroscopicity is one of the important physicochemical properties of aerosols, which not only affects the climate through atmospheric radiation effects, but also has an important impact on atmospheric visibility. The concepts of aerosol particle size hygroscopic growth and scattered hygroscopic growth were introduced, the methods for measuring aerosol hygroscopic growth were summarized and the effects of particle size, chemical compositions, pollution conditions and mixing state on hygroscopicity were analyzed. It was found that the hygroscopic growth of aerosols could increase the water content of particles and affect the aerosol extinction capacity, thus affecting atmospheric visibility and aerosol radiative forcing. In the future, it was recommended to focus on aerosol hygroscopic growth at high relative humidity (>95%), strengthen vertical observation research on aerosol hygroscopic growth, and widely carry out the measurement and research on aerosol scattering hygroscopic growth under both hygroscopic and dehydrated conditions.

     

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