不同封闭时间油井沉积物PAHs污染特征及来源解析

Characteristics and source analysis of PAHs pollution in sediments of oil wells with different closure times

  • 摘要: 为评估黄河三角洲北部滨海滩涂湿地油井封闭清退区的生态环境状况,比较油井封闭时间不同的区域间修复成效差异,选择分别于2002年、2012年和2018年封闭的油井清退区,分析表层沉积物中多环芳烃(PAHs)的污染特征,用特征比值法和正定矩阵因子分解(PMF)解析来源,用毒性当量因子评价法(TEQ)和平均效应区间中值商法(M-ERM-Q)评价生态风险。结果表明:总体沉积物ΣPAHs平均含量为791.691 ng/g,为中度污染,以4~5环为主,2002年、2012年和2018年沉积物中ΣPAHs平均含量分别为587.29、135.36、1 652.41 ng/g,分别为轻度污染、未污染和重度污染,主要环数分别为4~5环、2环和4~5环;总体沉积物PAHs主要受到石油泄漏影响,以汽车排放、薪材燃烧和煤炭燃烧的影响为辅,2002年和2012年的主要来源均含有石油泄漏、汽车排放、煤炭燃烧,2002年还有薪材燃烧,2018年由薪材燃烧和汽车排放组成;总体沉积物ΣPAHs的TEQ平均值为193.53 ng/g,在环境和人体健康的安全范围内,不同年份沉积物ΣPAHs的M-ERM-Q平均值均小于0.1,生态风险较低,但2018年封闭区的个别点位有30%概率产生毒性。油井封闭清退区沉积物的修复成效总体较好,但个别点位存在高污染水平、较高毒性概率的情况,需要开展进一步的调查研究和生态修复。

     

    Abstract: To evaluate the ecological environment of the closed clearance area in the coastal wetland of the northern part of the Yellow River Delta and compare the ecological environment effect between areas with different oil well closure times, oil well clearance areas respectively closed in 2002, 2012 and 2018 were selected. The pollution characteristics of polycyclic aromatic hydrocarbons (PAHs) in surface sediments were analyzed, the sources were analyzed by characteristic ratio method and positive matrix factorization (PMF), and the ecological risk was evaluated by toxic equivalent quantity (TEQ) and mean effects range median (M-ERM-Q) methods. The results showed that the average content in total sediments ΣPAHs was 791.691 ng/g, which was moderately polluted and mainly with 4 to 5 rings. The average content of ΣPAHs in the sediments in 2002, 2012 and 2018 were 587.29, 135.36 and 1 652.41 ng/g, respectively, which were slightly polluted, unpolluted and severely polluted, and the main number of rings were 4-5, 2 and 4-5 rings, respectively. The total sediments PAHs were mainly affected by the oil spill, supplemented by the effects of vehicle emissions, fuelwood, and coal combustion. The main sources in 2002 and 2012 included oil leaks, vehicle emissions, and coal combustion, and in 2002 they also included fuelwood burning. In 2018, the sources included fuel wood combustion and vehicle emissions. The average TEQ of total sediments ΣPAHs was 193.53 ng/g, which fell within the safety range of environmental and human health. The average M-ERM-Q of sediments ΣPAHs in different years was less than 0.1, with low ecological risk, but there was a 30% probability of toxicity at individual points in the closed area in 2018. The restoration effect of sediments in the oil well clearance areas was generally good, but the individual points had high pollution and high probability of toxicity, so further research and ecological restoration were needed.

     

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