基于油井不同封闭时间沉积物中PAHs污染特征及来源解析

Characteristics and source analysis of PAHs pollution in sediments based on different closing times of oil well

  • 摘要: 为评估黄河三角洲北部滨海滩涂湿地油井封闭清退区的生态环境状况,比较油井封闭时间不同的区域间修复成效差异,选择分别于2002年、2012年和2018年封闭的油井清退区,分析表层沉积物中多环芳烃(PAHs)的污染特征,用特征比值法和正定矩阵因子分解(PMF)解析来源,用毒性当量因子评价法(TEQ)和平均效应区间中值商法(M-ERM-Q)评价生态风险。结果表明:总体沉积物ΣPAHs平均含量为791.691 ng/g,为中度污染,以4~5环为主,2002年、2012年和2018年沉积物中ΣPAHs平均含量分别为587.29、135.36、1 652.41 ng/g,分别为轻度污染、未污染和重度污染,主要环数分别为4~5环、2环和4~5环;总体沉积物PAHs主要受到石油泄漏影响,以汽车排放、薪材燃烧和煤炭燃烧的影响为辅,2002年和2012年的主要来源均含有石油泄漏、汽车排放、煤炭燃烧,2002年还有薪材燃烧,2018年由薪材燃烧和汽车排放组成;总体沉积物ΣPAHs的TEQ平均值为193.53 ng/g,在环境和人体健康的安全范围内,不同年份沉积物ΣPAHs的M-ERM-Q平均值均小于0.1,生态风险较低,但2018年封闭区的个别点位有30%概率产生毒性。油井封闭清退区沉积物的修复成效总体较好,但个别点位存在高污染水平、较低生态风险的情况,需要开展进一步的调查研究和生态修复工程。

     

    Abstract: In order to evaluate the ecological environment of the oil well closed clearance area in the coastal wetland of the northern part of the Yellow River Delta and compare the ecological environment effect between area at different closing times, the oil well clearance areas that closed in 2002, 2012 and 2018 were selected. The pollution characteristics of polycyclic aromatic hydrocarbons (PAHs) in surface sediments were analyzed, the source was analyzed by characteristic ratio method and positive matrix factorization (PMF), and the ecological risk was evaluated by toxic equivalent quantity (TEQ) and mean effects range median (M-ERM-Q) methods. The results show that the average content in total sediments ΣPAHs is 791.691 ng/g, which is moderately polluted, mainly with 4 to 5 rings. The average content of ΣPAHs in the sediments in 2002, 2012 and 2018 are 587.29, 135.36 and 1 652.41 ng/g respectively, which are slightly polluted, unpolluted and severely polluted, and the main number of rings are 4~5,2 and 4~5 rings respectively. Total sediments PAHs are mainly affected by the oil spill, supplemented by the effects of vehicle emissions, sall, and coal combustion. The main sources in 2002 and 2012 contains oil leaks, vehicle emissions, coal combustion, and 2002 contains fuelwood burning, and in 2018 contains fuel wood combustion and vehicle emissions. The average TEQ of total sediments ΣPAHs is 193.53 ng/g, which falls within the safety range of environmental and human health. The average M-ERM-Q of sediments ΣPAHs in different years are less than 0.1, with low ecological risk, but there is a 30% probability of toxicity at individual points in the closed area in 2018. The restoration effect of the closed well was generally good, but the individual points had high pollution and low ecological risk, so further researches and ecological restoration projects were needed.

     

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