污染土壤的危险废物属性鉴别技术要点解析

Analysis of key technical points for hazardous waste identification of contaminated soil

  • 摘要: 污染土壤的危险废物鉴别是危险废物鉴别环境管理中的特别情形。分析各级危险废物鉴别专家委员会发布的工作简报发现,部分鉴别单位未充分理解HJ 298—2019《危险废物鉴别技术规范》中污染土壤危险废物鉴别相关技术要求,导致污染土壤危险废物鉴别报告技术问题突出、异议率较高,鉴别结论准确性和科学性存疑。因此,对照危险废物鉴别相关规范和标准,系统分析全国危险废物鉴别信息公开服务平台公示的污染土壤危险废物鉴别报告案例,针对污染土壤危险废物鉴别过程中关键技术要点进行解析。结果表明:检测因子筛选过程要充分利用土壤污染状况调查和风险评估阶段掌握信息分析特征污染物,全面识别危险特性;毒性物质的选择需关注污染物的来源和土壤的特性,排除不可能存在的物质;采样过程应按土壤污染程度分区布点,高污染区域单独鉴别,低污染区域合理划分采样单元;超标区域划定过程以无超标点位连线法为基础,结合黄金分割加密布点,科学缩减超标范围。

     

    Abstract: Hazardous waste identification of contaminated soil is a special case within the framework of environmental management of hazardous waste identification. An analysis of work briefings released by hazardous waste identification expert committees at all levels revealed that some identification institutions do not fully understand the technical requirements for identifying hazardous wastes in contaminated soil stipulated by Technical Specifications on Identification for Hazardous Waste (HJ 298-2019). This deficiency has resulted in prominent technical shortcomings in identification reports, a high dispute rate, and questionable accuracy and scientific rigor of the identification outcomes. With reference to the relevant norms and standards for hazardous waste identification, the study systematically analyzed the cases of hazardous waste identification reports of contaminated soil publicly disclosed on the National Hazardous Waste Identification Information Disclosure Service Platform. Then, the key technical points in hazardous waste identification in contaminated soil were analyzed. The results show that in the process of screening detection factors, it is necessary to fully utilize the available information from the stages of soil pollution status investigation and risk assessment to analyze characteristic pollutants and comprehensively identify the hazardous properties. The screening of toxic substances should focus on the sources of contaminants and soil characteristics, excluding substances that are unlikely to be present. The sampling process should employ zoning according to the degree of soil pollution, with heavily polluted areas identified separately and lightly polluted areas divided into reasonable sampling units. The delineation of exceedance areas should be based on the non-exceedance point connection method, supplemented by dense sampling points based on the golden-section method to scientifically reduce the extent of exceedance.

     

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