修复后农药场地有机污染物空间分布与迁移驱动机制

Spatial distribution and migration driving mechanisms of organic pollutants at pesticide sites after remediation

  • 摘要: 针对修复后农药场地残留污染物稳定性对二次利用的潜在影响,基于江苏省某典型修复后农药生产场地的检测数据,系统分析土壤有机污染物的空间分布特征及主控环境因子。通过采集0~13 m深度90个土壤样品,检测138种有机污染物,揭示土壤中有机污染物的水平和垂直分布特征,结合主成分分析(PCA)探究污染物垂向迁移规律与土壤理化参数的耦合关系。结果表明,酚类和胺类在特定区域残留显著,轻质非水相液体(LNAPLs)因毛细作用富集于0~3 m浅层粉砂粒主导区域,与粉砂粒占比呈正相关;重质非水相液体(DNAPLs)受重力驱动向深层迁移,在3~6 m碱性(pH为7.0~10.5)、低黏粒(11%)土壤中穿透能力增强,浓度极值达243.9 mg/kg。驱动因素分析表明,浅层LNAPLs受粉砂粒毛细阻滞控制,深层则与黏粒吸附相关;DNAPLs在浅层受pH调控,深层则受含水率影响。尽管修复工程有效降低了污染水平,但深层DNAPLs的持续迁移及局部高浓度聚集仍存在二次释放风险。建议针对不同深度污染特征优化监测与修复策略,重点关注深层DNAPLs的长期迁移动态,为修复后场地安全再利用提供理论依据。

     

    Abstract: To assess the potential impact of the stability of residual pollutants in the restored pesticide site on secondary utilization, this study systematically analyzes the spatial distribution characteristics and key controlling environmental factors of soil organic pollutants, based on the detection data of a typical restored pesticide production site in Jiangsu Province. A total of 90 soil samples from depths of 0-13 m were analyzed for 138 organic pollutants to reveal the horizontal and vertical distribution characteristics of organic pollutants in the soil. Principal component analysis (PCA) was further employed to explore the vertical migration law of pollutants and their coupling relationship with soil physicochemical parameters. The results showed that phenols (Phes) and amines (Ams) remained significantly in specific areas, while light non-aqueous phase liquids (LNAPLs) were enriched in the dominant area of 0-3 m shallow silt particles due to capillary action, and positively correlated with the proportion of silt particles. Heavy non-aqueous phase liquids (DNAPLs) migrated towards deeper layers driven by gravity, and their penetration was enhanced in 3-6 m alkaline (pH 7.0-10.5) and low clay (11%) soils, with a peak concentration of 243.9 mg/kg. The analysis of the main controlling factors showed that shallow LNAPLs were controlled by capillary entrapment of fine sand particles, while deep LNAPLs were related to the adsorption of clay particles. DNAPLs were regulated by pH in shallow layers and affected by moisture content in deep layers. Although remediation projects had effectively reduced pollution levels, there was still a risk of secondary release due to the continuous migration and local high concentration aggregation of deep DNAPLs. It was recommended to optimize monitoring and remediation strategies according to the depth-specific pollution characteristics, with a focus on the long-term dynamics of deep DNAPLs, to provide a theoretical basis for the safe reuse of the site after remediation.

     

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