基于全生命周期与土壤碳库的污染修复技术碳足迹比较与优化

Carbon footprint comparison and optimization of pollution remediation technologies based on life cycle and soil carbon pool

  • 摘要: 各类土壤修复技术在降低土壤环境风险的同时,也伴随显著的能源消耗和温室气体排放。基于荟萃分析并结合部分实测数据,定量评估了主流土壤修复技术全生命周期的碳排放特征,并探讨了修复过程中土壤有机碳(SOC)库变化对碳排放的贡献。结果表明:以高温高能耗为主的水泥窑协同处置、挖掘填埋、土壤气相抽提和热脱附技术的碳排放量最大,为207.85~270.64 kg/m3(以CO2当量计,全文同),而在最不利情景下排放可达1436 kg/m3;微生物和植物修复技术的平均碳排放量分别为44.69和39.17 kg/m3,部分情景下甚至低于3 kg/m3,凸显其低碳生态修复的优势。其他修复技术(化学淋洗、固化稳定化等)的平均碳排放量介于64.42~175.19 kg/m3。此外,修复过程中SOC的变化亦受不同类型技术的影响,水泥窑协同处置、热脱附、电动修复技术以及化学氧化还原修复技术对SOC含量均具有显著负效应(P<0.05),而土壤淋洗、微生物修复以及固化稳定化技术对SOC含量具有显著正效应(P<0.05),变化率分别为18.2%、35.5%和54.1%。本研究首次将SOC库动态纳入土壤污染修复技术的全生命周期评估框架,系统揭示了不同土壤修复技术的碳排放特征及其减排潜力。结果支持在修复技术选择与优化中同步纳入温室气体减排指标,以兼顾污染治理与气候协同效益,为相关政策制定与工程实践提供了量化依据。

     

    Abstract: While various soil remediation technologies effectively mitigate environmental risks, they also incur substantial energy consumption and greenhouse gas (GHG) emissions. In this study, we performed a meta-analysis complemented by field-measured data to quantify the life-cycle carbon emissions of prevailing soil remediation technologies, and then evaluated the contribution of soil organic carbon (SOC) stock variations during remediation to GHG emissions. The results demonstrate that high-temperature, energy-intensive technologies–namely cement-kiln co-disposal, excavation and landfill, soil vapor extraction, and thermal desorption–exhibit the highest carbon emissions, averaging 207.85-270.64 kg/m3 and reaching up to 1436 kg/m3 under worst-case scenarios. In contrast, microbial and phytoremediation technologies demonstrate markedly lower average emissions of 44.69 and 39.17 kg/m3, respectively, and in some cases, even below 3 kg/m3, highlighting their low-carbon and environmentally sustainable nature. Intermediate technologies (e.g., chemical leaching and solidification/stabilization) produce average carbon emissions in the range of 64.42-175.19 kg/m3. Additionally, changes in SOC during remediation are influenced by different technological approaches. Cement-kiln co-disposal, thermal desorption, electro-remediation, and chemical redox remediation all exhibit significant negative effects on SOC content (P<0.05), while soil washing, microbial remediation, and solidification/stabilization technologies exert significant positive effects on SOC content (P<0.05), with change rates of 18.2%, 35.5%, and 54.1%, respectively. This work pioneers the incorporation of SOC dynamics into the life cycle assessment (LCA) framework for contaminated soil remediation, systematically unraveling the emission profiles and decarbonization potentials of different soil remediation technologies. These findings advocate integrating GHG reduction metrics into technology selection and optimization processes, harmonizing pollution control with climate co-benefits, thereby providing quantitative support for policy formulation and engineering practice.

     

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