含油污泥热解产物资源化路径与碳减排潜力

Resource recovery pathways and carbon reduction potential of pyrolysis products from oily sludge

  • 摘要: 含油污泥是石油开采、储运和炼制过程中产生的典型危险废物,具有高含水率、黏性强和成分复杂等特征,处置不当易造成严重的环境与生态风险。随着“双碳”目标的推进,含油污泥的资源化与低碳化处理成为固体废物管理领域的重要研究方向。系统综述了近年来含油污泥主要资源化处理技术的研究进展,包括热解技术、溶剂萃取技术、调质-机械分离技术、超声技术和热化学清洗技术。热解技术具备资源回收、能源转化和碳减排潜力,是实现含油污泥高值化利用的关键途径。通过催化热解、共热解及微波热解等工艺改进,可显著提升产物品质与能源转化效率。进一步比较发现,热解炭在土壤改良与碳封存方面具有持久减排效益,热解油与热解气则在替代化石燃料和清洁能源利用方面展现出良好应用前景。但含油污泥热解碳减排研究仍处于初始阶段,在碳足迹量化、环境风险评估及工业化应用等方面仍存在不足。未来应加强热解过程的生命周期评价与多技术耦合研究,构建含油污泥资源化与碳减排的系统评估框架,为实现石油行业绿色低碳转型提供科学支撑。

     

    Abstract: Oily sludge is a typical hazardous waste generated in the processes of petroleum extraction, storage, transportation, and refining. It is characterized by high water content, strong viscosity, and complex composition, and its improper disposal may lead to serious environmental and ecological risks. With the advancement of the dual-carbon strategy, the resource recovery and low carbon treatment of oily sludge have become important research directions in the field of solid waste management. This article systematically reviews the research progress of major resource recovery technologies for oily sludge in recent years, including methods such as pyrolysis, solvent extraction, conditioning-mechanical separation, ultrasonic treatment, and thermochemical cleaning. Pyrolysis technology has the potential for resource recovery, energy conversion, and carbon emission reduction, and represents a key approach for the high-value utilization of oily sludge. Through improvements such as catalytic pyrolysis, co-pyrolysis, and microwave pyrolysis, the quality of the products and the energy conversion efficiency can be significantly enhanced. Comparative analysis further indicates that pyrolysis char has long-lasting emission reduction benefits in soil improvement and carbon sequestration, while pyrolysis oil and pyrolysis gas show promising potential for replacing fossil fuels in clean energy applications. Research on carbon emission reduction through pyrolysis of oily sludge is still in its initial stage, with deficiencies remaining in carbon footprint quantification, environmental risk assessment, and industrial-scale application. Future efforts should focus on strengthening the life cycle assessment of the pyrolysis process and research on multi-technology coupling, and establishing a systematic evaluation framework for the resource recovery of oily sludge and carbon emission reduction, thereby providing scientific support for achieving a green and low-carbon transformation of the petroleum industry.

     

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