生物炭基材料强化生态处理工艺效能的作用机制与研究进展

Mechanism and research progress of biochar-based materials to enhance the efficiency of ecological treatment processes

  • 摘要: 生物炭因其发达的孔隙结构、丰富的表面官能团以及良好的经济性,成为提升生态处理工艺效能的热点材料。基于文献计量学方法,系统分析了2015—2024年Web of Science核心数据库中生物炭应用于生态处理工艺的研究进展。通过对人工湿地、生物滤池及生态沟渠等典型工艺的相关文献进行梳理,总结了生物炭对常规污染物(化学需氧量、氮、磷)、重金属及新污染物的强化去除效能,并探讨了生物炭基材料在生态处理工艺中通过吸附、催化、离子交换等物化作用与微生物群落调控的生物作用所形成的协同净化机制。结果表明:近10年来该领域发文量呈持续增长态势,当前研究焦点集中于生物炭在人工湿地和生物滤池中的应用,而在生态沟渠中的应用研究相对薄弱;研究内容通过以生物炭改性及与其他填料的复配为核心强化生态处理工艺的效能。对已有文献数据的定量分析显示,相较于传统基质,生物炭的投加对化学需氧量、总氮、总磷去除率的中值提升幅度均超过10个百分点,对氨氮的去除提升较为有限(中值增幅为4.46~7.80个百分点),对多种重金属的去除率提升幅度介于6.11~22.70个百分点。其主要依靠生物炭自身的吸附机制和生物炭对植物和微生物调控作用,使得生态处理工艺的效能提高。最后,针对当前面临的关键挑战,包括新污染物归趋机制不明、基质界面行为与复合污染物协同机制不清、系统长效运行与低温适应性不足,以及工程化应用瓶颈等方面,对未来研究方向进行了展望。

     

    Abstract: Biochar has become a prominent material to improve the efficiency of ecological treatment processes due to its well-developed pore structure, abundant surface functional groups and cost-effectiveness. Employing the bibliometric method, this study systematically analyzes the research progress of biochar application in ecological treatment processes based on Web of Science core database from 2015 to 2024. By reviewing the literature on typical processes such as constructed wetlands, biofilters and ecological ditches, the enhanced removal efficiency of conventional pollutants (chemical oxygen demand, nitrogen, phosphorus), heavy metals, and emerging pollutants by biochar is summarized. Furthermore, the synergistic purification mechanism of biochar-based materials in ecological treatment processes through physicochemical effects such as adsorption, catalysis, and ion exchange, combined with biological effects of microbial community regulation, is discussed. The results show that the number of research papers in this field has been increasing in the past 10 years. The current research focuses on the application of biochar in constructed wetlands and biofilters, while the application research in ecological ditches is relatively weak. The research content focuses on enhancing the efficiency of ecological treatment processes by using biochar modification and compounding with other fillers as the core. The quantitative analysis of the existing literature data shows that, compared with the traditional substrates, the median removal rates of chemical oxygen demand, total nitrogen and total phosphorus are increased by more than 10%. The enhancement in ammonia nitrogen removal is relatively limited (median increase: 4.46%-7.80%), while the removal rate of various heavy metals is increased by 6.11%-22.70%. These improvements are primarily attributed to the adsorption mechanism of biochar itself and its regulatory effects on plants and microorganisms, thereby boosting the efficiency of ecological treatment processes. Finally, the study discusses key challenges and future research directions, including the unclear mechanisms governing the fate of emerging pollutants, insufficient understanding of the interactions at substrate interfaces with compound pollutants, the lack of long-term operation and low temperature adaptability of systems, and practical engineering applications.

     

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