引黄灌区补水湖泊夏季pH分布特征及影响因素——以阅海为例

Distribution characteristics and influencing factors of summer pH levels in replenishment lakes within Yellow River diversion irrigation districts: the case of Yuehai Lake

  • 摘要: 阅海是国家重要湿地,水体pH影响湖泊生态系统稳定性。为探究阅海夏季pH偏高的影响因素,基于2020—2024年阅海区控断面月度水质数据及阅海水质自动站日数据、2025年夏季黄河补水及阅海湖区水质详细调查数据,探讨阅海pH时空分布特征及黄河补水、蒸发浓缩、生物过程对阅海pH的影响。结果表明:1)2020—2024年阅海夏季pH高于冬季且夏季存在日尺度pH大于GB 3838—2002《地表水环境质量标准》标准限值现象(pH>9),2025年夏季阅海pH范围在8.23~9.24,空间分布上在东南侧补水口较低,至湖心出现高值区。2)相关性分析结果表明,pH与溶解氧(DO)呈显著正相关,与钙离子(Ca2+)、碳酸氢根(HCO3-)呈显著负相关。主成分分析结果显示pH在代表水体光合作用强度以及碳酸钙(CaCO3)沉淀溶解平衡的主成分中为正载荷,阅海pH受到黄河补水、蒸发浓缩以及生物活动的影响。3)夏季黄河补水pH为8.02,根据水化学特征分析,阅海属于Cl--SO42--Na+-Mg2+型湖泊,黄河补水为HCO3--SO42--Ca2+-Mg2+型,存在离子浓度差异,黄河补水Ca2++Mg2+/CO32-+HCO3-+H2CO3*值大于1,进入湖泊后会消耗湖泊中溶解的无机碳导致湖泊pH上升。Gibbs图显示阅海受到蒸发浓缩作用,湖水样品方解石、白云石的饱和指数均大于0,说明蒸发浓缩作用通过促进碳酸盐沉淀,消耗湖泊CO32-和HCO3-导致湖泊pH上升。夏季湖泊二氧化碳分压指数〔log ρ(CO2)〕均小于0且溶解氧饱和度(DO%)>100%,表明生物光合作用占据主导,湖泊中CO2被消耗导致pH上升。研究解释了黄河补水、蒸发浓缩及生物活动为阅海夏季pH高值作出贡献,为缓解pH升高,可优化补水配置、关注湖泊营养状态。

     

    Abstract: Yuehai Lake is a nationally significant wetland, where water pH influences the stability of the lake ecosystem. To investigate factors influencing Yuehai's elevated summer pH, this study analyzed monthly water quality data from controlled cross-sections in the Yuehai area (2020-2024), daily data from the Yuehai automatic monitoring station, and detailed surveys of water quality during the 2025 summer Yellow River replenishment period. It examined the spatiotemporal distribution of Yuehai's pH and the effects of Yellow River replenishment, evaporative concentration, and biological processes on pH levels. Results indicate: 1) From 2020 to 2024, summer pH levels in Yuehai Lake exceeded winter values, with daily pH readings occasionally surpassing surface water quality standards (pH>9). During the summer of 2025, pH ranged from 8.23 to 9.24, spatially distributed with lower pH near the southeastern inflow point and higher values towards the lake center. 2) Correlation analysis revealed significant positive correlations between pH and dissolved oxygen (DO), and significant negative correlations with Ca2+and HCO3- . Principal component analysis revealed positive loadings for pH with components representing photosynthetic activity intensity and calcium carbonate (CaCO3) precipitation-dissolution equilibrium. Yuehai Lake's pH is influenced by Yellow River inflow, evaporative concentration, and biological activity. 3) During summer, the pH of Yellow River inflow water is 8.02. Based on hydrochemical analysis, Yuehai Lake exhibits a Cl--SO42--Na+-Mg2+ ion composition, whereas Yellow River inflow water displays an HCO3--SO42--Ca2+-Mg2+ composition, indicating ionic concentration disparities. The Ca2++Mg2+/CO32-+HCO3-+H2CO3* ratio of the Yellow River inflow exceeds 1. Upon entering the lake, this inflow consumes dissolved inorganic carbon, leading to an increase in lake pH. Gibbs diagrams indicated evaporative concentration in Yuehai Lake, with saturation indices for calcite and dolomite exceeding zero in lake water samples. This demonstrated that evaporative concentration promotes carbonate precipitation, consuming CO32- and HCO3- to elevate lake pH. During summer, the partial pressure of carbon dioxide index (logρ(CO2)) consistently falled below zero while dissolved oxygen saturation (DO%) exceeds 100%, indicating that biological photosynthesis dominates. The lake system absorbed CO2 and releases O2, consuming CO2 within the lake and consequently raising pH. The study explains that the replenishment of water in the Yellow River, evaporation concentration, and biological activities contribute to the high pH values in summer. To alleviate the increase in pH, it is recommended to optimize the water replenishment plan and pay attention to the nutrient status of the lake.

     

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