基于动态淋溶机制的电镀污泥陶粒路用环境安全阈值评估

Assessment of Environmental Safety Thresholds for Electroplating Sludge-derived Ceramsite as Road Subbase Based on Dynamic Leaching Mechanisms

  • 摘要: 为评估电镀污泥陶粒作为路面基层材料长期使用过程中的重金属环境风险并确立管控限值,本研究构建了耦合降雨入渗与土壤淋溶稀释过程的动态风险评估模型。研究以质量占比58%的电镀污泥陶粒为对象,在模拟极端酸雨(pH=3.2,旨在模拟最不利环境情境)条件下,依据欧盟浸出标准(NEN 7371-2004与NEN 7375-2004)分别开展了破坏性浸出实验与64天动态淋溶实验。结果表明:高温烧结促使陶粒内部生成了尖晶石族(如磁铁矿)等稳定矿相,通过晶格取代与物理包裹作用有效固化铜、锌、镉。结合浸出量与时间在对数坐标系中的斜率(rc)计算证明,即便在酸性环境下,上述三种重金属的释放仍受扩散机制主导;而镍、铬、铅、砷则受非扩散机制控制。风险评估模型显示,以地下水为保护目标时,铜、锌、镉、铬、铅无环境风险;但镍和砷存在潜在风险:在旱季条件下,其到达地下水的最大浓度分别为0.044 mg/L 和0.18 mg/L,分别超出《地下水质量标准》(GB/T 14848-2017)中Ⅲ类标准限值2.2倍和18倍。相比之下,30年路用周期内所有重金属对土壤环境均无超标风险。本研究建立的评估框架验证了模型对关键风险因子的灵敏识别能力,为电镀污泥资源化产品的分级管控提供了科学依据。

     

    Abstract: To evaluate the long term environmental risks of heavy metals in electroplating sludge ceramsites during their service as road sub base materials and to establish control limits, this study developed a dynamic risk assessment model by coupling rainfall infiltration with soil leaching dilution processes. Using ceramsites with a high electroplating sludge mass fraction(58%) as the research object, destructive leaching tests and 64 day dynamic leaching tests were conducted in accordance with EU standards(NEN 7371and NEN 7375) under simulated extreme acid rain conditions(pH =3.2, designed to simulate a worst-case environmental scenario).The results indicated that high-temperature sintering promoted the formation of stable mineral phases, such as the spinel group(e.g., magnetite), thereby achieving immobilization of Copper, Zinc, and Cadmium through lattice substitution and physical encapsulation. Calculations of the slope (rc) of leaching amount versus time in logarithmic coordinates confirmed that the release of these three heavy metals remained diffusion mechanism even under aggressive acidic conditions, whereas Nickel, Chromium, Lead, and Arsenic were governed by non-diffusion mechanism. The risk assessment model revealed that when groundwater was designated as the protection target, Copper, Zinc, Cadmium, Chromium, and Lead posed no environmental risk. However, Nickel and Arsenic exhibited potential risks: under dry season conditions, their maximum attainable concentrations in groundwater were 0.044 mg/L and 0.18 mg/L, respectively. These values exceed the Class III limits in the Standard for Groundwater Quality (GB/T 14848-2017) by 2.2fold and 18fold, respectively. In contrast, none of the heavy metals posed exceedance risks to the soil environment over a 30 year road service life. This study validates the assessment framework's sensitivity in identifying key risk factors, providing a scientific basis for the hierarchical management of electroplating sludge -derived resource products.

     

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