基于文献计量学协同分析市政污泥热解过程含氮化合物迁移转化路径

A comprehensive bibliometric analysis of migration and transformation pathways of nitrogenous compounds during municipal sludge pyrolysis

  • 摘要: 市政污泥热解过程中含氮化合物的迁移转化行为是控制污染与资源化的关键。基于文献计量学对污泥热解过程中含氮化合物的迁移转化、影响因素和调控策略等进行了系统分析。结果显示,相关研究主要聚焦于固相、液相和气相中含氮化合物的转化和调控,固相中含氮化合物由活性有机氮向杂环-N及季铵-N转化,液相中含氮化合物由胺/酰胺类向多氮杂环类和腈类转化,气相中含氮化合物主要由蛋白质向NH3和HCN转化。含氮化合物迁移转化的影响因素主要为热解温度、加热速率和热解气氛,这些因素主要通过改变含氮化合物的裂解程度、挥发分停留时间和自由基环境,影响其迁移转化路径。此外,可通过添加金属氧化物和生物质进行调控,抑制NH3与HCN等NOx前体物的释放。本研究可为市政污泥热解过程中含氮化合物转化路径的定向调控及污泥资源化效率提升提供理论参考。

     

    Abstract: The migration and transformation behavior of nitrogenous compounds during municipal sludge pyrolysis is crucial for pollution control and resource recovery. Using a bibliometric approach, this study systematically analyzed the migration and transformation pathways, influencing factors, and control strategies of nitrogenous compounds during sludge pyrolysis. The results show that existing studies mainly focus on the transformation and control of nitrogenous compounds in the solid, liquid, and gas phases. In the solid phase, nitrogenous compounds are converted from reactive organic nitrogen to heterocyclic nitrogen and quaternary ammonium nitrogen. In the liquid phase, nitrogenous compounds evolve from amines and amides to nitrogen-rich heterocycles and nitriles. In the gas phase, nitrogenous compounds are mainly converted from proteins to NH3 and HCN. Pyrolysis temperature, pyrolysis atmosphere, and heating rate are the main factors affecting nitrogen migration and transformation; these factors influence the migration and transformation pathways by changing the extent of cracking of nitrogenous compounds, the residence time of volatiles, and the radical environment. In addition, control can be achieved by adding metal oxides or biomass, which suppresses the release of NOx precursors such as NH3 and HCN. Overall, this study can provide a theoretical basis for directional control of nitrogen transformation pathways of nitrogenous compounds and for improvement of sludge resource recovery efficiency during municipal sludge pyrolysis.

     

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