钠型丝光沸石去除猪场废水中营养元素的试验研究

Nutrients Removal from Swine Wastewater by Natural Na-type Mordenite

  • 摘要: 以钠型丝光沸石为试验材料进行猪场废水同步脱氮除磷研究,考察了沸石投加量、吸附时间、pH、Ca2+和Mg2+浓度对钠型丝光沸石同步去除氨氮和磷的影响。结果表明,在沸石投加量为300 g/L,pH为8.0~9.0,吸附时间为4 h的条件下,钠型丝光沸石对氨氮的去除率达到92%,对磷的去除率达到86%。随着pH的升高,氨氮和磷的去除率均先升高再降低,氨氮的去除率在pH为8.0时达到最高,为90%;磷的去除率在pH为9.0时达到最高,为85%。Ca2+浓度的增加对沸石去除氨氮的影响不大,但对磷的去除效果影响较显著,在P与Ca的摩尔比为1:6,pH为9.0时,磷的去除率达到88%。Mg2+浓度的增加对沸石去除氨氮和磷的效果影响较显著,在P与Mg的摩尔比为1:4,pH为10.0时,废水中氨氮和磷的去除率达到93%和91%。

     

    Abstract: Taking Na-type mordenite as the experimental material, batch experiments were carried out to investigate the influence of mordenite dosage, reaction time, pH, Ca2+ concentration and Mg2+ concentration on simultaneous removals of nitrogen and phosphorus from actual swine wastewater. It showed that under the conditions of mordenite dosage of 300 mg/L, pH of 8.0~9.0 and adsorption duration of 4 h, the removal efficiencies of high-concentration ammonia and phosphate by mordenite could reach 92% and 86%, respectively. With the increase of pH, the removal efficiency of ammonia and phosphate increased firstly and then decreased. However, the removal efficiency of ammonia reached the highest value around 90% at pH of 8.0, with phosphorus removal efficiency reaching the highest value of 85% at pH of 9.0. The effect of Ca2+ concentration on ammonia removal was not obvious, but was significant for phosphate removal. At P: Ca molar ratio of 1:6 and pH of 9.0, the removal efficiency of phosphate could reach 88%. The effect of Mg2+ concentration was significant for ammonia and phosphate removal. At P:Mg molar ratio of 1:4 and pH of 10.0, the removal efficiencies of ammonia and phosphate could reach 93% and 91%, respectively.

     

/

返回文章
返回