Abstract:
The Two-component model assumes that UV-absorbing dissolved organic matter (DOM) consists of two components (A and B). Component A absorbs UV light strongly, therefore being presumed to possess aromatic chromophores and hydrophobic character, while component B absorbs weakly and can be assumed hydrophilic. The water samples in Qixing wetland were scanned by UV-visible spectra, the dissolved organic carbon (DOC) concentrations estimated by two-component model, and then the relationship between
fA (the fraction of component A) and DOM properties studied. The results showed that: the two-component model provided accurate estimates of DOC concentrations in water of Qixing wetland (
rmsd=2.18mg/L,
R2=0.963), the corresponding model parameter values were
EA,254=95.04 L/(g·cm),
EB,254=0.15 L/(g·cm),
EA,340=30 L/(g·cm),
EB,340=0, respectively. fA values show a declining trend with the increase of the DOC concentration. There are good linear relationships (
R2>0.900) between
fA and special UV absorbance SUVA254, SUVA280.
fA can reflect the unsaturated conjugated double bonds, benzene ring compounds and aromatic compounds in DOM, but it cannot reflect the molecular weight size of the DOM. Accordingly, two-component model can be used for qualitative and quantitative analysis of DOM.