辽河保护区七星湿地磷的空间分布特征

The Spatial Distribution Characteristics of Phosphorus in Qixing Wetland of Liaohe Conservation Area

  • 摘要: 为明确七星湿地水体和沉积物中磷的迁移转化过程,分析了上覆水和间隙水中磷的浓度及分布,研究了沉积物中磷的形态分布特征,计算了沉积物-水界面正磷酸盐(PO43--P)的扩散通量,并对水体及沉积物中不同形态磷进行了Pearson相关性分析。结果表明,水体和沉积物中总磷(TP)空间分布特征为在西小河和万泉河汇入口处二者浓度均较高;在羊肠河处二者浓度均较低;在湿地出口处,干流中TP浓度有所降低。沉积物中的TP以无机磷(IP)为主,所占比例为68.27%~87.41%。IP中各形态磷所占比例为金属(水合)氧化物结合态磷(NaOH-rP)>钙结合态磷(HCl-P)>残渣态磷(Res-P)>有机质和腐殖质中的磷(NaOH-nrP)>氧化还原敏感态磷(BD-P)。沉积物-水界面PO43--P扩散通量为正值,表明沉积物是上覆水中磷元素的重要来源。Pearson相关性分析结果表明,沉积物中BD-P是水体中磷的重要来源之一,NaOH-rP是沉积物中TP和IP的重要控制因子。

     

    Abstract: In order to identify the migration transformation process of phosphorus in water body and sediments in Qixing wetland, the concentration and distribution of phosphorus in surface water and porewater were analyzed, the morphological distribution characteristics of phosphorus in sediments studied, and the diffusion flux of phosphorus in the sediment-overlying water interface measured. Pearson correlation analysis was used to distinguish the different forms of phosphorus in water body and sediments. The results showed that the spatial distribution characteristics of total phosphorus in water body and sediments were slightly different. The concentration of TP in water body and sediments was higher at the entrance of the Xixiao River and the Wanquan River, and the concentration in both of them was lower at the Yangchang River. At the same time, the concentration of TP in the mainstream at exports of the wetlands was lower. IP was the main form of TP in sediments, accounting for 68.27%-87.41%. The proportion order of various forms of phosphorus in IP was NaOH-rP> HCl-P> Res-P> NaOH-nrP> BD-P. The diffusion flux of phosphorus in sediment-overlying water interface was positive, and the results showed that the sediments were important sources of phosphorus in the overlying water. Pearson correlation analysis also showed that BD-P from sediments was one of important inputs of phosphorus in body water, and TP and IP in sediments were mainly controlled by NaOH-rP.

     

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