基于植物仿生的污染土壤原位自持修复中重金属形态变化分析

Morphology analysis of heavy metals in soil pollution in-situ remediation technique based on phyto-mimic method

  • 摘要: 采用基于植物仿生的污染土壤原位自持修复技术,研究了植物仿生修复技术的实地修复效果及修复过程中土壤Cr、Ni、Zn和Fe不同形态浓度的变化。结果表明:植物仿生修复3个月后土壤中Cr、Zn、Ni和Fe浓度逐月递减,分别下降17.33%、27.03%、31.60%和5.17%;4种重金属的形态变化并不相同,土壤Zn和Cr不同形态浓度的下降率为酸溶解态>可还原态>可氧化态>残渣态,土壤Ni和Fe不同形态浓度的下降率为酸溶解态>可氧化态>可还原态>残渣态。植物仿生修复装置填料和模拟叶片均能富集4种重金属,填料吸附性能的大小将影响模拟叶片中4种重金属的浓度。

     

    Abstract: The field remediation effect of phyto-mimic method and the changes of Cr, Ni, Zn and Fe in different forms of soil were studied, using the in situ remediation technique based on phyto-mimic method. Results showed that after three months of phyto-mimic remediation, the concentration of Cr, Zn, Ni and Fe decreased month by month, with the reduction rate for heavy metals being 17.33%, 27.03%, 31.60% and 5.17%, respectively. The morphological changes of the four kinds of heavy metals in phyto-mimic remediation are not the same. The reduction rate of soil Zn and Cr contents of different forms is as follows: acid soluble> reducible> oxidizable> residual fraction; while the reduction rate of soil Ni and Fe contents of different forms is as follows: acid soluble> oxidizable > reducible > residual fraction. The four kinds of heavy metals can be enriched in the filler and simulation blade of the phyto-mimic remediation device, and the adsorption properties of the filler will affect the content of the four kinds of heavy metals in the simulated blade.

     

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