留言板

尊敬的读者、作者、审稿人, 关于本刊的投稿、审稿、编辑和出版的任何问题, 您可以本页添加留言。我们将尽快给您答复。谢谢您的支持!

姓名
邮箱
手机号码
标题
留言内容
验证码

白塔堡河水体DOM分布特征及来源

颜秉斐 彭剑峰 邓齐玉 李丹 刘雪瑜 李洁

颜秉斐, 彭剑峰, 邓齐玉, 李丹, 刘雪瑜, 李洁. 白塔堡河水体DOM分布特征及来源[J]. 环境工程技术学报, 2019, 9(3): 225-232. doi: 10.12153/j.issn.1674-991X.2019.02.190
引用本文: 颜秉斐, 彭剑峰, 邓齐玉, 李丹, 刘雪瑜, 李洁. 白塔堡河水体DOM分布特征及来源[J]. 环境工程技术学报, 2019, 9(3): 225-232. doi: 10.12153/j.issn.1674-991X.2019.02.190
YAN Bingfei, PENG Jianfeng, DENG Qiyu, LI Dan, LIU Xueyu, LI Jie. DOM distribution characteristics and source analysis of Baitabu River[J]. Journal of Environmental Engineering Technology, 2019, 9(3): 225-232. doi: 10.12153/j.issn.1674-991X.2019.02.190
Citation: YAN Bingfei, PENG Jianfeng, DENG Qiyu, LI Dan, LIU Xueyu, LI Jie. DOM distribution characteristics and source analysis of Baitabu River[J]. Journal of Environmental Engineering Technology, 2019, 9(3): 225-232. doi: 10.12153/j.issn.1674-991X.2019.02.190

白塔堡河水体DOM分布特征及来源

doi: 10.12153/j.issn.1674-991X.2019.02.190
详细信息
    作者简介:

    颜秉斐(1989—),女,硕士,主要从事水环境处理技术研究, ybf201506@163.com

    通讯作者:

    刘雪瑜 E-mail: liuxueyu@craes.org.cn

  • 中图分类号: X524

DOM distribution characteristics and source analysis of Baitabu River

More Information
    Corresponding author: Xueyu LIU E-mail: liuxueyu@craes.org.cn
  • 摘要: 利用三维荧光光谱法和Pearson相关性分析,研究了典型东北城镇型河流——白塔堡河水体溶解性有机物(DOM)的污染特征,并解析了其来源。结果表明:白塔堡河水体DOM的荧光峰类型主要有紫外区类富里酸峰(A峰)、可见区类富里酸峰(C峰)、类蛋白峰(B峰)和类蛋白峰(T峰);水体DOM主要组分及其浓度顺序为蛋白类物质>溶解性微生物代谢产物>富里酸类物质>腐殖酸类物质,水体DOM浓度空间分布表现为中下游>上游;水体DOM来源表现为内源和外源的双重特性,其中内源污染不容忽视;水体DOM各组分浓度与氨氮(NH3-N)和总磷(TP)浓度呈显著正相关,与溶解氧(DO)浓度呈负相关。

     

  • [1] 环境保护部. 2016 中国环境状况公报[A/OL].( 2017-06-15)[2018-01-30].http://www.cnemc.cn/jcbg/zghjzkgb/201706/W020181008686150202337.pdf.
    [2] 郝瑞霞, 曹可心, 邓亦文 . 城市污水处理过程中有机污染物三维荧光特性的变化规律[J]. 分析测试学报, 2007,26(6):789-792.
    doi: 10.3969/j.issn.1004-4957.2007.06.005

    HAO R X, CAO K X, DENG Y W . The variation trend of three-dimensional characteristic fluorescence of dissolved organic matter in the wastewater treatment process[J]. Journal of Instrumental Analysis, 2007,26(6):789-792. doi: 10.3969/j.issn.1004-4957.2007.06.005
    [3] 高霞, 周凌云, 席景砖 . 荧光分析法在环境有机污染物检测中的应用[J]. 光谱实验室, 2011,28(4):2008-2016.
    doi: 10.3969/j.issn.1004-8138.2011.04.109

    GAO X, ZHOU L Y, XI J Z . Applications of fluorescence analysis methods in detection of environmental organic pollutants[J]. Chinese Journal of Spectroscopy Laboratory, 2011,28(4):2008-2016. doi: 10.3969/j.issn.1004-8138.2011.04.109
    [4] LEENHEER J A, CROUA J P . Characterizing aquatic dissolved organic matter[J]. Environmental Science and Technology, 2003,37(1):18-26.
    doi: 10.1021/es032333c
    [5] 虞敏达, 张慧, 何小松 , 等. 河北洨河溶解性有机物光谱学特性[J]. 环境科学, 2015,36(9):3194-3201.
    doi: 10.13227/j.hjkx.2015.09.010

    YU M D, ZHANG H, HE X S , et al. Spectral characteristic of dissolved organic matter in Xiaohe River,Hebei[J]. Environmental Science, 2015,36(9):3194-3201. doi: 10.13227/j.hjkx.2015.09.010
    [6] 刘瑞霞, 李斌, 刘娜娜 , 等. 辽河流域与英国中部河湖水体中溶解有机质的荧光特性[J]. 环境科学学报, 2014,34(9):2321-2328.
    doi: 10.13671/j.hjkxxb.2014.0603

    LIU R X, LI B, LIU N N , et al. Fluorescence characteristics of dissolved organic matter in freshwaters from Liaohe Basin and Midland of UK[J]. Acta Scientiae Circumstantiae, 2014,34(9):2321-2328. doi: 10.13671/j.hjkxxb.2014.0603
    [7] 宋晓娜, 于涛, 张远 , 等. 利用三维荧光技术分析太湖水体溶解性有机质的分布特征及来源[J]. 环境科学学报, 2010,30(11):2321-2331.

    SONG X N, YU T, ZHANG Y , et al. Distribution characterization and source analysis of dissolved organic matter in Taihu Lake using a three dimensional fluorescence excitation-emission matrix[J]. Acta Scientiae Circumstantiae, 2010,30(11):2321-2331.
    [8] 张海威, 张飞, 李哲 , 等. 新疆艾比湖主要入湖河流精河与博尔塔拉河三维荧光光谱特性及其与水质的关系[J]. 湖泊科学, 2017,29(5):1112-1120.
    doi: 10.18307/2017.0509

    ZHANG H W, ZHANG F, LI Z , et al. Characteristics of three dimensional fluorescence spectra and its correlation with water quality in Jinghe and Bortala River from Lake Ebinur’s major inflow tributaries, Xinjiang[J]. Journal of Lake Sciences, 2017,29(5):1112-1120. doi: 10.18307/2017.0509
    [9] 吴志皓, 唐尧基, 李桂敏 , 等. 荧光分析法在环境有机污染物分析中的应用[J].分析仪器, 2005(3):13-19.
    doi: 10.3969/j.issn.1001-232X.2005.03.003

    WU Z H, TANG Y J, LI G M , et al. Applications of fluorescence analysis methods in the analysis of environmental organic pollutants[J].Analytical Instrumentation, 2005(3):13-19. doi: 10.3969/j.issn.1001-232X.2005.03.003
    [10] 唐亮 . 北方地区中小河流水生态特征与主要评价因子的研究[J]. 环境保护科学, 2014,40(1):41-45.
    doi: 10.3969/j.issn.1004-6216.2014.01.010

    TANG L . Study on water ecological characteristics and main evaluation factors of medium and small rivers in north area[J]. Environmental Protection Science, 2014,40(1):41-45. doi: 10.3969/j.issn.1004-6216.2014.01.010
    [11] HENDERSON R K, BAKER A, MURPHY K R , et al. Fluorescenceas a potential monitoring tool for recycled water systems:a review[J]. Water Research, 2009,43(4):863-881.
    doi: 10.1016/j.watres.2008.11.027 pmid: 19081598
    [12] BRIDGEMAN J, BIEROZA M, BAKER A . The application of fluorescence spectroscopy to organic matter characterization in drinking water treatment[J]. Reviews in Environmental Science and Biotechnology, 2011,10(3):277-290.
    doi: 10.1007/s11157-011-9243-x
    [13] 杨楠, 于会彬, 宋永会 , 等. 白塔堡河上覆水与沉积物间隙N、P分布特征[J]. 环境科学研究, 2013,26(7):728-735.

    YANG N, YU H B, SONG Y H , et al. Distribution of nitrogen and phosphorus in overlying water and pore water of sediment in Baitabuhe River[J]. Research of Environmental Sciences, 2013,26(7):728-735.
    [14] 于会彬, 高红杰, 宋永会 , 等. 城镇化河流DOM组成结构及与水质相关性研究[J]. 环境科学学报, 2016,36(2):435-441.
    doi: 10.13671/j.hjkxxb.2015.0515

    YU H B, GAO H J, SONG Y H , et al. Study on composition structure of DOM and its correlation with water quality in an urbanized river[J]. Acta Scientiae Circumstantiae, 2016,36(2):435-441. doi: 10.13671/j.hjkxxb.2015.0515
    [15] 王琳 . 白塔堡河防洪规划及环境影响评价建议[J]. 中国防汛抗旱, 2015,25(1):91-93.
    [16] 国家环境保护总局. 水和废水监测分析方法[M]. 4版.北京: 中国环境科学出版社, 2002.
    [17] MURPHY K R, HAMBLY A, SINGH S , et al. Organic matter fluorescence in municipal water recycling schemes: toward a unified PARAFAC Model[J]. Environmental Science & Technology, 2011,45(7):2909-2916.
    doi: 10.1021/es103015e pmid: 21361278
    [18] CHEN W, WESTERHOFF P, LEENHEER J A , et al. Fluorescence excitation-emission matrix regional integration to quantify spectra for dissolved organic matter[J]. Environmental Science & Technology, 2003,37(24):5701-5710.
    doi: 10.1021/es034354c pmid: 14717183
    [19] 姚璐璐, 涂响, 于会彬 , 等. 三维荧光区域积分评估城市污水中溶解性有机物去除[J]. 环境工程学报, 2013,7(2):411-416.

    YAO L L, TU X, YU H B , et al. Evaluation of dissolved organic matter removal in municipal wastewater based on fluorescence regional integration[J]. Chinese Journal of Environmental Engineering, 2013,7(2):411-416.
    [20] 李东俊 . 溶解氧在河流水质污染中的作用与分析[J].河南水利与南水北调, 2014(14):7-8.
    [21] 温永昇 . 氧垂曲线在处理水污染事故中的应用[J].江苏环境科技, 1994(1):25-27.
    [22] WU F C, TANOUE E . Isolation and partial characterization of dissolved copper-complexing ligands in streamwaters[J]. Environmental Science & Technology, 2001,35:3646-3652.
    doi: 10.1021/es0019023 pmid: 11783640
    [23] BARKER D J, STUCKEY D C . A review of soluble microbial products(SMP) in wastewater treatment system[J]. Water Research, 1999,33:3063-3082.
    doi: 10.1016/S0043-1354(99)00022-6
    [24] LI W H, SHENG G P, LIU X W , et al. Characterizing the extracellular and intracellular fluorescent products of activated sludge in a sequencing batch reactor[J]. Water Research, 2008,42:3173-3181.
    doi: 10.1016/j.watres.2008.03.010 pmid: 18423798
    [25] YU H B, SONG Y H, TU X , et al. Assessing removal efficiency of dissolved organic matter in wastewater treatment using fluorescence excitation emission matrices with parallel factor analysis and second derivative synchronous fluorescence[J]. Bioresource Technology, 2013,144:595-601.
    doi: 10.1016/j.biortech.2013.07.025 pmid: 23896440
    [26] LI W T, XU Z X, LI A M , et al. HPLC/HPSEC-FLD with multi-excitation/emission scan for EEM interpretation and dissolved organic matter analysis[J]. Water Research, 2013,47(3):1246-1256.
    doi: 10.1016/j.watres.2012.11.040 pmid: 23260178
    [27] 傅平青, 刘丛强, 吴丰昌 . 溶解有机质的三维荧光光谱特征研究[J]. 光谱学与光谱分析, 2005,25(12):2024-2028.
    doi: 10.3321/j.issn:1000-0593.2005.12.031

    FU P Q, LIU C Q, WU F C . Three-dimensional excitation emission matrix fluorescence spectroscopy characterization of dissolved organic matter[J]. Spectroscopy and Spectral Analysis, 2005,25(12):2024-2028. doi: 10.3321/j.issn:1000-0593.2005.12.031
    [28] 谢秀风, 郗敏, 李悦 , 等. 湿地溶解性有机质(DOM)源识别方法研究[J]. 地质评论, 2014,60(5):1102-1108.
    doi: 10.3969/j.issn.0371-5736.2014.05.014

    XIE X F, XI M, LI Y , et al. Research of the source identification methods for dissolved organic matter(DOM) in wetland[J]. Geological Review, 2014,60(5):1102-1108. doi: 10.3969/j.issn.0371-5736.2014.05.014
    [29] 叶少帆, 吴志超, 王志伟 , 等. Fenton法处理垃圾渗滤液过程中有机物分子质量分布和荧光特性[J]. 环境科学研究, 2010,23(8):1049-1054.

    YE S F, WU Z C, WANG Z W , et al. Fluorescent characteristics and molecular weight distribution of organic substances in the course of treating landfill leachate by Fenton oxidation[J]. Research of Environmental Sciences, 2010,23(8):1049-1054.
    [30] 王翼, 吴昌永, 周岳溪 , 等. Fenton氧化深度处理石化废水厂二级出水研究[J]. 环境科学, 2015,36(7):2597-2603.
    doi: 10.13227/j.hjkx.2015.07.036

    WANG Y, WU C Y, ZHOU Y X , et al. Treatment of petrochemical treatment plant secondary effluent by Fenton oxidation[J]. Environmental Science, 2015,36(7):2597-2603. doi: 10.13227/j.hjkx.2015.07.036
    [31] 陈蕾, 沈超峰, 陈英旭 . 溶解性有机质与水生生物的直接相互作用研究进展[J]. 湖泊科学, 2011,23(1):1-8.
    doi: 10.18307/2011.0101

    CHEN L, SHEN C F, CHEN Y X . Direct interaction of dissolved organic matter with aquatic organisms[J]. Journal of Lake Sciences, 2011,23(1):1-8. doi: 10.18307/2011.0101
    [32] GLOVER C N, PANE E F, WOOD C M . Humic substances influence sodium metabolism in the freshwater crustacean Daphnia magna[J]. Physiological and Biochemical Zoology, 2005,78(3):405-416.
    doi: 10.1086/430036 pmid: 15887087
    [33] MCKNIGHT D W, AIKEN G R, SMITH R L . Aquatic fulvic acids in microbially based ecosystems: results from two desert lakes in Antarctica[J]. Limnology and Oceanography, 1991,36(5):998-1006.
    doi: 10.4319/lo.1991.36.5.0998
    [34] 郭旭晶, 席北斗, 谢森 , 等. 乌梁素海沉积物孔隙水中溶解有机质的荧光及紫外光谱研究[J]. 环境工程学报, 2012,6(2):440-444.

    GUO X J, XI B D, XIE S , et al. Study on fluorescence spectra and UV-vis spectra of dissolved organic matter collected from sediment pore water in Wuliangsuhai Lake[J]. Chinese Journal of Environmental Engineering, 2012,6(2):440-444.
    [35] 冯伟莹, 焦立新, 张生 , 等. 乌梁素海沉积物溶解有机质荧光光谱特性[J]. 中国环境科学, 2013,33(6):1068-1074.
    doi: 10.3969/j.issn.1000-6923.2013.06.015

    FENG W Y, JIAO L X, ZHANG S , et al. Spectral characteristics of dissolved organic matter in the sediments of Wuliangsuhai Lake[J]. China Environmental Science, 2013,33(6):1068-1074. doi: 10.3969/j.issn.1000-6923.2013.06.015
    [36] TZORTZIOU M, NEALE P J, OSBURN C L , et al. Tidal marshes as a source of optically and chemically distinctive colored dissolved organic matter in the Chesapeake Bay[J]. Limnology and Oceanography, 2008,53(1):148-159.
    doi: 10.4319/lo.2008.53.1.0148
    [37] JAFFÉ R, MCKNIGHT D, MAIE N , et al. Spatial and temporal variations in DOM composims: the importance of long-term monitoring of optical properties[J]. Journal of Geophysical Research: Biogeosciences, 2008,113:1-15.
    [38] 刘琦, 江源, 丁佼 , 等. 东江流域主要支流溶解性有机质污染特征初探[J]. 自然资源学报, 2016,31(7):1231-1240.

    LIU Q, JIANG Y, DING J , et al. Exploring the pollution characteristics of dissolved organic matter in the primary tributaries of the Dongjiang River[J]. Journal of Natural Resources, 2016,31(7):1231-1240.
    [39] 赵丛丛 . 城市纳污河流溶解性有机质时空演变规律分析[D]. 石家庄:河北科技大学, 2017.
  • 加载中
计量
  • 文章访问数:  521
  • HTML全文浏览量:  81
  • PDF下载量:  176
  • 被引次数: 0
出版历程
  • 收稿日期:  2018-11-13
  • 刊出日期:  2019-05-20

目录

    /

    返回文章
    返回