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污染地下水可渗透反应墙(PRB)技术研究进展

王泓泉

王泓泉. 污染地下水可渗透反应墙(PRB)技术研究进展[J]. 环境工程技术学报, 2020, 10(2): 251-259. doi: 10.12153/j.issn.1674-991X.20190129
引用本文: 王泓泉. 污染地下水可渗透反应墙(PRB)技术研究进展[J]. 环境工程技术学报, 2020, 10(2): 251-259. doi: 10.12153/j.issn.1674-991X.20190129
WANG Hongquan. Study on permeable reactive barrier technology for the remediation of polluted groundwater[J]. Journal of Environmental Engineering Technology, 2020, 10(2): 251-259. doi: 10.12153/j.issn.1674-991X.20190129
Citation: WANG Hongquan. Study on permeable reactive barrier technology for the remediation of polluted groundwater[J]. Journal of Environmental Engineering Technology, 2020, 10(2): 251-259. doi: 10.12153/j.issn.1674-991X.20190129

污染地下水可渗透反应墙(PRB)技术研究进展

doi: 10.12153/j.issn.1674-991X.20190129
详细信息
    作者简介:

    王泓泉(1987—),男,工程师,硕士,主要从事污染生态修复及污染场地调查评估研究,wanghq87@126.com

  • 中图分类号: X523

Study on permeable reactive barrier technology for the remediation of polluted groundwater

  • 摘要: 地下水污染已成为我国严峻的环境问题,治理污染地下水工作迫在眉睫。可渗透反应墙(permeable reactive barrier,PRB)技术是污染地下水修复的新兴技术,具有治理效果好、造价低廉、对生态环境影响小等特点,能够有效去除地下水中的有机氯化物、重金属和无机离子等。PRB技术在美国已广泛应用到工程领域并实现商业化,在我国目前处于实验室研究和现场示范应用阶段。综述了PRB技术的原理、结构类型、活性填料、修复机理和工程应用,指出PRB系统长期有效运行存在的技术问题,以及PRB技术的应用前景和重点研究方向,以期为PRB技术在我国的研发和推广应用及地下水污染治理提供参考。

     

  • [1] 姜建军 . 中国地下水污染现状与防治对策[J]. 环境保护, 2007,381(19):16-17.
    [2] 中国环境保护产业协会. 污染场地修复技术目录(第一批)[A]. 北京:中国环境保护产业发展报告(2014), 2015.
    [3] 生态环境部. 污染地块地下水修复和风险管控技术导则:HJ 25.6—2019[S]. 北京:中国环境出版集团 2019.
    [4] 隋红, 李洪, 李鑫钢 , 等. 有机污染土壤和地下水修复[M]. 北京:科学出版社 2013.
    [5] 刘玲, 徐文彬, 甘树福 . PRB技术在地下水污染修复中的研究进展[J]. 水资源保护, 2006,22(6):76-80.

    LIU L, XU W B, GAN S F . Study on permeable reactive barrier for remediation of groundwater contamination[J]. Water Resources Protection, 2006,22(6):76-80.
    [6] 陆泗进, 王红旗, 杜琳娜 . 污染地下水原位治理技术-透水性反应墙法[J]. 环境污染与防治, 2006,28(6):452-457.

    LU S J, WANG H Q, DU L N . In situ remediation of contaminated underground water:permeable reactive barrier[J]. Environmental Pollution & Control, 2006,28(6):452-457.
    [7] 柏耀辉, 张淑娟 . 地下水污染修复技术:可渗透反应墙[J]. 云南环境科学, 2005,24(4):51-54.

    BAI Y H, ZHANG S J . Permeable reactive barrier as a remedy technology of contaminated groundwater[J]. Yunnan Environmental Science, 2005,24(4):51-54.
    [8] 束善治, 袁勇 . 污染地下水原位处理方法:可渗透反应墙[J]. 环境污染治理技术与设备, 2002,3(1):47-51.

    SHU S Z, YUAN Y . In situ remediation of contaminated ground water:permeable reactive barrier[J]. Techniques and Equipment for Environmental Pollution Control, 2002,3(1):47-51.
    [9] 翟亚丽, 王兴润, 舒新前 , 等. PRB技术修复铬污染地下水的试验研究[J]. 环境工程, 2012,30(增刊2):54-58.

    ZHAI Y L, WANG X R, SHU X Q , et al. Experimental study on the remediation of chromium contaminated groundwater with PRB media[J]. Environmental Engineering, 2012,30(Suppl 2):54-58.
    [10] 刘翔, 唐翠梅, 陆兆华 , 等. 零价铁PRB技术在地下水原位修复中的研究进展[J]. 环境科学研究, 2013,26(12):1309-1315.

    LIU X, TANG C M, LU Z H , et al. Progress of Fe 0-PRB in remediation of contaminated groundwater [J]. Research of Environmental Sciences, 2013,26(12):1309-1315.
    [11] 陈梦舫, 钱林波, 晏井春 , 等. 地下水可渗透反应墙修复技术原理、设计及应用[M]. 北京:科学出版社 2017.
    [12] POWELL R M, PULS R W, BLOWES D W , et al. Permeable reactive barrier technologies for contaminant remediation[R]. Washington DC:US Environmental Protection Agency, 1998.
    [13] LUDWIG R D, SMYTH D J, BLOWES D W , et al. Treatment of arsenic,heavy metals,and acidity using a mixed ZVI-compost PRB[J]. Environmental Science and Technology, 2009,43(6):1970-1976.
    [14] VOGAN J L, FOCHT R M, CLARK D K , et al. Performance evaluation of a permeable reactive barrier for remediation of dissolved chlorinated solvents in groundwater[J]. Journal of Hazardous Materials, 1999,68(1∕2):97-108.
    [15] BARTON C S, STEWART I, MORRIS K , et al. Performance of three resin-based materials for treating uranium-contaminated groundwater within a PRB[J]. Journal of Hazardous Materials, 2004,116(3):191-204.
    [16] SU C M, PULS R W . Nitrate reduction by zerovalent iron:effects of formate,oxalate,citrate,chloride,sulfate,borate,and phosphate[J]. Environmental Science and Technology, 2004,38(9):2715-2720.
    [17] TURNER M, DAVE N M, MODENA T , et al. Permeable reactive barriers:lessons learned∕new directions[M]. Washington DC:The Interstate Technology and Regulatory Council, 2005.
    [18] 邱锦安, 张澄博, 李洪艺 , 等. PRB在地下水污染修复中的应用与研究进展[J]. 广东农业科学, 2011,38(13):144-146.

    QIU J A, ZHANG C B, LI H Y , et al. Application and research progress of PRB in remediation of polluted groudwater[J]. Guangdong Agricultural Sciences, 2011,38(13):144-146.
    [19] 李志红, 王广才, 史浙明 , 等. 渗透反应格栅技术综述:填充材料实验研究、修复技术实例和系统运行寿命[J]. 环境化学, 2017,36(2):316-327.

    LI Z H, WANG G C, SHI Z M , et al. Review of permeable reactive barrier technology:the experimental study of filling materials,the example of remediation technology,and the longevity of the system[J]. Environmental Chemistry, 2017,36(2):316-327.
    [20] GAVASKAR A, GUPTA N, SASS B , et al. Design guidance for application of permeable reactive barriers for groundwater remediation[R]. Columbus,Ohio:Battelle, 2000.
    [21] BLOWES D W, PTACEK C J, CHERRY J A , et al. Passive remediation of groundwater using in situ treatment curtains[M]. ASCE:Geotechnical Special Publication, 1995.
    [22] YOU Y, HAN J, CHIU P C , et al. Removal and inactivation of waterborne viruses using zerovalent iron[J]. Environmental Science and Technology, 2005,39(2):9263-9269.
    [23] OBIRI-NYARKO F, GRAJALES-MESA S J, MALINA G . An overview of permeable reactive barriers for in situ sustainable groundwater remediation[J]. Chemosphere, 2014,111(1):243-259.
    [24] 张晓慧, 葛芳州, 董玉婧 , 等. 可渗透反应墙原位修复污染地下水研究进展[J]. 工业用水与废水, 2015,46(3):1-5.

    ZHANG X H, GE F Z, DONG Y J , et al. Research progress of permeable reactive barriers for in situ groundwater remediation[J]. Industrial Water & Wastewater, 2015,46(3):1-5.
    [25] 刘菲, 陈亮, 王广才 , 等. 地下水渗透反应格栅技术发展综述[J]. 地球科学进展, 2015,30(8):863-877.

    LIU F, CHEN L, WANG G C , et al. Permeable reactive barrier for groundwater pollution remediation:an overview[J]. Advances in Earth Science, 2015,30(8):863-877.
    [26] FARRELL J, KASON M, MELITAS N , et al. Investigation of the long-term performance of zero-valent iron for reductive dechlorination of trichloroethylene[J]. Environmental Science and Technology, 2000,34(3):514-521.
    [27] PARBS A, EBERT M, DAHINKE A . Long-term effects of dissolved carbonate species on the degradation of trichloroethylene by zerovalent iron[J]. Environmental Science and Technology, 2007,41(1):291-296.
    [28] RITTER K, ODZIEMKOWSKI M S, SIMPGRAGA R , et al. An in situ study of the effect of nitrate on the reduction of trichloroethylene by granular iron[J]. Journal of Contaminant Hydrology, 2003,39(5):1309-1318.
    [29] CHEN J L, AL-ABED S R, RYAN J A , et al. Effects of pH on dechlorination of trichloroethylene by zero-valent iron[J]. Journal of Hazardous Materials, 2001,83(3):243-254.
    [30] GILLHAM R W, VOGAN J, GUI L , et al. Iron barrier walls for chlorinated solvent remediation[M] ∕∕STROO H,WARD C H.Situ remediation of chlorinated solvent plumes.NewYork:Springer-Verlag, 2010: 537-571.
    [31] GILLHAM R W . Enhanced degradation of halogenated aliphatics by zero-valent iron[J]. Ground Water, 1994,32(6):958-967.
    [32] BLOWES D W, PTACEK C J, BENNER S G , et al. Treatment of inorganic contaminants using permeable reactivebarriers[J]. Journal of Contaminant Hydrology, 2000,45(1):123-137.
    [33] CONCA J L, WRIGHT J . An apatiteⅡpermeable reactive barrier to remediate groundwater containing Zn,Pb and Cd[J]. Applied Geochemistry, 2006,21(12):1288-1300.
    [34] 刘凤莲, 刘兴荣 . 零价铁脱除水中六价铬的实验研究[J]. 环境与健康杂志, 2009,26(2):139-141.

    LIU F L, LIU X R . Removal of chromium(Ⅵ) with zero valent iron:an experimental research[J]. Journal of Environment and Health, 2009,26(2):139-141.
    [35] 李雅, 张增强, 唐次来 , 等. Fe 0去除地下水中六价铬的研究 [J]. 中国农业大学学报, 2011,16(2):160-164.

    LI Y, ZHANG Z Q, TANG C L , et al. Simulation on reduction of hexavalent chromium from groundwater using zero valent iron[J]. Journal of China Agricultural University, 2011,16(2):160-164.
    [36] 王兴润, 翟亚丽, 舒新前 , 等. 修复铬污染地下水的可渗透反应墙介质筛选[J]. 环境工程学报, 2013,7(7):2523-2528.

    WANG X R, ZHAI Y L, SHU X Q , et al. Selection of permeable reactive barrier media for remediation of contaminated groundwater with chromium[J]. Chinese Journal of Environmental Engineering, 2013,7(7):2523-2528.
    [37] HOSSEINIS M, ATAIE-ASHTIANI B, KHOLGHIAM . Nitrate reduction by nano-Fe∕Cu particles in packed column[J]. Desalination, 2011,276(1∕2∕3):214-221.
    [38] MOON H S, AHN K H, LEE S , et al. Use of autotrophic sulfuroxidizers to remove nitrate from bank filtrate in a permeable reactive barrier system[J]. Environmental Pollution, 2004,129(3):499-507.
    [39] 张增强, 唐次来, 邵淼 , 等. Fe 0去除地下水中硝酸盐的条件研究 [J]. 中国农业大学学报, 2008,13(6):37-42.

    ZHANG Z Q, TANG C L, SHAO M , et al. Parameters optimization for removal of nitrate in groundwater by zero-valent iron[J]. Journal of China Agricultural University, 2008,13(6):37-42.
    [40] 孟凡生, 王业耀, 张星星 . 零价铁PRB修复硝酸盐和铬复合污染地下水[J]. 环境科学研究, 2012,25(11):1279-1284.

    MENG F S, WANG Y Y, ZHANG X X , et al. Remediation of ground water contaminated by nitrate nitrogen and chromium using zero-valent iron PRB technology[J]. Research of Environmental Sciences, 2012,25(11):1279-1284.
    [41] FU F, DIONYSIOS D D, LIU H , et al. The use of zero-valent iron for groundwater remediation and wastewater treatment:a review[J]. Journal of Hazardous Materials, 2014,267(3):194-205.
    [42] MANDJINY S, ZOUBOULIS A I, MATIS K A . Removal of cadmium from dilute solutions by hydroxyapatite:Ⅰ.sorption studies[J]. Separation Science and Technology, 1995,30(15):2963-2978.
    [43] XU Y, SCHWARTZ F W, TRAINA S J . Sorption of Zn 2+and Cd 2+on hydroxyapatite surfaces [J]. Separation Science and Technology, 1994,28(8):1472-1480.
    [44] WOINARSKI A Z, SNAPE I, STEVENS G W , et al. The effects of cold temperature on copper ion exchange by natural zeolite for use in a permeable reactive barrier in Antarctica[J]. Cold Regions Science and Technology, 2003,37(2):159-168.
    [45] ARORA M, SNAPE I, STEVENS G W . The effect of temperature on toluene sorption by granular activated carbon and its use in permeable reactive barriers in cold regions[J]. Cold Regions Science and Technology, 2011,66(1):12-16.
    [46] XIN B P, WU C H, LIN C W . Bioaugmented remediation of high concentration BTEX-contaminated groundwater by permeable reactive barrier with immobilized bead[J]. Journal of Hazardous Materials, 2013,244∕245:765-772.
    [47] LI S, HUANG G, KONG X , et al. Ammonium removal from groundwater using a zeolite permeable reactive barrier:a pilot-scale demonstration[J]. Water Science and Technology, 2014,70(9):1540-1547.
    [48] VESELA L, NEMECEK J, SIGLOVA M , et al. The biofiltration permeable reactive barrier:practical experience from Synthesia[J]. International Biodeterioration & Biodegradation, 2006,58(3∕4):224-230.
    [49] O’HANNESIN S F, GILLHAM R W, VOGAN J L . TCE degradation in groundwater using zero-valent iron[R]. Washington DC:American Chemical Society Extended Abstract,Industrial and Engineering Chemistry Division, 1995:55-58.
    [50] USCG. In situ permeable reactive barrier for treatment of contaminated groundwater at the US Coast Guard Support Center,Elizabeth City,North Carolina[R]. Elizabeth City,NC:US Coast Guard Support Center, 1998.
    [51] VANSTONE N, PRZEPIORA A, VOGAN J , et al. Monitoring trichloroethene remediation at an iron permeable reactive barrier using stable carbon isotopic analysis[J]. Journal of Contaminant Hydrology, 2005,78(4):313-325.
    [52] ZOLLA V, FREYRIA F S, SETHI R , et al. Hydrogeochemical and biological processes affecting the long-term performance of an iron-based permeable reactive barrier[J]. Journal of Environmental Quality, 2009,38(3):897-908.
    [53] PHILLIPS D H, NOOTEN T N, BASTIAENS L , et al. Ten year performance evaluation of a field-scale zero-valent iron permeable reactive barrier installed to remediate trichloroethene contaminated groundwater[J]. Environmental Science and Technology, 2010,44(10):3861-3869.
    [54] MUCHITSCH N, VAN NOOTEN T, BASTIAENS L , et al. Integrated evaluation of the performance of a more than seven year old permeable reactive barrier at a site contaminated with chlorinated aliphatic hydrocarbons(CAHs)[J]. Journal of Contaminant Hydrology, 2011,126(3):258-270.
    [55] WANNER C, ZINK S, EGGENBERGER U , et al. Assessing the Cr(Ⅵ) reduction efficiency of a permeable reactive barrier using Cr isotope measurements and 2D reactive transport modeling[J]. Journal of Contaminant Hydrology, 2012,131(1∕2∕3∕4):54-63.
    [56] HOU G, LIU F, LIU M , et al. Performance of a permeable reactive barrier for in situ removal of ammonium in groundwater[J]. Water Science and Technology:Water Supply, 2014,14(4):585-592.
    [57] 李圣品, 刘菲, 黄国鑫 , 等. 傍河型水源井氨氮阻断与去除工程设计案例分析[J]. 环境科学学报, 2015,35(8):2471-2480.

    LI S P, LIU F, HUANG G X , et al. Remediation and interception of riverside water wells contaminated by ammonium-nitrogen:an engineering case study[J]. Acta Scientiae Circumstantiae, 2015,35(8):2471-2480.
    [58] 田雷 . 复合介质PRB去除地下水中氯代烃和苯系物混合污染研究[D]. 北京:中国地质大学(北京),2014.
    [59] 腾应, 陈梦舫 . 稀土尾矿库区地下水污染风险评估与防控修复技术[M]. 北京:科学出版社 2016.
    [60] 中国科学院南京土壤研究所宋昕团队. 原长沙铬盐厂可渗透反应墙(PRB)原位修复铬污染地下水[EB∕OL].(2019-04-04)[2019-07-14].
    [61] 张桂华, 潘伟斌, 秦玉洁 , 等. 受污染地下水可渗透反应墙修复技术研究[J]. 农业环境科学学报, 2005,24(增刊1):153-157.

    ZHANG G H, PAN W B, QIN Y J , et al. Study on the reaction media of PRB technology in the remediation of polluted groundwater[J]. Journal of Agro-Environment Science, 2005,24(Suppl 1):153-157.
    [62] WILKIN R T, PULS R W, SEWELL G W . Long-term performance of permeable reactive barriers using zero-valent iron:geochemical and microbiological effects[J]. Ground Water, 2003,41(4):493-503.
    [63] LU X, LI M, TANG C , et al. Electrochemical depassivation for recovering Fe0 reactivity by Cr(Ⅵ)removal with a permeable reactive barrier system[J]. Journal of Hazardous Materials, 2012,213∕214:355-360.
    [64] GEIGER C L, CLAUSEN C, REINHART D R , et al. Using ultrasound for restoring iron activity in permeable reactive barriers[J]. ACS Symposium Series, 2002,837:286-303.
    [65] VIKESLAND P J, KLAUSEN J, ZIMMERMANN H , et al. Longevity of granular iron in groundwater treatment processes:changes in solute transport properties over time[J]. Journal of Contaminant Hydrology, 2003,64(1):3-33.
    [66] 陶征义, 隋天娥 . 酸性矿山排水被动处理方法研究进展[J]. 环境科学与管理, 2009,34(3):96-99.

    TAO Z Y, SUI T E . The passive treatment system of acid mine drainage research progress[J]. Environmental Science and Management, 2009,34(3):96-99.
    [67] NOUBACTEP C . Review:the fundamental mechanism of aqueous contaminant removal by metallic iron[J]. Water SA, 2010,36(5):663-670.
    [68] MATHESON L J, TRATNYEK P G . Reductive dehalogenation of chlorinated methanes by iron metal[J]. Environmental Science and Technology, 1994,28(12):2045-2053.
    [69] TÁMARA M L, BUTLER E C . Effects of iron purity and groundwater characteristics on rates and products in the degradation of carbon tetrachloride by iron metal[J]. Environmental Science and Technology, 2004,38(6):1866-1876.
    [70] 陈亮 . 零价铁渗透反应格栅中铁的微生物钝化效应及电活化技术[D]. 北京:中国地质大学, 2012.
    [71] CHEN L, JIN S, FALLGREN P H , et al. Passivation of ZVI by denitrifying bacteria and the impact on trichloroethene reduction in groundwater[J]. Water Science and Technology, 2013,67(6):1254-1259.
    [72] 王伟宁, 许光泉, 史红伟 , 等. PRB修复地下水污染的研究综述[J]. 能源环境保护, 2009,23(3):9-13.

    WANG W N, XU G Q, SHI H W , et al. Status review of groundwater pollution restoration by permeable reactive barrier[J]. Energy Environmental Protection, 2009,23(3):9-13.
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  • 收稿日期:  2019-07-24
  • 刊出日期:  2020-03-20

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