Study on permeable reactive barrier technology for the remediation of polluted groundwater
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摘要: 地下水污染已成为我国严峻的环境问题,治理污染地下水工作迫在眉睫。可渗透反应墙(permeable reactive barrier,PRB)技术是污染地下水修复的新兴技术,具有治理效果好、造价低廉、对生态环境影响小等特点,能够有效去除地下水中的有机氯化物、重金属和无机离子等。PRB技术在美国已广泛应用到工程领域并实现商业化,在我国目前处于实验室研究和现场示范应用阶段。综述了PRB技术的原理、结构类型、活性填料、修复机理和工程应用,指出PRB系统长期有效运行存在的技术问题,以及PRB技术的应用前景和重点研究方向,以期为PRB技术在我国的研发和推广应用及地下水污染治理提供参考。
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关键词:
- 可渗透反应墙(PRB) /
- 地下水污染 /
- 零价铁(ZVI)
Abstract: With the increasingly serious environmental problem of groundwater pollution in China, the remediation of polluted groundwater is extremely urgent. Permeable reactive barrier(PRB)is a new technology for groundwater remediation of contaminated sites, which can effectively remove organic chlorides, heavy metals and inorganic ions with the advantages of good treatment effect, low cost and little impact on ecology and environment. PRB technology has been widely used in the engineering field and commercialized in the United States, which is currently used in the laboratory research and field-pilot demonstration in China. The contaminants-removing principles, structure types, active packing materials, reactive mechanism and engineering application of PRB system were summarized, and the technical issues of long-term effective performance of PRB system, as well as the application prospects and key research directions of PRB technology were pointed out, so as to provide references for the R&D and application of PRB technology and the remediation of polluted groundwater in China.-
Key words:
- PRB /
- groundwater pollution /
- zero valent iron (ZVI)
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[1] 姜建军 . 中国地下水污染现状与防治对策[J]. 环境保护, 2007,381(19):16-17. [2] 中国环境保护产业协会. 污染场地修复技术目录(第一批)[A]. 北京:中国环境保护产业发展报告(2014), 2015. [3] 生态环境部. 污染地块地下水修复和风险管控技术导则:HJ 25.6—2019[S]. 北京:中国环境出版集团 2019. [4] 隋红, 李洪, 李鑫钢 , 等. 有机污染土壤和地下水修复[M]. 北京:科学出版社 2013. [5] 刘玲, 徐文彬, 甘树福 . PRB技术在地下水污染修复中的研究进展[J]. 水资源保护, 2006,22(6):76-80.LIU L, XU W B, GAN S F . Study on permeable reactive barrier for remediation of groundwater contamination[J]. Water Resources Protection, 2006,22(6):76-80. [6] 陆泗进, 王红旗, 杜琳娜 . 污染地下水原位治理技术-透水性反应墙法[J]. 环境污染与防治, 2006,28(6):452-457.LU S J, WANG H Q, DU L N . In situ remediation of contaminated underground water:permeable reactive barrier[J]. Environmental Pollution & Control, 2006,28(6):452-457. [7] 柏耀辉, 张淑娟 . 地下水污染修复技术:可渗透反应墙[J]. 云南环境科学, 2005,24(4):51-54.BAI Y H, ZHANG S J . Permeable reactive barrier as a remedy technology of contaminated groundwater[J]. Yunnan Environmental Science, 2005,24(4):51-54. [8] 束善治, 袁勇 . 污染地下水原位处理方法:可渗透反应墙[J]. 环境污染治理技术与设备, 2002,3(1):47-51.SHU S Z, YUAN Y . In situ remediation of contaminated ground water:permeable reactive barrier[J]. Techniques and Equipment for Environmental Pollution Control, 2002,3(1):47-51. [9] 翟亚丽, 王兴润, 舒新前 , 等. PRB技术修复铬污染地下水的试验研究[J]. 环境工程, 2012,30(增刊2):54-58.ZHAI Y L, WANG X R, SHU X Q , et al. Experimental study on the remediation of chromium contaminated groundwater with PRB media[J]. Environmental Engineering, 2012,30(Suppl 2):54-58. [10] 刘翔, 唐翠梅, 陆兆华 , 等. 零价铁PRB技术在地下水原位修复中的研究进展[J]. 环境科学研究, 2013,26(12):1309-1315.LIU X, TANG C M, LU Z H , et al. Progress of Fe 0-PRB in remediation of contaminated groundwater [J]. Research of Environmental Sciences, 2013,26(12):1309-1315. [11] 陈梦舫, 钱林波, 晏井春 , 等. 地下水可渗透反应墙修复技术原理、设计及应用[M]. 北京:科学出版社 2017. [12] POWELL R M, PULS R W, BLOWES D W , et al. Permeable reactive barrier technologies for contaminant remediation[R]. Washington DC:US Environmental Protection Agency, 1998. [13] LUDWIG R D, SMYTH D J, BLOWES D W , et al. Treatment of arsenic,heavy metals,and acidity using a mixed ZVI-compost PRB[J]. Environmental Science and Technology, 2009,43(6):1970-1976. [14] VOGAN J L, FOCHT R M, CLARK D K , et al. Performance evaluation of a permeable reactive barrier for remediation of dissolved chlorinated solvents in groundwater[J]. Journal of Hazardous Materials, 1999,68(1∕2):97-108. [15] BARTON C S, STEWART I, MORRIS K , et al. Performance of three resin-based materials for treating uranium-contaminated groundwater within a PRB[J]. Journal of Hazardous Materials, 2004,116(3):191-204. [16] SU C M, PULS R W . Nitrate reduction by zerovalent iron:effects of formate,oxalate,citrate,chloride,sulfate,borate,and phosphate[J]. Environmental Science and Technology, 2004,38(9):2715-2720. [17] TURNER M, DAVE N M, MODENA T , et al. Permeable reactive barriers:lessons learned∕new directions[M]. Washington DC:The Interstate Technology and Regulatory Council, 2005. [18] 邱锦安, 张澄博, 李洪艺 , 等. PRB在地下水污染修复中的应用与研究进展[J]. 广东农业科学, 2011,38(13):144-146.QIU J A, ZHANG C B, LI H Y , et al. Application and research progress of PRB in remediation of polluted groudwater[J]. Guangdong Agricultural Sciences, 2011,38(13):144-146. [19] 李志红, 王广才, 史浙明 , 等. 渗透反应格栅技术综述:填充材料实验研究、修复技术实例和系统运行寿命[J]. 环境化学, 2017,36(2):316-327.LI Z H, WANG G C, SHI Z M , et al. Review of permeable reactive barrier technology:the experimental study of filling materials,the example of remediation technology,and the longevity of the system[J]. Environmental Chemistry, 2017,36(2):316-327. [20] GAVASKAR A, GUPTA N, SASS B , et al. Design guidance for application of permeable reactive barriers for groundwater remediation[R]. Columbus,Ohio:Battelle, 2000. [21] BLOWES D W, PTACEK C J, CHERRY J A , et al. Passive remediation of groundwater using in situ treatment curtains[M]. ASCE:Geotechnical Special Publication, 1995. [22] YOU Y, HAN J, CHIU P C , et al. Removal and inactivation of waterborne viruses using zerovalent iron[J]. Environmental Science and Technology, 2005,39(2):9263-9269. [23] OBIRI-NYARKO F, GRAJALES-MESA S J, MALINA G . An overview of permeable reactive barriers for in situ sustainable groundwater remediation[J]. Chemosphere, 2014,111(1):243-259. [24] 张晓慧, 葛芳州, 董玉婧 , 等. 可渗透反应墙原位修复污染地下水研究进展[J]. 工业用水与废水, 2015,46(3):1-5.ZHANG X H, GE F Z, DONG Y J , et al. Research progress of permeable reactive barriers for in situ groundwater remediation[J]. Industrial Water & Wastewater, 2015,46(3):1-5. [25] 刘菲, 陈亮, 王广才 , 等. 地下水渗透反应格栅技术发展综述[J]. 地球科学进展, 2015,30(8):863-877.LIU F, CHEN L, WANG G C , et al. Permeable reactive barrier for groundwater pollution remediation:an overview[J]. Advances in Earth Science, 2015,30(8):863-877. [26] FARRELL J, KASON M, MELITAS N , et al. Investigation of the long-term performance of zero-valent iron for reductive dechlorination of trichloroethylene[J]. Environmental Science and Technology, 2000,34(3):514-521. [27] PARBS A, EBERT M, DAHINKE A . Long-term effects of dissolved carbonate species on the degradation of trichloroethylene by zerovalent iron[J]. Environmental Science and Technology, 2007,41(1):291-296. [28] RITTER K, ODZIEMKOWSKI M S, SIMPGRAGA R , et al. An in situ study of the effect of nitrate on the reduction of trichloroethylene by granular iron[J]. Journal of Contaminant Hydrology, 2003,39(5):1309-1318. [29] CHEN J L, AL-ABED S R, RYAN J A , et al. Effects of pH on dechlorination of trichloroethylene by zero-valent iron[J]. Journal of Hazardous Materials, 2001,83(3):243-254. [30] GILLHAM R W, VOGAN J, GUI L , et al. Iron barrier walls for chlorinated solvent remediation[M] ∕∕STROO H,WARD C H.Situ remediation of chlorinated solvent plumes.NewYork:Springer-Verlag, 2010: 537-571. [31] GILLHAM R W . Enhanced degradation of halogenated aliphatics by zero-valent iron[J]. Ground Water, 1994,32(6):958-967. [32] BLOWES D W, PTACEK C J, BENNER S G , et al. Treatment of inorganic contaminants using permeable reactivebarriers[J]. Journal of Contaminant Hydrology, 2000,45(1):123-137. [33] CONCA J L, WRIGHT J . An apatiteⅡpermeable reactive barrier to remediate groundwater containing Zn,Pb and Cd[J]. Applied Geochemistry, 2006,21(12):1288-1300. [34] 刘凤莲, 刘兴荣 . 零价铁脱除水中六价铬的实验研究[J]. 环境与健康杂志, 2009,26(2):139-141.LIU F L, LIU X R . Removal of chromium(Ⅵ) with zero valent iron:an experimental research[J]. Journal of Environment and Health, 2009,26(2):139-141. [35] 李雅, 张增强, 唐次来 , 等. Fe 0去除地下水中六价铬的研究 [J]. 中国农业大学学报, 2011,16(2):160-164.LI Y, ZHANG Z Q, TANG C L , et al. Simulation on reduction of hexavalent chromium from groundwater using zero valent iron[J]. Journal of China Agricultural University, 2011,16(2):160-164. [36] 王兴润, 翟亚丽, 舒新前 , 等. 修复铬污染地下水的可渗透反应墙介质筛选[J]. 环境工程学报, 2013,7(7):2523-2528.WANG X R, ZHAI Y L, SHU X Q , et al. Selection of permeable reactive barrier media for remediation of contaminated groundwater with chromium[J]. Chinese Journal of Environmental Engineering, 2013,7(7):2523-2528. [37] HOSSEINIS M, ATAIE-ASHTIANI B, KHOLGHIAM . Nitrate reduction by nano-Fe∕Cu particles in packed column[J]. Desalination, 2011,276(1∕2∕3):214-221. [38] MOON H S, AHN K H, LEE S , et al. Use of autotrophic sulfuroxidizers to remove nitrate from bank filtrate in a permeable reactive barrier system[J]. Environmental Pollution, 2004,129(3):499-507. [39] 张增强, 唐次来, 邵淼 , 等. Fe 0去除地下水中硝酸盐的条件研究 [J]. 中国农业大学学报, 2008,13(6):37-42.ZHANG Z Q, TANG C L, SHAO M , et al. Parameters optimization for removal of nitrate in groundwater by zero-valent iron[J]. Journal of China Agricultural University, 2008,13(6):37-42. [40] 孟凡生, 王业耀, 张星星 . 零价铁PRB修复硝酸盐和铬复合污染地下水[J]. 环境科学研究, 2012,25(11):1279-1284.MENG F S, WANG Y Y, ZHANG X X , et al. Remediation of ground water contaminated by nitrate nitrogen and chromium using zero-valent iron PRB technology[J]. Research of Environmental Sciences, 2012,25(11):1279-1284. [41] FU F, DIONYSIOS D D, LIU H , et al. The use of zero-valent iron for groundwater remediation and wastewater treatment:a review[J]. Journal of Hazardous Materials, 2014,267(3):194-205. [42] MANDJINY S, ZOUBOULIS A I, MATIS K A . Removal of cadmium from dilute solutions by hydroxyapatite:Ⅰ.sorption studies[J]. Separation Science and Technology, 1995,30(15):2963-2978. [43] XU Y, SCHWARTZ F W, TRAINA S J . Sorption of Zn 2+and Cd 2+on hydroxyapatite surfaces [J]. Separation Science and Technology, 1994,28(8):1472-1480. [44] WOINARSKI A Z, SNAPE I, STEVENS G W , et al. The effects of cold temperature on copper ion exchange by natural zeolite for use in a permeable reactive barrier in Antarctica[J]. Cold Regions Science and Technology, 2003,37(2):159-168. [45] ARORA M, SNAPE I, STEVENS G W . The effect of temperature on toluene sorption by granular activated carbon and its use in permeable reactive barriers in cold regions[J]. Cold Regions Science and Technology, 2011,66(1):12-16. [46] XIN B P, WU C H, LIN C W . Bioaugmented remediation of high concentration BTEX-contaminated groundwater by permeable reactive barrier with immobilized bead[J]. Journal of Hazardous Materials, 2013,244∕245:765-772. [47] LI S, HUANG G, KONG X , et al. Ammonium removal from groundwater using a zeolite permeable reactive barrier:a pilot-scale demonstration[J]. Water Science and Technology, 2014,70(9):1540-1547. [48] VESELA L, NEMECEK J, SIGLOVA M , et al. The biofiltration permeable reactive barrier:practical experience from Synthesia[J]. International Biodeterioration & Biodegradation, 2006,58(3∕4):224-230. [49] O’HANNESIN S F, GILLHAM R W, VOGAN J L . TCE degradation in groundwater using zero-valent iron[R]. Washington DC:American Chemical Society Extended Abstract,Industrial and Engineering Chemistry Division, 1995:55-58. [50] USCG. In situ permeable reactive barrier for treatment of contaminated groundwater at the US Coast Guard Support Center,Elizabeth City,North Carolina[R]. Elizabeth City,NC:US Coast Guard Support Center, 1998. [51] VANSTONE N, PRZEPIORA A, VOGAN J , et al. Monitoring trichloroethene remediation at an iron permeable reactive barrier using stable carbon isotopic analysis[J]. Journal of Contaminant Hydrology, 2005,78(4):313-325. [52] ZOLLA V, FREYRIA F S, SETHI R , et al. Hydrogeochemical and biological processes affecting the long-term performance of an iron-based permeable reactive barrier[J]. Journal of Environmental Quality, 2009,38(3):897-908. [53] PHILLIPS D H, NOOTEN T N, BASTIAENS L , et al. Ten year performance evaluation of a field-scale zero-valent iron permeable reactive barrier installed to remediate trichloroethene contaminated groundwater[J]. Environmental Science and Technology, 2010,44(10):3861-3869. [54] MUCHITSCH N, VAN NOOTEN T, BASTIAENS L , et al. Integrated evaluation of the performance of a more than seven year old permeable reactive barrier at a site contaminated with chlorinated aliphatic hydrocarbons(CAHs)[J]. Journal of Contaminant Hydrology, 2011,126(3):258-270. [55] WANNER C, ZINK S, EGGENBERGER U , et al. Assessing the Cr(Ⅵ) reduction efficiency of a permeable reactive barrier using Cr isotope measurements and 2D reactive transport modeling[J]. Journal of Contaminant Hydrology, 2012,131(1∕2∕3∕4):54-63. [56] HOU G, LIU F, LIU M , et al. Performance of a permeable reactive barrier for in situ removal of ammonium in groundwater[J]. Water Science and Technology:Water Supply, 2014,14(4):585-592. [57] 李圣品, 刘菲, 黄国鑫 , 等. 傍河型水源井氨氮阻断与去除工程设计案例分析[J]. 环境科学学报, 2015,35(8):2471-2480.LI S P, LIU F, HUANG G X , et al. Remediation and interception of riverside water wells contaminated by ammonium-nitrogen:an engineering case study[J]. Acta Scientiae Circumstantiae, 2015,35(8):2471-2480. [58] 田雷 . 复合介质PRB去除地下水中氯代烃和苯系物混合污染研究[D]. 北京:中国地质大学(北京),2014. [59] 腾应, 陈梦舫 . 稀土尾矿库区地下水污染风险评估与防控修复技术[M]. 北京:科学出版社 2016. [60] 中国科学院南京土壤研究所宋昕团队. 原长沙铬盐厂可渗透反应墙(PRB)原位修复铬污染地下水[EB∕OL].(2019-04-04)[2019-07-14]. [61] 张桂华, 潘伟斌, 秦玉洁 , 等. 受污染地下水可渗透反应墙修复技术研究[J]. 农业环境科学学报, 2005,24(增刊1):153-157.ZHANG G H, PAN W B, QIN Y J , et al. Study on the reaction media of PRB technology in the remediation of polluted groundwater[J]. Journal of Agro-Environment Science, 2005,24(Suppl 1):153-157. [62] WILKIN R T, PULS R W, SEWELL G W . Long-term performance of permeable reactive barriers using zero-valent iron:geochemical and microbiological effects[J]. Ground Water, 2003,41(4):493-503. [63] LU X, LI M, TANG C , et al. Electrochemical depassivation for recovering Fe0 reactivity by Cr(Ⅵ)removal with a permeable reactive barrier system[J]. Journal of Hazardous Materials, 2012,213∕214:355-360. [64] GEIGER C L, CLAUSEN C, REINHART D R , et al. Using ultrasound for restoring iron activity in permeable reactive barriers[J]. ACS Symposium Series, 2002,837:286-303. [65] VIKESLAND P J, KLAUSEN J, ZIMMERMANN H , et al. Longevity of granular iron in groundwater treatment processes:changes in solute transport properties over time[J]. Journal of Contaminant Hydrology, 2003,64(1):3-33. [66] 陶征义, 隋天娥 . 酸性矿山排水被动处理方法研究进展[J]. 环境科学与管理, 2009,34(3):96-99.TAO Z Y, SUI T E . The passive treatment system of acid mine drainage research progress[J]. Environmental Science and Management, 2009,34(3):96-99. [67] NOUBACTEP C . Review:the fundamental mechanism of aqueous contaminant removal by metallic iron[J]. Water SA, 2010,36(5):663-670. [68] MATHESON L J, TRATNYEK P G . Reductive dehalogenation of chlorinated methanes by iron metal[J]. Environmental Science and Technology, 1994,28(12):2045-2053. [69] TÁMARA M L, BUTLER E C . Effects of iron purity and groundwater characteristics on rates and products in the degradation of carbon tetrachloride by iron metal[J]. Environmental Science and Technology, 2004,38(6):1866-1876. [70] 陈亮 . 零价铁渗透反应格栅中铁的微生物钝化效应及电活化技术[D]. 北京:中国地质大学, 2012. [71] CHEN L, JIN S, FALLGREN P H , et al. Passivation of ZVI by denitrifying bacteria and the impact on trichloroethene reduction in groundwater[J]. Water Science and Technology, 2013,67(6):1254-1259. [72] 王伟宁, 许光泉, 史红伟 , 等. PRB修复地下水污染的研究综述[J]. 能源环境保护, 2009,23(3):9-13.WANG W N, XU G Q, SHI H W , et al. Status review of groundwater pollution restoration by permeable reactive barrier[J]. Energy Environmental Protection, 2009,23(3):9-13.
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