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基于不同自由基的高级氧化技术对水中诺氟沙星的去除效果

许若梦 吴桐 锁瑞娟 钱雅洁

许若梦, 吴桐, 锁瑞娟, 钱雅洁. 基于不同自由基的高级氧化技术对水中诺氟沙星的去除效果[J]. 环境工程技术学报, 2020, 10(3): 433-439. doi: 10.12153/j.issn.1674-991X.20190177
引用本文: 许若梦, 吴桐, 锁瑞娟, 钱雅洁. 基于不同自由基的高级氧化技术对水中诺氟沙星的去除效果[J]. 环境工程技术学报, 2020, 10(3): 433-439. doi: 10.12153/j.issn.1674-991X.20190177
XU Ruomeng, WU Tong, SUO Ruijuan, QIAN Yajie. Removal performance of norfloxacin from waters by advanced oxidation processes based on different free radicals[J]. Journal of Environmental Engineering Technology, 2020, 10(3): 433-439. doi: 10.12153/j.issn.1674-991X.20190177
Citation: XU Ruomeng, WU Tong, SUO Ruijuan, QIAN Yajie. Removal performance of norfloxacin from waters by advanced oxidation processes based on different free radicals[J]. Journal of Environmental Engineering Technology, 2020, 10(3): 433-439. doi: 10.12153/j.issn.1674-991X.20190177

基于不同自由基的高级氧化技术对水中诺氟沙星的去除效果

doi: 10.12153/j.issn.1674-991X.20190177
详细信息
    作者简介:

    许若梦(1998—),女,研究方向为高级氧化技术,951985273@qq.com

    通讯作者:

    钱雅洁 E-mail: yqian@dhu.edu.cn

  • 中图分类号: X703

Removal performance of norfloxacin from waters by advanced oxidation processes based on different free radicals

More Information
    Corresponding author: QIAN Yajie E-mail: yqian@dhu.edu.cn
  • 摘要: 抗生素在水中的赋存浓度较低,难以被常规的城市污水处理系统有效去除。考察了紫外光联合氯(UV/氯)、双氧水(UV/H2O2)、过硫酸盐(UV/PS) 3种高级氧化体系对诺氟沙星(NFX)的去除效果。结果表明:UV/氯体系降解NFX相比于其他2种具有显著的高效性,当溶液初始pH为7、氯浓度为30 μmol/L时,NFX在2 min内的去除率可达98.67%,相同氧化剂浓度下,UV/H2O2和UV/PS体系10 min内对NFX的去除率仅为41.41%和65.73%;对于UV/氯体系,NFX的去除率随氯浓度的升高而上升,同时考虑成本,最优氯浓度为30 μmol/L;pH影响3种体系对NFX的去除速率,但效果不同,对于UV/氯体系,强碱性条件有利于NFX的去除,对于UV/H2O2和UV/PS体系,中性及弱碱性更有利于NFX的去除;水体基质Cl-对UV/氯体系去除NFX有抑制作用,但对UV/H2O2和UV/PS体系影响不大; HCO 3 - 对3种体系去除NFX均有抑制作用。

     

  • [1] 吴曼琳 . 城市水环境中药品和个人护理用品的研究现状和去除[J]. 净水技术, 2018,37(增刊1):230-234.

    WU M L . Research status and removal of pharmaceuticals and personal care products in urban water environment[J]. Water Purification Technology, 2018,37(Suppl 1):230-234.
    [2] 施文杰, 王长友, 杨锐 . 诺氟沙星对盐生杜氏藻、新月菱形藻和小球藻的生态毒性效应[J]. 海洋环境科学, 2019,38(1):1-6.

    SHI W J, WANG C Y, YANG R . Effects of norfloxacin on Dunaliella salina,Nitzschia closterium F. minutissima and Chlorella vulgaris[J]. Marine Environmental Science, 2019,38(1):1-6.
    [3] 郭隽, 张亚雷, 周雪飞 , 等. 城市污水中氟氟喹诺酮类抗生素药物的来源与去除研究进展[J]. 环境污染与防治, 2016,38(2):75-80.

    GUO J, ZHANG Y L, ZHOU X F , et al. Occurrence and removal of fluoroquinolones in municipal sewage:a review[J]. Environmental Pollution & Control, 2016,38(2):75-80.
    [4] 李华瑞, 梁立锐, 程士 , 等. 水中诺氟沙星污染现状及其处理方法研究进展[J]. 山东化工, 2015,44(15):60-62.

    LI H R, LIANG L R, CHENG S , et al. Research progress in the pollution situation and treatment methods for norfloxacin in water[J]. Shandong Chemical Industry, 2015,44(15):60-62.
    [5] 陈凯杰 . 试论饮用水中抗生素去除技术研究进展[J]. 科技经济导刊, 2018,26(8):103-105.
    [6] 张玮玮, 弓爱君, 邱丽娜 , 等. 废水中抗生素降解和去除方法的研究进展[J]. 中国抗生素杂志, 2013,38(6):401-410.

    ZHANG W W, GONG A J, QIU L N , et al. Processes of degradation and removal methods of antibiotics from waste water[J]. Chinese Journal of Antibiotics, 2013,38(6):401-410.
    [7] 李博 . 莲杆活性炭对诺氟沙星吸附性的研究[D]. 济南:山东大学, 2011.
    [8] DORIVAL-GARCÍA N, ZAFRA-GOMEZ A, NAVALON A , et al. Removal and degradation characteristics of quinolone antibiotics in laboratory-scale activated sludge reactors under aerobic,nitrifying and anoxic conditions[J]. Journal of Environmental Management, 2013,120:75-83.
    doi: 10.1016/j.jenvman.2013.02.007 pmid: 23507246
    [9] YANG X, FLOWERS R C, WEINBERG H S , et al. Occurrence and removal of pharmaceuticals and personal care products(PPCPs) in an advanced wastewater reclamation plant[J]. Water Research, 2011,45(16):5218-5228.
    doi: 10.1016/j.watres.2011.07.026 pmid: 21864879
    [10] 赵丽红, 聂飞 . 水处理高级氧化技术研究进展[J]. 科学技术与工程, 2019,19(10):1-9.

    ZHAO L H, NIE F . Research progress in advanced oxidation technology for water treatment[J]. Science Technology and Engineering, 2019,19(10):1-9.
    [11] 余臻 . 光催化氧化技术在水处理中的应用及研究进展[J]. 绿色科技, 2019(8):62-63.
    [12] 周明毅, 魏琛, 盛贵尚 , 等. 紫外活化过硫酸钠降解水中三唑酮的效能[J]. 环境工程学报, 2019,13(4):810-817.

    ZHOU M Y, WEI C, SHENG G S , et al. Degradation of triadimefon in water by UV irradiation-activated sodium persulfate process[J]. Chinese Journal of Environmental Engineering, 2019,13(4):810-817.
    [13] BARAKAT M A, TSENG J M, HUANG C P . Hydrogen peroxide-assisted photocatalytic oxidation of phenolic compounds[J]. Applied Catalysis B:Environmental, 2005,59(1):99-104.
    [14] CRITTENDEN J C, HU S M, HAND D W , et al. A kinetic model for H2O2/UV process in a completely mixed batch reactor[J]. Water Research, 1999,33(10):2315-2328.
    doi: 10.1080/03601234.2019.1571365 pmid: 30729853
    [15] 朱欢欢, 孙韶华, 冯桂学 , 等. 紫外联用高级氧化技术处理饮用水应用进展[J]. 水处理技术, 2019,45(3):1-7.
    [16] DING W, BOLTON J R, HOFMANN R . Medium pressure UV combined with chlorine advanced oxidation for trichloroethylene destruction in a model water[J]. Water Research, 2012,46(15):4677-4686.
    doi: 10.1016/j.watres.2012.06.007
    [17] XIANG Y Y, FANG J Y, SHANG C . Kinetics and pathways of ibuprofen degradation by the UV/chlorine advanced oxidation process[J]. Water Research, 2016,90:301-308.
    doi: 10.1016/j.watres.2015.11.069 pmid: 26748208
    [18] SICHEL C, GARCIA C, ANDRE K . Feasibility studies:UV/chlorine advanced oxidation treatment for the removal of emergin contaminants[J]. Water Research, 2011,45(19):6371-6380.
    doi: 10.1016/j.watres.2011.09.025 pmid: 22000058
    [19] 王中兰, 陈菊, 冯碧敏 . 高效液相色谱法测定诺氟沙星滴眼液中诺氟沙星含量[J]. 哈尔滨医药, 2006,26(1):10-11.
    [20] WATTS M J, LINDEN K G . Chlorine photolysis and subsequent OH radical production during UV treatment of chlorinated water[J]. Water Research, 2007,41(13):2871-2878.
    doi: 10.1016/j.watres.2007.03.032 pmid: 17498769
    [21] 伊学农, 方佳男, 高玉琼 , 等. 紫外线-氯联合高级氧化体系降解水中的萘普生[J]. 环境工程学报, 2019,13(5):1030-1037.

    YI X N, FANG J N, GAO Y Q , et al. Degradation of naproxen in water by UV/chlorine advanced oxidation process[J]. Chinese Journal of Environmental Engineering, 2019,13(5):1030-1037.
    [22] NETA P, HUIE R E, ROSS A B . Rate constants for reactions of inorganic radicals in aqueous solution[J]. Journal of Physical and Chemical Reference Data, 1988,17(3):1027-1284.
    [23] GUO K H, WU Z H, YAN S W , et al. Comparison of the UV/chlorine and UV/H2O2 processes in the degradation of PPCPs in simulated drinking water and wastewater:kinetics,radical mechanism and energy requirements[J]. Water Research, 2018,147:184-194.
    doi: 10.1016/j.watres.2018.08.048 pmid: 30312791
    [24] WANG W L, WU Q Y, HUANG N , et al. Synergistic effect between UV and chlorine(UV/chlorine)on the degradation of carbamazepine:influence factors and radical species[J]. Water Research, 2016,98:190-198.
    doi: 10.1016/j.watres.2016.04.015 pmid: 27105033
    [25] 李国亭, 宋海燕, 刘秉涛 , 等. 光催化过程中羟基自由基的产生与效能[J]. 环境工程学报, 2012,6(10):3388-3392.

    LI G T, SONG H Y, LIU B T , et al. Production and contribution of hydroxyl radicals in photocatalytic oxidation process[J]. Chinese Journal of Environmental Engineering, 2012,6(10):3388-3392.
    [26] 喻杰, 叶志伟, 党文悦 , 等. 紫外波长对UV/Cl2高级氧化去除水中有机物的影响[J]. 环境工程学报, 2019,13(3):577-585.

    YU J, YE Z W, DANG W Y , et al. Effect of ultraviolet wavelength on organic matter removal from water by UV/Cl2 advanced oxidation[J]. Chinese Journal of Environmental Engineering, 2019,13(3):577-585.
    [27] YANG Y, CAO Y, JIANG J , et al. Comparative study on degradation of propranolol and formation of oxidation products by UV/H2O2 and UV/persulfate(PDS)[J]. Water Research, 2019,149:543-552.
    doi: 10.1016/j.watres.2018.08.074 pmid: 30502740
    [28] WANG A Q, LIN Y L, XU B , et al. Kinetics and modeling otiodoform degradation during UV/chlorine advanced oxidation process[J]. Chemical Engineering Journal, 2017,323:312-319.
    doi: 10.1016/j.watres.2016.08.011 pmid: 27544349
    [29] JAYSON G, PARSONS B, SWALLOW A J . Some simple,highly reactive,inorganic chlorinederivatives in aqueous solution:their formation using pulses of radiation and their role in the mechanism of the Fricke dosimeter[J]. Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, 1973,69:1597-1607.
    [30] YUAN R X, WANG Z H, HU Y , et al. Probing the radical chemistry in UV/persulfate-based saline wastewater treatment:kinetics modeling and byproducts ide.pngication[J]. Chemosphere, 2014,109:106-112.
    doi: 10.1016/j.chemosphere.2014.03.007 pmid: 24873714
    [31] DENG J, SHAO Y S, GAO N Y , et al. Degradation of the antiepileptic drug carbamazepine upon different UV-based advanced oxidation processes in water[J]. Chemical Engineering Journal, 2013,222:150-158.
    doi: 10.1016/j.cej.2013.02.045
    [32] YANG Y, JIANG J, LU XL , et al. Production of sulfate radical and hydroxyl radical by reaction of ozone with peroxymonosulfate:a novel advanced oxidation process[J]. Environmental Science & Technology, 2015,49(12):7300-7339.
    doi: 10.1021/es506362e pmid: 25988821
    [33] FANG J Y, FU Y, SHANG C . The roles of reactive species in micropollutant degradation in the UV/free chlorine system[J]. Environmental Science & Technology, 2014,48(3):1859-1868.
    doi: 10.1021/es4036094 pmid: 24400681
    [34] BUXTON G V, GREENSTOCK C L, HELMAN WP , et al. Critical review of rate constants for reactions of hydrated electrons,hydrogen atoms and hydroxyl radicals (·OH/·O-) in aqueous solution [J]. Journal of Physical and Chemical Reference Data, 1988,17(2):513-886.
    [35] WU Z, GUO K, FANG J , et al. Factors affecting the roles of reactive species in the degradation of micropollutants by the UV/chlorine process[J]. Water Research, 2017,126:351-360.
    doi: 10.1016/j.watres.2017.09.028 pmid: 28985600
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  • 收稿日期:  2019-10-20
  • 刊出日期:  2020-05-20

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