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ICP-MS法测定PM2.5中无机元素浓度及污染特征分析

王婉,  王立,  张晓,  张宝军,  曹振红,  张佳浩,  朱媛媛

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文章导航 > 环境工程技术学报  > 2020 >  10(4): 631-638
王婉, 王立, 张晓, 张宝军, 曹振红, 张佳浩, 朱媛媛. ICP-MS法测定PM2.5中无机元素浓度及污染特征分析[J]. 环境工程技术学报, 2020, 10(4): 631-638. doi: 10.12153/j.issn.1674-991X.20190181
引用本文: 王婉, 王立, 张晓, 张宝军, 曹振红, 张佳浩, 朱媛媛. ICP-MS法测定PM2.5中无机元素浓度及污染特征分析[J]. 环境工程技术学报, 2020, 10(4): 631-638. doi: 10.12153/j.issn.1674-991X.20190181
shu
WANG Wan, WANG Li, ZHANG Xiao, ZHANG Baojun, CAO Zhenhong, ZHANG Jiahao, ZHU Yuanyuan. Determination of inorganic elemental concentrations in PM2.5 by ICP-MS and the analysis of pollution characteristics[J]. Journal of Environmental Engineering Technology, 2020, 10(4): 631-638. doi: 10.12153/j.issn.1674-991X.20190181
Citation: WANG Wan, WANG Li, ZHANG Xiao, ZHANG Baojun, CAO Zhenhong, ZHANG Jiahao, ZHU Yuanyuan. Determination of inorganic elemental concentrations in PM2.5 by ICP-MS and the analysis of pollution characteristics[J]. Journal of Environmental Engineering Technology, 2020, 10(4): 631-638. doi: 10.12153/j.issn.1674-991X.20190181
shu

ICP-MS法测定PM2.5中无机元素浓度及污染特征分析

doi: 10.12153/j.issn.1674-991X.20190181
  • 1.

    中国环境科学研究院

  • 2.

    国标(北京)检验认证有限公司

  • 3.

    唐山市环境保护研究所

  • 4.

    中国环境监测总站

详细信息
    作者简介:

    王婉(1972—),女,助理研究员,博士,主要从事大气颗粒物环境化学分析及污染物源解析研究,wangwan@craes.org.cn

    通讯作者:

    朱媛媛 E-mail: zhuyy@cnemc.cn

  • 中图分类号: X513;X831

Determination of inorganic elemental concentrations in PM2.5 by ICP-MS and the analysis of pollution characteristics

  • 1.

    Chinese Research Academy of Environmental Sciences

  • 2.

    Guobiao (Beijing) Testing and Certification Co., Ltd.

  • 3.

    Tangshan Environmental Protection Research Institute

  • 4.

    China National Environmental Monitoring Centre

More Information
    Corresponding author: ZHU Yuanyuan E-mail: zhuyy@cnemc.cn

    摘要
  • 摘要: 采用微波消解、电感耦合等离子体质谱(ICP-MS)法同时直接测定了PM2.5中23种无机元素的浓度,并对消解方法、ICP-MS工作参数及条件进行了优化和选择。该方法的检出限为0.01~10.00 ng/mL,定量检出限为0.04~40.00 ng/mL。采用该方法测定了2017年10月—2018年1月秋冬季唐山市3个监测点位的PM2.5滤膜样品,结果表明:地壳元素中Si浓度最高,为2.30 μg/m3,大多元素浓度在采暖前高于采暖后;重金属元素中Zn浓度最高,为0.48 μg/m 3,大多元素浓度在本次观测的11月和12月较高;所测元素浓度与其他文献数据具有可比性,说明该方法适用于环境大气PM2.5中的无机多元素分析测试。

     

    Abstract: The concentrations of 23 inorganic elements in PM2.5 were determined directly and simultaneously by inductively coupled plasma mass spectrometry (ICP-MS) combined with microwave digestion. The working parameters and conditions of the digestion and ICP-MS were optimized and selected. The detection limits ranged from 0.01 to 10.00 ng/mL and the quantitative detection limits were at the range of 0.04-40.00 ng/mL. PM2.5 membrane filter samples, collected in three monitoring sites of Tangshan City from October of 2017 to January of 2018, were measured by the method. and the results of the analytical data were shown as follows. The concentration of Si was 2.30 μg/m3, which was the highest value among the measured crustal elements. Most elements had higher concentrations during the before-heating period than during the heating period. The concentration of Zn was 0.48 μg/m 3, which was the highest value among the heavy metals, and the concentrations of these heavy metals were mostly higher in November and December during this observation campaign. The measured elemental concentrations were mostly comparable to other literature data, which showed that this method was suitable for inorganic multi-element analysis of ambient atmospheric PM2.5.

     

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    • 参考文献(33)
  • [1] POSCHL U. Formation and decomposition of nonhazardous chemical components contained in atmospheric aerosol particles[J]. Journal Aerosol Medicine, 2002,15:203-212.
    doi: 10.1089/089426802320282329
    [2] HE K B, YANG F M, MA Y L, et al. The characteristics of PM2.5 in Beijing,China[J]. Atmospheric Environment, 2001,35(29):4959-4970.
    doi: 10.1016/S1352-2310(01)00301-6
    [3] CHAN C K, YAO X H. Air pollution in mega cities in China[J]. Atmospheric Environment, 2008,42(1):1-42.
    doi: 10.1016/j.atmosenv.2007.09.003
    [4] MAENHAUT W. New directions:future needs for global monitoring and research of aerosol chemical composition[J]. Atmospheric Environment, 2008,42(5):1070-1072.
    doi: 10.1016/j.atmosenv.2007.11.038
    [5] PUTAUD J P, RAES F, DINGENEN R V, et al. A European aerosol phenomenology:2.chemical characteristics of particulate matter at kerbside,urban,rural and background sites in Europe[J]. Atmospheric Environment, 2004,38(16):2579-2595.
    doi: 10.1016/j.atmosenv.2004.01.041
    [6] MAENHAUT W, RAES N, CHI X G, et al. Chemical composition and mass closure for PM2.5 and PM10 aerosols at K-puszta,Hungary,in summer 2006[J]. X-Ray Spectrometry, 2008,37(2):193-197.
    doi: 10.1002/(ISSN)1097-4539
    [7] 郑玫, 张延君, 闫才青, 等. 中国PM2.5来源解析方法综述[J]. 北京大学学报(自然科学版), 2014,50(6):1141-1154.

    ZHENG M, ZHANG Y J, YAN C Q, et al. Review of PM2.5 source apportionment methods in China[J]. Acta Scientiarum Naturalium Universitatis Pekinensis, 2014,50(6):1141-1154.
    [8] WANG W, MAENHAUT W, YANG W, et al. One-year aerosol characterization study for PM2.5 and PM10 in Beijing[J]. Atmospheric Pollution Research, 2014,5(3):554-562.
    doi: 10.5094/APR.2014.064
    [9] DUAN J C, TAN J H, WANG S L, et al. Size distributions and sources of elements in particulate matter at curbside,urban and rural sites in Beijing[J]. Journal of Environmental Sciences, 2012,24(1):87-94.
    doi: 10.1016/S1001-0742(11)60731-6
    [10] TAN J H, DUAN J C, ZHEN N, et al. Chemical characteristics and source of size-fractionated atmospheric particle in haze episode in Beijing[J]. Atmospheric Research, 2015,6:167.
    [11] 方凤满. 中国大气颗粒物中金属元素环境地球化学行为研究[J]. 生态环境学报, 2010,19(4):979-984.

    FANG F M. Research on environmental geochemistry of metal elements in atmospheric particles in China[J]. Ecology and Environmental Science, 2010,19(4):979-984.
    [12] 徐静, 李杏茹, 张兰, 等. 北京城郊PM2.5中金属元素的污染特征及潜在生态风险评价[J].环境科学, 2019(6):1-15.

    XU J, LI X R, ZHANG L, et al. Concentration and ecological risk assessment of heavy metals in PM2.5 collected in urban and suburban areas of Beijing[J].Environmental Science, 2019(6):1-15.
    [13] 张仁健, 王明星, 胡非, 等. 采暖期前和采暖期北京大气颗粒物的化学成分研究[J]. 中国科学院研究生院学报, 2002(1):75-81.

    ZHANG R J, WANG M X, HU F, et al. Elemental concentrations and distributions of atmospheric particles before and in heating period in Beijing[J]. Journal of University of Chinese Academy of Sciences, 2002(1):75-81.
    [14] 刘咸德, 朱祥坤, 董树屏, 等. 北京市大气颗粒物分级样品的铅同位素丰度比测量与来源研究[J]. 质谱学报, 2011,32(3):151-158.

    LIU X D, ZHU X K, DONG S P, et al. Lead isotopic measurements and source study for size-selective aerosol samples in Beijing[J]. Journal of Chinese Mass Spectrometry Society, 2011,32(3):151-158.
    [15] DUAN J C, TAN J H, HAO J M, et al. Size distribution,characteristics and sources of heavy metals in haze episode in Beijing[J]. Journal of Environmental Sciences, 2014,26(1):189-196.
    doi: 10.1016/S1001-0742(13)60397-6
    [16] 姬亚芹, 朱坦, 冯银厂, 等. 天津市PM10中元素的浓度特征和富集特征研究[J]. 环境科学与技术, 2006,29(7):49-51.

    JI Y Q, ZHU T, FENG Y C, et al. Concentration and enrichment characteristics of elements in PM10 of Tianjin[J]. Environmental Science & Technology, 2006,29(7):49-51.
    [17] 蒋昌潭, 张丹, 郑建军, 等. 公路隧道中可吸入颗粒物化学组分特征研究[J]. 四川环境, 2009,28(5):19-21.

    JIANG C T, ZHANG D, ZHENG J J, et al. Research on the characteristics of the chemical components of the inhalable particles in highway tunnels[J]. Sichuan Environment, 2009,28(5):19-21.
    [18] 王晴晴, 马永亮, 谭吉华, 等. 北京市冬季PM2.5中水溶性重金属污染特征[J]. 中国环境科学, 2014,34(9):2204-2210.

    WANG Q Q, MA Y L, TAN J H, et al. Characterization of water-soluble heavy metals of PM2.5 during winter in Beijing[J]. China Environmentol Science, 2014,34(9):2204-2210.
    [19] 陈江, 费勇, 马鑫雨, 等. 燃煤与垃圾焚烧飞灰中细颗粒物PM2.5的重金属元素风险评价[J]. 中国粉体技术, 2016,22(2):104-107.

    CHEN J, FEI Y, MA X Y, et al. Risk assessment on heavy metal elements of fine particulate matter PM2.5 in fly ash origin from coal and waste incineration[J]. China Powder Science and Technology, 2016,22(2):104-107.
    [20] 乔宝文, 刘子锐, 胡波, 等. 北京冬季PM2.5中金属元素浓度特征和来源分析[J]. 环境科学, 2017,38(3):876-883.

    QIAO B W, LIU Z R, HU B, et al. Concentration characteristics and sources of trace metals in PM2.5 during wintertime in Beijing[J]. Environmental Science, 2017,38(3):876-883.
    [21] 张蕾, 姬亚芹, 李越洋, 等. 钢铁冶炼尘两种采样方法PM2.5中元素的比较研究[J]. 中国环境科学, 2018,38(12):4426-4431.

    ZHANG L, JI Y Q, LI Y Y, et al. A comparative study on the elements of PM2.5 in two sampling methods of steel dust[J]. China Environmental Science, 2018,38(12):4426-4431.
    [22] MAENHAUT W, CAFMEYER J. Long-term atmospheric aerosol study at urban and rural sites in Belgium using multi-elemental analysis by particle-induced X-ray emission spectrometry and short-irradiation instrumental neutron activation analysis[J]. X-Ray Spectrometry, 1998,27(4):236-246.
    doi: 10.1002/(ISSN)1097-4539
    [23] WANG W, LIU X D, ZHAO L W, et al. Effectiveness of leaded petrol phase-out in Tianjin,China based on the aerosol lead concentration and isotope abundance ratio[J]. Science of the Total Environment, 2006,364(1/2/3):175-187.
    doi: 10.1016/j.scitotenv.2005.07.002
    [24] 郑乃嘉, 谭吉华, 段菁春, 等. 大气颗粒物水溶性重金属元素研究进展[J]. 环境化学, 2014,33(12):2109-2116.

    ZHENG N J, TAN J H, DUAN J C, et al. Research progress on water-soluble heavy metal in atmospheric particulate matters[J]. Environmental Chemistry, 2014,33(12):2109-2116.
    [25] 金铨, 任韧, 薛鸣, 等. 超声辅助提取-电感耦合等离子体质谱法测定杭州市主城区大气PM2.5中的47种元素[J]. 中国卫生检验杂志, 2017,27(17):2436-2440.

    JIN Q, REN R, XUE M, et al. Determination of 47 elements in PM2.5 in main urban area of Hangzhou using ultrasonic-assisted extraction-inductively coupled plasma mass spectrometry[J]. Chinese Journal of Health Laboratory Technology, 2017,27(17):2436-2440.
    [26] 董娴, 邹海凤, 梁隆超, 等. 贵阳市大气PM2.5中无机元素的组成及来源解析[J]. 环境监测管理与技术, 2019,31(1):14-18.

    DONG X, ZOU H F, LIANG L C, et al. Composition and source apportionment of inorganic element in PM2.5 in Guiyang[J]. The Administration and Technique of Environmental Monitoring, 2019,31(1):14-18.
    [27] 王的, 冯海艳, 景慧敏. 北京市冬季、春季PM10和PM2.5中元素地球化学特征[J]. 地球科学进展, 2017,32(8):850-858.

    WANG D, FENG H Y, JING H M. Elements’ geochemical characteristics of PM10 and PM2.5 in Beijing during winter and spring[J]. Advances in Earth Science, 2017,32(8):850-858.
    [28] 王士宝, 姬亚芹, 张伟, 等. 鞍山市冬季大气PM2.5中元素污染特征与来源解析[J]. 环境与可持续发展, 2017,42(2):160-164.

    WANG S B, JI Y Q, ZHANG W, et al. Pollution characteristics and sources of elements in PM2.5 during winter in Anshan City[J]. Environment and Sustainable Development, 2017,42(2):160-164.
    [29] 环境保护部科技标准司. 空气和废气颗粒物中铅等金属元素的测定电感耦合等离子体质谱法:HJ 657—2013[S]. 北京:中国环境科学出版社, 2013.
    [30] 赵冰. 沈阳市大气PM2.5污染规律及其化学组分分布特征研究[D]. 沈阳:辽宁大学, 2017.
    [31] 周雪明, 郑乃嘉, 李英红, 等. 2011—2012北京大气PM2.5中重金属的污染特征与来源分析[J]. 环境科学, 2017,38(10):4054-4060.

    ZHOU X M, ZHENG N J, LI Y H, et al. Chemical characteristics and sources of heavy metals in fine particles in Beijing in 2011-2012[J]. Environmental Science, 2017,38(10):4054-4060.
    [32] 王媛媛, 路新燕, 高勇, 等. 郑州市大气PM2.5中金属元素的污染特征[J]. 生态环境学报, 2016,25(5):829-834.

    WANG Y Y, LU X Y, GAO Y, et al. Pollution characteristics of metal elements in PM2.5 in the atmosphere of Zhengzhou[J]. Ecology and Environmental Sciences, 2016,25(5):829-834.
    [33] 杜青, 张予燕. ICP-MS法测定南京市环境空气PM2.5中多种元素[J]. 环境监测管理与技术, 2017,29(2):45-49.

    DU Q, ZHANG Y Y. Elements in PM2.5 in Nanjing by ICP-MS determination[J]. The Administration and Technique of Environmental Monitoring, 2017,29(2):45-49.
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