改性生物炭材料原位修复污染底泥的效果

Study on the effect of modified biochar materials on in situ remediation of contaminated sediments

  • 摘要: 以芦苇为原材料,FeCl3、AlCl3、MgCl2、KMnO4为改性剂,制备4种改性生物炭,以未改性生物炭、活性炭、锁磷剂(Phoslock)为对照修复材料,研究了7种修复材料对嘉兴市城市河网和湖荡2种污染底泥向水中释放氨氮(NH3-N)、硝氮( N O 3 - -N)、溶解性总氮(DTN)、正磷酸盐( P O 4 3 - -P)、溶解性总磷(DTP)及重金属离子的控制效果。结果表明:加入AlCl3改性生物炭后,2种污染底泥释放到水中的NH3-N、DTN、 P O 4 3 - -P、DTP与重金属Ni、As浓度最大可降低17.42%、18.61%、91.23%、77.04%与72.13%、46.21%;加入FeCl3改性生物炭后,2种污染底泥释放到水中的 P O 4 3 - -P、DTP、As浓度最大可降低91.23%、92.59%、95.80%,但水中DTN、Ni浓度有所增加;加入MgCl2和KMnO4改性生物炭后,2种底泥释放到水中的氮、磷、Ni、As污染物浓度不减反增。AlCl3改性生物炭能有效固定底泥中磷、Ni、As,可考虑作为污染底泥原位修复材料。

     

    Abstract: To study the control effect of biochar material on the release of nitrogen, phosphorus and heavy metal pollutants, two kinds of polluted sediment samples were collected from the river network and lake in Jiaxing City. Four kinds of modified biochars were produced using reed as the biomass feedstock and FeCl3, AlCl3, MgCl2 and KMnO4 as modifiers, while unmodified biochar, activated carbon and Phoslock were used as reference materials. The control effects of the seven kinds of remediation materials on the release of ammonia nitrogen (NH3-N), nitrate nitrogen ( NO   3 - -N) and total soluble nitrogen (DTN), orthophosphate ( P O 4 3 - -P), total soluble phosphorus (DTP) and heavy metal ions into the water from the two kinds of polluted sediments were analyzed. The results showed that after adding AlCl3 modified biochar to the sediments, the concentrations of NH3-N, DTN, P O 4 3 - -P, DTP, Ni, As released into the water from the two sediments could be reduced by 17.42%, 18.61%, 91.23%, 77.04%, 72.13%, 46.21%, respectively, at the most. After adding FeCl3 modified biochar, the concentrations of P O 4 3 - -P, DTP and As released into the water from the two sediments could be decreased by 91.23%, 92.59% and 95.80%, respectively, but the concentrations of DTN and Ni in the water increased. After adding MgCl2 and KMnO4 modified biochar, the concentrations of nitrogen, phosphorus, Ni and As pollutants released into the water from the two sediments increased rather than decreased. In conclusion, AlCl3 modified biochar could effectively fix phosphorus, Ni and As in sediments and thus be considered as a material for in situ remediation of contaminated sediment.

     

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