Abstract:
To study the control effect of biochar material on the release of nitrogen, phosphorus and heavy metal pollutants, two kinds of polluted sediment samples were collected from the river network and lake in Jiaxing City. Four kinds of modified biochars were produced using reed as the biomass feedstock and FeCl
3, AlCl
3, MgCl
2 and KMnO
4 as modifiers, while unmodified biochar, activated carbon and Phoslock were used as reference materials. The control effects of the seven kinds of remediation materials on the release of ammonia nitrogen (NH
3-N), nitrate nitrogen (
NO -N) and total soluble nitrogen (DTN), orthophosphate (
P -P), total soluble phosphorus (DTP) and heavy metal ions into the water from the two kinds of polluted sediments were analyzed. The results showed that after adding AlCl
3 modified biochar to the sediments, the concentrations of NH
3-N, DTN,
P -P, DTP, Ni, As released into the water from the two sediments could be reduced by 17.42%, 18.61%, 91.23%, 77.04%, 72.13%, 46.21%, respectively, at the most. After adding FeCl
3 modified biochar, the concentrations of
P -P, DTP and As released into the water from the two sediments could be decreased by 91.23%, 92.59% and 95.80%, respectively, but the concentrations of DTN and Ni in the water increased. After adding MgCl
2 and KMnO
4 modified biochar, the concentrations of nitrogen, phosphorus, Ni and As pollutants released into the water from the two sediments increased rather than decreased. In conclusion, AlCl
3 modified biochar could effectively fix phosphorus, Ni and As in sediments and thus be considered as a material for
in situ remediation of contaminated sediment.