Bibliometric analysis of hotspots and frontiers on remediation materials for heavy metal contaminated soils
-
摘要:
基于Web of Science(WoS)核心合集数据库和中国知网(CNKI),采用文献计量学方法和可视化分析软件揭示国内外重金属污染土壤修复材料研究领域近20年来的发展脉络、研究热点及发展方向。结果显示,相较于2001—2004年,2013—2016年和2017—2020年重金属污染土壤修复材料研究领域发文量显著增加,增长率分别为1 302%和2 201%。我国在该领域研究起步较晚,但发展迅速。关键词热点分析显示,当前污染修复研究侧重于农田土壤修复治理,重金属镉、铅及钝化材料应用。关键词聚类分析显示,钝化材料筛选和应用是当前热点主题,其中钝化材料修复机理和效果评估是该主题的重点和难点。当前农田土壤重金属污染修复材料研究正处于快速发展时期,钝化材料的功能化改性及其在农田应用中的研究有望取得较好的修复成效,绿色无污染和安全可持续的修复材料研发和应用是当下及未来的研究热点。
Abstract:Based on the database of Web of Science (WoS) Core Collection and China National Knowledge Infrastructure (CNKI), the literature in the past 20 years was searched by using literature metrology and visual analysis software to reveal the development context, research hotspots and development direction of the research field of heavy metal contaminated soil remediation materials at home and abroad. The results showed that compared with 2001-2004, the number of articles published in the field of heavy metal contaminated soil remediation materials in 2013-2016 and 2017-2020 increased significantly by 1302% and 2201% respectively, showing rapid growth. Compared with foreign research, although China started late in this field, it had developed rapidly. Keywords hot spot analysis showed current pollution remediation research focused on remediation of farmland soil, remediation of heavy metals cadmium and lead, and application of immobilized materials. Through keywords cluster analysis, screening and application of immobilized materials was a hot topic of current research, especially the repair mechanism and effect evaluation of immobilized materials were the focus and difficulty of this topic. At present, research on remediation materials for heavy metal pollution in farmland is developing rapidly and functional modification of immobilized materials and their application in farmland are expected to achieve good results in remediation. Moreover, the research and development and application of "green pollution-free" and "safe and sustainable" remediation materials are becoming a research hotspot at present and in the future.
-
Key words:
- bibliometric /
- soil contamination /
- immobilized material /
- network map /
- heavy metals
-
表 1 2001—2020年重金属污染土壤修复材料领域关键词突现分析
Table 1. Keywords emergent analysis in the field of remediation materials of heavy metals contaminated soil from 2001 to 2020
关键词 突现强度 开始年份 结束年份 2001—2020年 EDTA 11.83 2001 2011 堆肥 3.92 2002 2009 土壤污染 7.92 2003 2009 红壤 3.94 2003 2009 铜 9.52 2005 2013 壳聚糖 5.02 2006 2010 耐性 5.82 2007 2011 铅 13.01 2008 2012 锌 6.94 2008 2013 煤矸石 5.03 2008 2013 改良剂 7.23 2010 2013 赤泥 6.6 2010 2012 组配改良剂 4.23 2014 2016 肥料 3.93 2016 2018 钝化材料 10.13 2017 2020 生物炭 13.91 2018 2020 农田土壤 9.72 2018 2020 改性 4.04 2018 2020 纳米零价铁 3.9 2019 2020 土壤重金属污染 3.89 2019 2020 注:表中红色和黑色方块分别表示出现突现和未出现突现的年份。 -
[1] 骆永明, 滕应. 中国土壤污染与修复科技研究进展和展望[J]. 土壤学报, 2020, 57(5): 1137-1142.LUO Y M, TENG Y. Research progresses and prospects on soil pollution and remediation in China[J]. Acta Pedologica Sinica, 2020, 57(5): 1137-1142. [2] 环境保护部, 国土资源部. 全国土壤污染状况调查公报[EB/OL]. (2014-04-18)[2022-12-01]. http://www.gov.cn/foot/site1/20140417/782bcb88840814ba158d01.pdf. [3] 曾思燕, 于昊辰, 马静, 等. 中国耕地表层土壤重金属污染状况评判及休耕空间权衡[J]. 土壤学报, 2022, 59(4): 1036-1047.ZENG S Y, YU H C, MA J, et al. Identifying the status of heavy metal pollution of cultivated land for trade off spatial fallow in China[J]. Acta Pedologica Sinica, 2022, 59(4): 1036-1047. [4] 韩雷, 陈娟, 杜平, 等. 不同钝化剂对Cd污染农田土壤生态安全的影响[J]. 环境科学研究, 2018, 31(7): 1289-1295.HAN L, CHEN J, DU P, et al. Assessing the ecological security of the cadmium contaminated farmland treated with different amendments[J]. Research of Environmental Sciences, 2018, 31(7): 1289-1295. [5] 刘杏梅, 赵健, 徐建明. 污染农田土壤的重金属钝化技术研究: 基于Web of Science数据库的计量分析[J]. 土壤学报, 2021, 58(2): 445-455.LIU X M, ZHAO J, XU J M. Research on immobilization of heavy metals in contaminated agricultural soil:bibliometric analysis based on Web of Science database[J]. Acta Pedologica Sinica, 2021, 58(2): 445-455. [6] 黄占斌, 赵鹏, 王颖南, 等. 土壤重金属固化稳定化材料研发及其应用基础研究进展[J]. 农业资源与环境学报, 2022, 39(3): 435-445.HUANG Z B, ZHAO P, WANG Y N, et al. Progress in basic research & development and its application on solidification and stabilization materials of heavy metals in soil[J]. Journal of Agricultural Resources and Environment, 2022, 39(3): 435-445. [7] WU H H, WEI W X, XU C B, et al. Polyethylene glycol-stabilized nano zero-valent iron supported by biochar for highly efficient removal of Cr(Ⅵ)[J]. Ecotoxicology and Environmental Safety,2020,188:109902. doi: 10.1016/j.ecoenv.2019.109902 [8] 朱凰榕, 赵秋香, 倪卫东, 等.巯基-蒙脱石复合材料对不同程度Cd污染农田土壤修复研究[J]. 生态环境学报,2018,27(1):174-181.ZHU H R, ZHAO Q X, NI W D, et al. Immobilization of cadmium by thiol-functionalized montmorillonite in soils contaminated by cadmium in various degrees[J]. Ecology and Environmental Sciences,2018,27(1):174-181. [9] LIANG X F, QIN X, HUANG Q Q, et al. Mercapto functionalized sepiolite: a novel and efficient immobilization agent for cadmium polluted soil[J]. RSC Advances,2017,7(63):39955-39961. doi: 10.1039/C7RA07893E [10] NIE C R, YANG X, NIAZI N K, et al. Impact of sugarcane bagasse-derived biochar on heavy metal availability and microbial activity: a field study[J]. Chemosphere,2018,200:274-282. doi: 10.1016/j.chemosphere.2018.02.134 [11] MANDAL S, PU S Y, WANG X K, et al. Hierarchical porous structured polysulfide supported nZVI/biochar and efficient immobilization of selenium in the soil[J]. Science of the Total Environment,2020,708:134831. doi: 10.1016/j.scitotenv.2019.134831 [12] 倪柳芳, 翁仁贵.磁性黑炭的制备及其对土壤中重金属Pb和Cd的吸附[J]. 环境工程技术学报,2015,5(1):59-63. doi: 10.3969/j.issn.1674-991X.2015.01.009NI L F, WENG R G. Preparation of magnetic black carbon and its adsorption of heavy metals Pb and Cd in soil[J]. Journal of Environmental Engineering Technology,2015,5(1):59-63. doi: 10.3969/j.issn.1674-991X.2015.01.009 [13] HAN R R, ZHOU B H, HUANG Y Y, et al. Bibliometric overview of research trends on heavy metal health risks and impacts in 1989-2018[J]. Journal of Cleaner Production,2020,276:123249. doi: 10.1016/j.jclepro.2020.123249 [14] 张媛, 张艳杰, 朱静, 等.基于文献计量的湿地构建前沿进展[J]. 环境工程技术学报,2021,11(1):107-113. doi: 10.12153/j.issn.1674-991X.20200050ZHANG Y, ZHANG Y J, ZHU J, et al. A bibliometric analysis of the frontier progress in wetland construction[J]. Journal of Environmental Engineering Technology,2021,11(1):107-113. doi: 10.12153/j.issn.1674-991X.20200050 [15] LI D Y, ZHAO R, PENG X, et al. Biochar-related studies from 1999 to 2018: a bibliometrics-based review[J]. Environmental Science and Pollution Research International,2020,27(3):2898-2908. doi: 10.1007/s11356-019-06870-9 [16] 张力, 赵星, 叶鹰.信息可视化软件CiteSpace与VOSviewer的应用比较[J]. 信息资源管理学报,2011,1(1):95-98.ZHANG L, ZHAO X, YE Y. A comparison between CileSpace and VOSviewer in information visualization[J]. Journal of Information Resources Management,2011,1(1):95-98. [17] WOLNIK K A, FRICKE F L, CAPAR S G, et al. Elements in major raw agricultural crops in the United States: 3. cadmium, lead, and eleven other elements in carrots, field corn, onions, rice, spinach, and tomatoes[J]. Journal of Agricultural and Food Chemistry,1985,33(5):807-811. doi: 10.1021/jf00065a010 [18] 周芳, 金书秦.日本土壤污染防治政策研究[J]. 世界农业,2014(11):47-52. doi: 10.13856/j.cn11-1097/s.2014.11.012 [19] 姚毓春, 夏宇.日本、韩国粮食安全现状、政策及其启示[J]. 东北亚论坛,2021,30(5):83-98.YAO Y C, XIA Y. The current situation, policy, and enlightenment of food security in Japan and republic of Korea[J]. Northeast Asia Forum,2021,30(5):83-98. [20] LADO L R, HENGL T, REUTER H I. Heavy metals in European soils: a geostatistical analysis of the FOREGS Geochemical database[J]. Geoderma,2008,148(2):189-199. doi: 10.1016/j.geoderma.2008.09.020 [21] TÓTH G, HERMANN T, da SILVA M R, et al. Heavy metals in agricultural soils of the European Union with implications for food safety[J]. Environment International,2016,88:299-309. doi: 10.1016/j.envint.2015.12.017 [22] 国务院. 土壤污染防治行动计划[A/OL]. (2016-05-31). http://www.gov.cn/zhengce/content/2016-05/31/content5078377.htm. [23] 杨阳, 李艳玲, 王美娥, 等.湖南攸县稻米镉(Cd)富集特征及原因解析[J]. 环境科学学报,2017,37(4):1502-1507.YANG Y, LI Y L, WANG M E, et al. Enrichment characteristics of cadmium in rice and its influence factor in the Youxian prefecture, Hunan Province[J]. Acta Scientiae Circumstantiae,2017,37(4):1502-1507. [24] 周建军, 周桔, 冯仁国.我国土壤重金属污染现状及治理战略[J]. 中国科学院院刊,2014,29(3):315-320.ZHOU J J, ZHOU J, FENG R G. Status of China's heavy metal contamination in soil and its remediation strategy[J]. Bulletin of Chinese Academy of Sciences,2014,29(3):315-320. [25] 何绪文, 王宇翔, 房增强, 等.铅锌矿区土壤重金属污染特征及污染风险评价[J]. 环境工程技术学报,2016,6(5):476-483. doi: 10.3969/j.issn.1674-991X.2016.05.070HE X W, WANG Y X, FANG Z Q, et al. Pollution characteristics and pollution risk evaluation of heavy metals in soil of lead-zinc mining area[J]. Journal of Environmental Engineering Technology,2016,6(5):476-483. doi: 10.3969/j.issn.1674-991X.2016.05.070 [26] 孙约兵, 王永昕, 李烨, 等.Cd-Pb复合污染土壤钝化修复效率与生物标记物识别[J]. 环境科学研究,2015,28(6):951-958.SUN Y B, WANG Y X, LI Y, et al. Effectiveness of immobilization remediation of Cd and Pb combined contaminated soil and biomarker identification[J]. Research of Environmental Sciences,2015,28(6):951-958. [27] 曹心德, 魏晓欣, 代革联, 等.土壤重金属复合污染及其化学钝化修复技术研究进展[J]. 环境工程学报,2011,5(7):1441-1453.CAO X D, WEI X X, DAI G L, et al. Combined pollution of multiple heavy metals and their chemical immobilization in contaminated soils: a review[J]. Chinese Journal of Environmental Engineering,2011,5(7):1441-1453. [28] 周莉, 郑向群, 丁永祯, 等.农田镉砷污染防控与作物安全种植技术探讨[J]. 农业环境科学学报,2017,36(4):613-619. doi: 10.11654/jaes.2016-1518ZHOU L, ZHENG X Q, DING Y Z, et al. Probes of prevention and control of farmland pollution by cadmium & arsenic and crop production safety[J]. Journal of Agro-Environment Science,2017,36(4):613-619. doi: 10.11654/jaes.2016-1518 [29] HE L Z, ZHONG H, LIU G X, et al. Remediation of heavy metal contaminated soils by biochar: mechanisms, potential risks and applications in China[J]. Environmental Pollution,2019,252:846-855. doi: 10.1016/j.envpol.2019.05.151 [30] BRTNICKY M, DATTA R, HOLATKO J, et al. A critical review of the possible adverse effects of biochar in the soil environment[J]. Science of the Total Environment,2021,796:148756. doi: 10.1016/j.scitotenv.2021.148756 [31] ZHUANG Z, NIÑO-SAVALA A G, MI Z D, et al. Cadmium accumulation in wheat and maize grains from China: interaction of soil properties, novel enrichment models and soil thresholds[J]. Environmental Pollution,2021,275:116623. doi: 10.1016/j.envpol.2021.116623 [32] 曾秀君, 黄学平, 程坤, 等.石灰组配有机改良剂对农田铅镉污染土壤微生物活性的影响[J]. 环境科学研究,2020,33(10):2361-2369. doi: 10.13198/j.issn.1001-6929.2020.04.27ZENG X J, HUANG X P, CHENG K, et al. Effects of lime mixed with organic modifiers on microbial activity in lead and cadmium contaminated farmland soil[J]. Research of Environmental Sciences,2020,33(10):2361-2369. doi: 10.13198/j.issn.1001-6929.2020.04.27 [33] 刘娇娴, 崔骏, 刘洪宝, 等.土壤改良剂改良酸化土壤的研究进展[J]. 环境工程技术学报,2022,12(1):173-184. doi: 10.12153/j.issn.1674-991X.20210119LIU J X, CUI J, LIU H B, et al. Research progress of soil amelioration of acidified soil by soil amendments[J]. Journal of Environmental Engineering Technology,2022,12(1):173-184. doi: 10.12153/j.issn.1674-991X.20210119 [34] ZHANG Y F, WANG J M, FENG Y. The effects of biochar addition on soil physicochemical properties: a review[J]. CATENA,2021,202:105284. doi: 10.1016/j.catena.2021.105284 [35] OK Y S, CHANG S X, GAO B, et al. SMART biochar technology: a shifting paradigm towards advanced materials and healthcare research[J]. Environmental Technology & Innovation,2015,4:206-209. [36] CHEN M Q, WU P X, LI S S, et al. The effects of interaction between vermiculite and manganese dioxide on the environmental geochemical process of thallium[J]. Science of the Total Environment,2019,669:903-910. doi: 10.1016/j.scitotenv.2019.03.079 [37] EPELDE L, HERNÁNDEZ-ALLICA J, BECERRIL J M, et al. Effects of chelates on plants and soil microbial community: comparison of EDTA and EDDS for lead phytoextraction[J]. Science of the Total Environment,2008,401(1/2/3):21-28. [38] 骆永明, 滕应, 过园.土壤修复: 新兴的土壤科学分支学科[J]. 土壤,2005,37(3):230-235. doi: 10.3321/j.issn:0253-9829.2005.03.002LUO Y M, TENG Y, GUO Y. Soil remediation: a new branch discipline of soil science[J]. Soils,2005,37(3):230-235. doi: 10.3321/j.issn:0253-9829.2005.03.002 [39] GUO G H, WU F C, XIE F Z, et al. Spatial distribution and pollution assessment of heavy metals in urban soils from southwest China[J]. Journal of Environmental Sciences,2012,24(3):410-418. doi: 10.1016/S1001-0742(11)60762-6 [40] 王超, 宋卫锋, 杨佐毅, 等.工业固废基地聚合物的制备及其吸附Pb(Ⅱ)的性能[J]. 环境科学学报,2021,41(7):2700-2711.WANG C, SONG W F, YANG Z Y, et al. Synthesis of industrial wastes-based geopolymer and its adsorption capacity for Pb(Ⅱ)[J]. Acta Scientiae Circumstantiae,2021,41(7):2700-2711. [41] FANG Z Q, QIU X H, CHEN J H, et al. Degradation of the polybrominated diphenyl ethers by nanoscale zero-valent metallic particles prepared from steel pickling waste liquor[J]. Desalination,2011,267(1):34-41. doi: 10.1016/j.desal.2010.09.003 [42] 徐建明, 孟俊, 刘杏梅, 等.我国农田土壤重金属污染防治与粮食安全保障[J]. 中国科学院院刊,2018,33(2):153-159. doi: 10.16418/j.issn.1000-3045.2018.02.004XU J M, MENG J, LIU X M, et al. Control of heavy metal pollution in farmland of China in terms of food security[J]. Bulletin of Chinese Academy of Sciences,2018,33(2):153-159. doi: 10.16418/j.issn.1000-3045.2018.02.004 [43] 陈卫平, 杨阳, 谢天, 等.中国农田土壤重金属污染防治挑战与对策[J]. 土壤学报,2018,55(2):261-272.CHEN W P, YANG Y, XIE T, et al. Challenges and countermeasures for heavy metal pollution control in farmlands of China[J]. Acta Pedologica Sinica,2018,55(2):261-272. [44] 胡红青, 黄益宗, 黄巧云, 等.农田土壤重金属污染化学钝化修复研究进展[J]. 植物营养与肥料学报,2017,23(6):1676-1685. doi: 10.11674/zwyf.17299HU H Q, HUANG Y Z, HUANG Q Y, et al. Research progress of heavy metals chemical immobilization in farm land[J]. Journal of Plant Nutrition and Fertilizer,2017,23(6):1676-1685. ⊕ doi: 10.11674/zwyf.17299