Problems analysis based on the response of water quality to pollution sources in Xiangxi River Basin
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摘要: 开展流域水环境问题症结分析,是支撑流域水生态环境修复治理和精准管控的关键途径。应用“空-地-水”一体化模型体系,面向香溪河流域构建了“源-质”响应关系模型,并进一步对该流域水环境问题开展定量精准解析。根据水质监测断面2019年实测数据进行模型验证,总氮(TN)、总磷(TP)浓度相对误差均在10%以内。结果表明,污水处理厂、工业源和畜禽养殖是造成香溪河水质污染和富营养化的3类主要污染源,总贡献率超过60%。对于泗湘溪断面,污水处理厂输出的TN、TP总量为193.28和40.51 t/a,工业源为226.25和31.69 t/a,畜禽养殖为187.75和29.82 t/a;对于长沙坝断面,污水处理厂输出的TN、TP总量为376.31和48.97 t/a,工业源为295.30和39.91 t/a,畜禽养殖为128.09和41.61 t/a。基于当前流域水环境综合治理的迫切需求,该流域未来应加大这3类污染源的截污控源力度。
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关键词:
- 香溪河流域 /
- 污染负荷 /
- 源解析 /
- “空-地-水”一体化模型
Abstract: Analysis of the causes of water environment problems is the key way to support the water environment fine-management and water eco-environment recovery in the river basins. The Air-ground-water integrated model system was applied to establish the response model of water quality to pollution sources in Xiangxi River Basin, and the water environment problems in the basin were quantitatively analyzed. The model was verified according to the measured data of the water quality monitoring sections in 2019, and the relative error of total nitrogen (TN) and total phosphorus (TP) concentrations were within 10%. The results showed that sewage treatment plants, industrial enterprises and livestock breeding were three main sources of water pollution and eutrophication of Xiangxi River Basin, with a total contribution rate of more than 60%. For Sixiangxi section, TN and TP discharge from sewage treatment plants were 193.28 and 40.51 t/a, with 226.25 and 31.69 t/a from industrial sources, and 187.75 and 29.82 t/a from livestock breeding, respectively. For Changshaba section, TN and TP produced by sewage treatment plants were 376.31 and 48.97 t/a, with 295.30 and 39.91 t/a from industrial sources, 128.09 and 41.61 t/a from livestock breeding, respectively. Based on the urgent needs of comprehensive water environment management, the efforts to control pollution of these three kinds of sources should be intensified in the future.-
Key words:
- Xiangxi River /
- pollution load /
- source apportionment /
- Air-ground-water integrated model
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表 1 香溪河流域敏感参数取值
Table 1. Value of sensitive parameters in Xiangxi River Basin
参数 含义 排序 参数取值 敏感度值 RCN 降水中氮浓度/(mg/L) 1 4 3.31 CN2 径流曲线系数 2 70 2.99 FILTERW 田间过滤带宽度/m 3 5 2.71 SHALLST_N 浅层含水层中的硝酸盐浓度/(mg/L) 4 10 2.12 ALPHAA_BF 基流退水常数/d 5 0.03 1.97 ESCO 土壤蒸发补偿系数 6 0.33 1.91 GW_DELAY 含水层补给的延迟时间/d 7 5 1.85 CDN 反硝化作用速率系数 8 0.01 1.52 BC4 20 ℃时当地有机磷的成矿速率常数/d−1 9 0.7 0.88 SDNCO 能够发生反硝化作用的营养物质循环水因子的临界值 10 0.65 0.87 BC1 20 ℃时铵根离子的生物氧化速率常数/d−1 11 0.3 0.81 REVAPMN 潜水蒸发时浅层含水层的水位阈值/mm 11 460.31 0.81 PSP 磷的可利用率指数 13 0.7 0.76 HLIFE_NGW 浅层含水层中硝酸盐的半衰期/d−1 14 1 0.68 GW_SOLP 地下水流中可溶性磷浓度/(mg/L) 15 0.1 0.5 RS5 20 ℃时当地有机磷的沉降速率常数/d−1 16 0.1 0.34 BC2 20 ℃时亚硝酸盐向硝酸盐转化的生物氧化速率常数/d−1 17 1.2 0.28 SURLAG 地表径流的滞后系数 18 8.22 0.23 BC3 20 ℃时当地有机氮向铵根离子转化的生物氧化速率常数/d−1 19 0.4 0.21 表 2 香溪河流域水文、水质率定验证
Table 2. Calibration and verification of hydrology and water quantity in Xiangxi River Basin
类型 站点名称 率定期(2011—2012年) 验证期(2019年) R2 ENS R2 ENS 流量 南阳 0.71 0.68 0.75 0.60 总氮 泗湘溪 0.83 0.72 0.79 0.71 长沙坝 0.96 0.84 0.84 0.80 总磷 泗湘溪 0.84 0.62 0.78 0.61 长沙坝 0.86 0.65 0.82 0.63 表 3 各类污染源对断面TN和TP浓度的贡献率
Table 3. Contribution rate of pollution sources to TN and TP in different sections
% 水质断面 污染源类型 TN TP 工业源 29.20 20.11 污水处理厂 24.71 25.97 泗湘溪 畜禽养殖 23.95 18.86 生活源 10.75 14.95 农业源 11.39 20.11 工业源 24.97 20.44 污水处理厂 32.21 25.35 长沙坝 畜禽养殖 22.33 21.36 生活源 10.02 16.26 农业源 10.47 16.59 -
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