体相纳米气泡的消除与尺寸调控研究进展

张睿毅; 陈岚; 葛广路

doi:10.12153/j.issn.1674-991X.20210853

体相纳米气泡的消除与尺寸调控研究进展

doi: 10.12153/j.issn.1674-991X.20210853

张睿毅^{1, 2,},
陈岚^1, ,,
葛广路^1, ,

1.
中国科学院纳米标准与检测重点实验室, 中国科学院纳米科学卓越创新中心, 国家纳米科学中心
2.
中国科学院大学

基金项目: 中国科学院战略性先导科技专项（B类）（XDB36000000）

详细信息

作者简介:
张睿毅（1998—），男，博士研究生，主要从事纳米材料界面物理化学性质的研究，zhangry2018@nanoctr.cn

通讯作者:
陈岚（1974—），男，博士，研究员，主要从事纳米材料界面物理化学性质的研究，chenlan@nanoctr.cn

葛广路（1970—），男，博士，研究员，主要从事纳米标准测试方法研究，gegl@nanoctr.cn

中图分类号: X52,O35
计量
- 文章访问数: 496
- HTML全文浏览量: 358
- PDF下载量: 84
- 被引次数: 0
出版历程
- 收稿日期: 2021-12-22

Research progress on elimination and size control of bulk nanobubbles

ZHANG Ruiyi^{1, 2
,},
CHEN Lan^{1
, ,},
GE Guanglu^{1
, ,}

1.
CAS Key Laboratory of Standardization and Measurement for Nanotechnology, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology
2.
University of Chinese Academy of Sciences

摘要

摘要:
不同方法发生的体相纳米气泡尺寸与数量浓度相差悬殊。气泡尺寸的多分散性及数量浓度的本征差异性给体相纳米气泡的性能研究及效能比较带来了不便，同时也不利于纳米气泡技术的标准化、产业化。因此，体相纳米气泡尺寸及数量浓度的调控十分重要。对近年来体相纳米气泡尺寸和数量浓度的调控技术进行了总结及综合评估。主要分析对比了循环均化法、微流控技术和膜技术等尺寸调控方法与冻融去除法、超声消减法等数量浓度调控方法的优劣，从可调控性、设备依赖性、工艺难易度、可拓展性及成本等方面对各方法进行了评估，并结合本课题组已发表研究成果对体相纳米气泡的尺寸和数量浓度调控提出新的认识与思路，以期为深入了解纳米气泡的尺寸效应和超常稳定机制以及体相纳米气泡定量分析与应用，特别是与尺寸相关的性质、效应和应用提供新思考。
- 体相纳米气泡 /
- 发生方法 /
- 气泡消除 /
- 尺寸调控 /
- 尺寸效应
Abstract:
There are various bubble generation methods which can produce bulk nanobubbles with different sizes and different number concentrations. However, the polydispersity of bubble size and the intrinsic difference of number concentration are inconvenient to the performance research and efficiency comparison of bulk nanobubbles, and it is also not conducive to the standardization and industrialization of nanobubble technology. Therefore, the size control and number concentration adjustment for the bulk nanobubbles are very important. The technologies for controlling the size and number concentration of the bulk nanobubbles in recent years were summarized and comprehensively evaluated. The advantages and disadvantages of size control methods such as cyclic homogenization, microfluidic technology and membrane technology, and number concentration control methods such as freeze-thaw removal method and ultrasonication reduction method were analyzed and compared. All methods were evaluated in terms of controllability, equipment dependence, process difficulty, scalability and cost, and new understandings and ideas for the regulation of nanobubble size and concentration were proposed combined with the published research results. It helped to deeply understand the size effect of the nanobubbles and extra stabilization mechanism and provide new ideas for the quantitative analysis and applications of bulk nanobubbles, especially for the nanobubble size-related properties, effects and applications.
- bulk nanobubbles /
- generation method /
- bubble elimination /
- size control /
- size effect

HTML全文

图 1 冻融前后纳米气泡数量浓度的变化^[10]

Figure 1. Change of number concentration of the nanobubbles before and after freezing and thawing

下载: 全尺寸图片幻灯片

图 2 纳米气泡的超声消减

Figure 2. Ultrasonic elimination of nanobubbles

下载: 全尺寸图片幻灯片

图 3 文丘里型水动力空化装置中通过循环使纳米气泡尺寸均化^[38]

Figure 3. The size homogenization of the nanobubbles by circulation through Venturi-type hydrodynamic cavitation device

下载: 全尺寸图片幻灯片

图 4 通过微流控技术发生纳米气泡示意^[47]

Figure 4. Schematic for the nanobubbles generated by microfluidic technology

下载: 全尺寸图片幻灯片

图 5 使用多孔膜发生纳米气泡及孔尺寸对气泡粒径的影响

Figure 5. Generation of nanobubbles using porous membranes and the influence of the pore size on the nanobubbles size

下载: 全尺寸图片幻灯片

图 6 使用多孔氧化铝生成体相纳米气泡的示意及气泡尺寸分布^[9]

Figure 6. Schematic for the bulk nanobubbles generated by porous alumina and their bubble size distributions

下载: 全尺寸图片幻灯片

图 7 纳米气泡的尺寸调控与数量浓度调控技术综合评估结果

Figure 7. Comprehensive evaluation results on the size and concentration control methods for bulk nanobubbles.

下载: 全尺寸图片幻灯片

表 1 体相纳米气泡尺寸和数量浓度调控方法分类

Table 1. Classification of bulk nanobubbles size and number concentration control methods

调控参数	一次调控方法	二次调控方法
尺寸	循环均化法^[38-39,45]、微流控技术^[36,47-48]、膜技术^[6-9]	膜技术^[49]
数量浓度	循环均化法^[46]	超声消减法^[41-42]、超速离心法和冻融去除法^[10]

下载: 导出CSV

参考文献(49)

[1]	ALHESHIBRI M, QIAN J, JEHANNIN M, et al. A history of nanobubbles[J]. Langmuir,2016,32(43):11086-11100. doi: 10.1021/acs.langmuir.6b02489
[2]	JADHAV A J, BARIGOU M. Bulk nanobubbles or not nanobubbles: that is the question[J]. Langmuir,2020,36(7):1699-1708. doi: 10.1021/acs.langmuir.9b03532
[3]	OHGAKI K, KHANH N Q, JODEN Y, et al. Physicochemical approach to nanobubble solutions[J]. Chemical Engineering Science,2010,65(3):1296-1300. doi: 10.1016/j.ces.2009.10.003
[4]	CHEN Q J, WIEDENROTH H S, GERMAN S R, et al. Electrochemical nucleation of stable N₂ nanobubbles at Pt nanoelectrodes[J]. Journal of the American Chemical Society,2015,137(37):12064-12069. doi: 10.1021/jacs.5b07147
[5]	KIKUCHI K, NAGATA S, TANAKA Y, et al. Characteristics of hydrogen nanobubbles in solutions obtained with water electrolysis[J]. Journal of Electroanalytical Chemistry,2007,600(2):303-310. doi: 10.1016/j.jelechem.2006.10.005
[6]	KUKIZAKI M, GOTO M. Size control of nanobubbles generated from Shirasu-porous-glass (SPG) membranes[J]. Journal of Membrane Science,2006,281(1/2):386-396.
[7]	AHMED A K A, SUN C Z, HUA L K, et al. Generation of nanobubbles by ceramic membrane filters: the dependence of bubble size and zeta potential on surface coating, pore size and injected gas pressure[J]. Chemosphere,2018,203:327-335. doi: 10.1016/j.chemosphere.2018.03.157
[8]	ULATOWSKI K, SOBIESZUK P, MRÓZ A, et al. Stability of nanobubbles generated in water using porous membrane system[J]. Chemical Engineering and Processing - Process Intensification,2019,136:62-71. doi: 10.1016/j.cep.2018.12.010
[9]	MA T, KIMURA Y, YAMAMOTO H, et al. Characterization of bulk nanobubbles formed by using a porous alumina film with ordered nanopores[J]. The Journal of Physical Chemistry B,2020,124(24):5067-5072. doi: 10.1021/acs.jpcb.0c02279
[10]	NIRMALKAR N, PACEK A W, BARIGOU M. On the existence and stability of bulk nanobubbles[J]. Langmuir:the ACS Journal of Surfaces and Colloids,2018,34(37):10964-10973. doi: 10.1021/acs.langmuir.8b01163
[11]	NIRMALKAR N, PACEK A W, BARIGOU M. Bulk nanobubbles from acoustically cavitated aqueous organic solvent mixtures[J]. Langmuir:the ACS Journal of Surfaces and Colloids,2019,35(6):2188-2195. doi: 10.1021/acs.langmuir.8b03113
[12]	MILLARE J C, BASILIA B A. Nanobubbles from ethanol-water mixtures: generation and solute effects via solvent replacement method[J]. ChemistrySelect,2018,3(32):9268-9275. doi: 10.1002/slct.201801504
[13]	QIU J, ZOU Z L, WANG S, et al. Formation and stability of bulk nanobubbles generated by ethanol-water exchange[J]. ChemPhysChem,2017,18(10):1345-1350. doi: 10.1002/cphc.201700010
[14]	WANG Q Z, ZHAO H, QI N, et al. Generation and stability of size-adjustable bulk nanobubbles based on periodic pressure change[J]. Scientific Reports,2019,9:1118. doi: 10.1038/s41598-018-38066-5
[15]	XIAO W, KE S, QUAN N N, et al. The role of nanobubbles in the precipitation and recovery of organic-phosphine-containing beneficiation wastewater[J]. Langmuir,2018,34(21):6217-6224. doi: 10.1021/acs.langmuir.8b01123
[16]	叶春, 张保君, 李春华, 等.微纳米曝气对植物浮床处理支浜水脱氮效果的影响[J]. 环境科学研究,2012,25(10):1173-1179. YE C, ZHANG B J, LI C H, et al. Effects of micro-nanometer aeration on nitrogen removal by plant floating-beds[J]. Research of Environmental Sciences,2012,25(10):1173-1179.
[17]	AGARWAL A, NG W J, LIU Y. Principle and applications of microbubble and nanobubble technology for water treatment[J]. Chemosphere,2011,84(9):1175-1180. doi: 10.1016/j.chemosphere.2011.05.054
[18]	洪涛, 叶春, 李春华, 等.微米气泡曝气技术处理黑臭河水的效果研究[J]. 环境工程技术学报,2011,1(1):20-25. doi: 10.3969/j.issn.1674-991X.2011.01.004 HONG T, YE C, LI C H, et al. Treatment effect of microbubble aeration technology on black-odor river water[J]. Journal of Environmental Engineering Technology,2011,1(1):20-25. doi: 10.3969/j.issn.1674-991X.2011.01.004
[19]	TAKENOUCHI T. Behavior of hydrogen nanobubbles in alkaline electrolyzed water and its rinse effect for sulfate ion remained on nickel-plated surface[J]. Journal of Applied Electrochemistry,2010,40(4):849-854. doi: 10.1007/s10800-009-0068-z
[20]	CHEN H B, MAO H L, WU L P, et al. Defouling and cleaning using nanobubbles on stainless steel[J]. Biofouling,2009,25(4):353-357. doi: 10.1080/08927010902807645
[21]	WU Z H, CHEN H B, DONG Y M, et al. Cleaning using nanobubbles: defouling by electrochemical generation of bubbles[J]. Journal of Colloid and Interface Science,2008,328(1):10-14. doi: 10.1016/j.jcis.2008.08.064
[22]	ZHU J, AN H J, ALHESHIBRI M, et al. Cleaning with bulk nanobubbles[J]. Langmuir,2016,32(43):11203-11211. doi: 10.1021/acs.langmuir.6b01004
[23]	FAN M M, TAO D, HONAKER R, et al. Nanobubble generation and its application in froth flotation: part I. nanobubble generation and its effects on properties of microbubble and millimeter scale bubble solutions[J]. Mining Science and Technology (China),2010,20(1):1-19. doi: 10.1016/S1674-5264(09)60154-X
[24]	ZHOU W G, LIU K, WANG L, et al. The role of bulk micro-nanobubbles in reagent desorption and potential implication in flotation separation of highly hydrophobized minerals[J]. Ultrasonics Sonochemistry,2020,64:104996. doi: 10.1016/j.ultsonch.2020.104996
[25]	POURKARIMI Z, REZAI B, NOAPARAST M. Effective parameters on generation of nanobubbles by cavitation method for froth flotation applications[J]. Physicochemical Problems of Mineral Processing,2017,53(2):920-942.
[26]	LIU S, OSHITA S, MAKINO Y, et al. Oxidative capacity of nanobubbles and its effect on seed germination[J]. ACS Sustainable Chemistry & Engineering,2016,4(3):1347-1353.
[27]	AHMED A K A, SHI X N, HUA L K, et al. Influences of air, oxygen, nitrogen, and carbon dioxide nanobubbles on seed germination and plant growth[J]. Journal of Agricultural and Food Chemistry,2018,66(20):5117-5124. doi: 10.1021/acs.jafc.8b00333
[28]	SHA Z M, CHEN Z, FENG Y F, et al. Minerals loaded with oxygen nanobubbles mitigate arsenic translocation from paddy soils to rice[J]. Journal of Hazardous Materials,2020,398:122818. doi: 10.1016/j.jhazmat.2020.122818
[29]	EBINA K, SHI K, HIRAO M, et al. Oxygen and air nanobubble water solution promote the growth of plants, fishes, and mice[J]. PLoS One,2013,8(6):e65339. doi: 10.1371/journal.pone.0065339
[30]	LUKIANOVA-HLEB E Y, REN X Y, ZASADZINSKI J A, et al. Plasmonic nanobubbles enhance efficacy and selectivity of chemotherapy against drug-resistant cancer cells[J]. Advanced Materials,2012,24(28):3831-3837. doi: 10.1002/adma.201103550
[31]	GAO Z G, KENNEDY A M, CHRISTENSEN D A, et al. Drug-loaded nano/microbubbles for combining ultrasonography and targeted chemotherapy[J]. Ultrasonics,2008,48(4):260-270. doi: 10.1016/j.ultras.2007.11.002
[32]	RAPOPORT N, GAO Z G, KENNEDY A. Multifunctional nanoparticles for combining ultrasonic tumor imaging and targeted chemotherapy[J]. JNCI:Journal of the National Cancer Institute,2007,99(14):1095-1106. doi: 10.1093/jnci/djm043
[33]	FAVVAS E P, KYZAS G Z, EFTHIMIADOU E K, et al. Bulk nanobubbles, generation methods and potential applications[J]. Current Opinion in Colloid & Interface Science,2021,54:101455.
[34]	NAZARI S, ZIAEDIN SHAFAEI S, HASSANZADEH A, et al. Study of effective parameters on generating submicron (nano)-bubbles using the hydrodynamic cavitation[J]. Physicochemical Problems of Mineral Processing,2020,56(5):884-904. doi: 10.37190/ppmp/126628
[35]	ZHOU L M, WANG S, ZHANG L J, et al. Generation and stability of bulk nanobubbles: a review and perspective[J]. Current Opinion in Colloid & Interface Science,2021,53:101439.
[36]	XU J, SALARI A, WANG Y J, et al. Microfluidic generation of monodisperse nanobubbles by selective gas dissolution[J]. Small,2021,17(20):2100345. doi: 10.1002/smll.202100345
[37]	Fine bubble technology. elimination method for sample characterization. fine bubble elimination techniques: BS ISO 24261-2-2021[S]. London: British Standards Institution, 2021.
[38]	LI T, CUI Z, SUN J, et al. Generation of bulk nanobubbles by self-developed venturi-type circulation hydrodynamic cavitation device[J]. Langmuir,2021,37(44):12952-12960. doi: 10.1021/acs.langmuir.1c02010
[39]	ZHANG R Y, GAO Y, CHEN L, et al. Nanobubble boundary layer thickness quantified by solvent relaxation NMR[J]. Journal of Colloid and Interface Science,2022,609:637-644. doi: 10.1016/j.jcis.2021.11.072
[40]	NITTAYACHARN P, DAI K, de LEON A, et al. The effect of freeze/thawing on the physical properties and acoustic performance of perfluoropropane nanobubble suspensions[C]//2019 IEEE International Ultrasonics Symposium.Glasgow, UK: IEEE, 2019: 2279-2282.
[41]	YASUDA K, MATSUSHIMA H, ASAKURA Y. Generation and reduction of bulk nanobubbles by ultrasonic irradiation[J]. Chemical Engineering Science,2019,195:455-461. doi: 10.1016/j.ces.2018.09.044
[42]	TANAKA S, KOBAYASHI H, OHUCHI S, et al. Destabilization of ultrafine bubbles in water using indirect ultrasonic irradiation[J]. Ultrasonics Sonochemistry,2021,71:105366. doi: 10.1016/j.ultsonch.2020.105366
[43]	LEROY P, JOUGNOT D, REVIL A, et al. A double layer model of the gas bubble/water interface[J]. Journal of Colloid and Interface Science,2012,388(1):243-256. doi: 10.1016/j.jcis.2012.07.029
[44]	HEWAGE S A, KEWALRAMANI J, MEEGODA J N. Stability of nanobubbles in different salts solutions[J]. Colloids and Surfaces A:Physicochemical and Engineering Aspects,2021,609:125669. doi: 10.1016/j.colsurfa.2020.125669
[45]	MICHAILIDI E D, BOMIS G, VAROUTOGLOU A, et al. Bulk nanobubbles: production and investigation of their formation/stability mechanism[J]. Journal of Colloid and Interface Science,2020,564:371-380. doi: 10.1016/j.jcis.2019.12.093
[46]	GAO Y W, DASHLIBORUN A M, ZHOU J Z, et al. Formation and stability of cavitation microbubbles in process water from the oilsands industry[J]. Industrial & Engineering Chemistry Research,2021,60(7):3198-3209.
[47]	ABOU-SALEH R H, ARMISTEAD F J, BATCHELOR D V B, et al. Horizon: microfluidic platform for the production of therapeutic microbubbles and nanobubbles[J]. Review of Scientific Instruments,2021,92(7):074105. doi: 10.1063/5.0040213
[48]	SONG R Y, PENG C, XU X N, et al. Controllable formation of monodisperse polymer microbubbles as ultrasound contrast agents[J]. ACS Applied Materials & Interfaces,2018,10(17):14312-14320.
[49]	ZHANG R, GAO Y, CHEN L, et al. Controllable preparation of monodisperse nanobubbles by membrane sieving[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects,2022,642:128656. ◇