我国地表水和沉积物PPCPs赋存与交互迁移影响因素

田永静; 武宇圣; 黄天寅; 陈书琴; 张家根; 庞燕

doi:10.12153/j.issn.1674-991X.20220418

我国地表水和沉积物PPCPs赋存与交互迁移影响因素

doi: 10.12153/j.issn.1674-991X.20220418

田永静^1,,
武宇圣^{1, 2, 3},
黄天寅¹,
陈书琴⁴,
张家根^{1, 2, 3},
庞燕^{2, 3, ,}

1.
苏州科技大学环境科学与工程学院
2.
湖泊水污染治理与生态修复技术国家工程实验室, 中国环境科学研究院
3.
国家环境保护湖泊污染控制重点实验室, 中国环境科学研究院
4.
安庆师范大学资源环境学院

基金项目: 国家水体污染控制与治理科技重大专项(2017ZX07301-006-06)

详细信息

作者简介:
田永静（1969—），女，副教授，主要从事水污染控制工程研究，t12612618@163.com

通讯作者:
庞燕（1970—），女，研究员，主要从事湖泊水污染控制及生态修复研究，190068749@qq.com

中图分类号: X52
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出版历程
- 收稿日期: 2022-05-02

Occurrence of PPCPs in surface water and sediment in China and influencing factors of interactive migration

TIAN Yongjing^1
,,
WU Yusheng^{1, 2, 3},
HUANG Tianyin¹,
CHEN Shuqin⁴,
ZHANG Jiagen^{1, 2, 3},
PANG Yan^{2, 3
, ,}

1.
School of Environmental Science and Engineering, Suzhou University of Science and Technology
2.
National Engineering Laboratory for Lake Pollution Control and Ecological Restoration, Chinese Research Academy of Environmental Sciences
3.
State Environmental Protection Key Laboratory for Lake Pollution Control, Chinese Research Academy of Environmental Sciences
4.
Resource and Environment College of Anqing Normal University

摘要

摘要:
药品及个人护理品（PPCPs）作为一类典型的新型污染物，由于被广泛使用和存在“假持久性”，在水环境中经常被检测到，引起全球的广泛关注。沉积物是PPCPs重要的环境蓄积库，被污染的沉积物可成为长期污染源对上覆水造成污染。综述了近年来国内外研究成果，分析了PPCPs在中国七大地区典型地表水和沉积物中的赋存现状，归纳总结了PPCPs自身性质、沉积物组分和环境因素对PPCPs在水-沉积物体系交互迁移的影响。结果表明：1）我国地表水中检测到的PPCPs浓度为未检出（ND）~9 785 ng/L，检出率和浓度较高的PPCPs有20种，浓度最高的为非抗生素类药物的咖啡因（CAF），其次为红霉素（ETM）和磺胺甲噁唑（SMX）。我国七大地区地表水中浓度最高的PPCPs是非抗生素类药物兴奋剂，其在华北、华南、西南和西北地区污染程度较高；其次是抗生素类药物中的大环内酯类和磺胺类，其在东北、华东和华中地区污染程度较高。华北地区地表水中PPCPs污染程度最高，其次为华东地区。2）我国水体沉积物中检测到的PPCPs浓度为ND~3 440 ng/g，检出率和浓度较高的PPCPs有18种，其中浓度最高的是三氯卡班（TCC），其次是土霉素（OTC）和诺氟沙星（NOR）。我国七大地区沉积物中浓度最高的PPCPs是个人护理品抗菌剂，其在华南地区污染程度最高；其次是四环素类和喹诺酮类，其中四环素类在华东、华中和东北地区污染程度较高，喹诺酮类在华北、西北和西南地区污染程度较高。华南地区沉积物中PPCPs污染程度最高，其次为华东地区。3）我国地表水和沉积物中PPCPs浓度在世界范围内处于较高水平。水-沉积物体系的交互迁移主要受PPCPs自身性质和沉积物组分的影响，需要进一步明确沉积物组分和水环境条件等多因素耦合作用下的PPCPs交互迁移机制。
- 药品及个人护理品（PPCPs） /
- 地表水 /
- 沉积物 /
- 抗生素 /
- 交互迁移 /
- 七大地区
Abstract:
Pharmaceuticals and personal care products (PPCPs), as a class of typical new pollutants, are often detected in the water environment due to their widespread use and pseudo-persistence, which has aroused worldwide attention. Sediments are important environmental repositories of PPCPs, and polluted sediments can be regarded as long-term pollution sources to cause the pollution of the overlying water. The research results at home and abroad in recent years were reviewed, the occurrence of PPCPs in typical surface water and sediment in seven regions of China were analyzed, and the effects of PPCPs characteristics, sediment components and environmental factors on the interaction migration of PPCPs in water-sediment system were summarized. The results showed as follows:1) The concentration of PPCPs detected in surface water in China ranged from undetected (ND) to 9 785 ng/L. There were 20 kinds of PPCPs with high detection rates and concentrations. The highest concentration was with caffeine (CAF), a non-antibiotic drug, followed by erythromycin (ETM) and sulfamethoxazole (SMX). PPCPs with the highest pollution concentration in the surface water of seven regions of China were non-antibiotic stimulants, which were highly polluted in North China, South China, and Southwest and Northwest, followed by macrolides and sulfonamides in antibiotics which were highly polluted in Northeast, East China and Central China. The highest level of PPCPs pollution in surface water was found in North China, followed by East China. 2) The concentration of PPCPs detected in sediments in China was ND-3 440 ng/g. There were 18 kinds of PPCPs with high detection rates and concentrations, among which triclocarban (TCC) had the highest concentration, followed by oxytetracycline (OTC) and norfloxacin (NOR). PPCPs with the highest pollution concentration in the sediments of seven regions of China were personal care antibacterial agents, with the highest pollution degree in South China, followed by tetracycline and quinolones. Tetracycline pollution degree was higher in East China, Central China and Northeast, and quinolones pollution degree was higher in north China, Northwest and Southwest. The pollution degree of PPCPs in sediments in South China was the highest, followed by East China. 3) PPCPs concentrations in surface water and sediments in China were at a higher level worldwide. The interaction migration of water-sediment system was mainly affected by the nature of PPCPs and sediment components, and the interaction migration mechanism of PPCPs under the coupling effect of sediment components and water environment conditions needed to be further clarified.
- pharmaceuticals and personal care products (PPCPs) /
- surface water /
- sediment /
- antibiotic /
- interactive migration /
- seven regions ofChina

HTML全文

图 1 我国七大地区地表水中主要赋存的PPCPs及检测到的最高浓度^{[16-21,24-29,31-43,54]}

Figure 1. Main PPCPs and the highest concentrations detected in surface water from seven regions of China

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图 2 我国七大地区地表水体沉积物中主要赋存的PPCPs及检测到的最高浓度^{[17,21,25-26,29-30,34-37,40,43-44,58-62,64]}

Figure 2. Main PPCPs and the highest concentrations detected in sediments from surface water bodies of seven regions of China

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表 1 我国七大地区地表水中易检测到的20种PPCPs及其浓度

Table 1. 20 kinds of PPCPs and their concentrations in surface water from seven regions of China

PPCPs类别		污染物名称	使用类型	浓度/（ng/L）	数据来源
抗生素类药物	磺胺类（SAs）	磺胺甲噁唑（SMX）	人兽共用	ND~1 830.2	文献[16-44]
		磺胺甲嘧啶（SMZ）	人兽共用	ND~654.0	文献[16-21,24-33,36-38]
		磺胺嘧啶（SDZ）	人兽共用	ND~520	文献[16-21,24-33,36-38]
		甲氧苄啶（TMP）	人用	ND~976.10	文献[16-21,24-33,36-38]
	喹诺酮类 (QNs)	诺氟沙星（NOR）	人兽共用	ND~403	文献[16-44]
		氧氟沙星（OFL）	人兽共用	ND~632.52	文献[16-44]
		环丙沙星（CIP）	人用	ND~414	文献[16-44]
	四环素类 (TCs)	四环素（TC）	人兽共用	ND~250.37	文献[16-44]
	四环素类 (TCs)	土霉素（OTC）	人兽共用	ND~321	文献[16-44]
	大环内酯类 (MLs)	红霉素（ETM）	人兽共用	ND~2 834.6	文献[16-44]
	大环内酯类 (MLs)	罗红霉素（ROX）	人用	ND~740.99	文献[16-21,24-33,36-38,42,44]
	其他类	林可霉素(LIN)	人兽共用	ND~407.12	文献[16-21,24-33,36-38]
非抗生素类药物	非甾体抗炎药	双氯芬酸（DIC）	人用	ND~645	文献[16-21,24-33,36-38,41-44]
		布洛芬（IBU）	人用	ND~362	文献[16-21,24-33,36-38,41-44]
		对乙酰氨基酚（ATP）	人用	ND~960	文献[16-21,24-33,36-38,41-44]
	抗癫痫药	卡马西平（CBZ）	人用	ND~271.02	文献[16-21,24-33,36-38,41-44]
	兴奋剂	咖啡因（CAF）	人用	ND~9 785	文献[16-21,24-33,36-38, 41-44]
个人护理品	抗菌剂	三氯生（TCS）	人用	ND~282	文献[16-21,24-33,36-38,41-44]
	抗菌剂	三氯卡班（TCC）	人用	ND~210	文献[16-21,24-33,36-38,41-44]
	杀虫剂	避蚊胺（DEET）	兽用	ND~574.75	文献[16-21,24-33,36-38,41-44]
注：ND为未检出。

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表 2 我国七大地区水体沉积物中易检测到的18种PPCPs及其浓度

Table 2. 18 kinds of PPCPs and their concentrations in sediments from seven regions of China

PPCPs类别		污染物名称	使用类型	浓度/（ng/g）	数据来源
抗生素类药物	磺胺类（SAs）	磺胺甲噁唑（SMX）	人兽共用	ND~688.59	文献[17,21,25-26,29-30,34-36,40,43-44,58-64]
		磺胺甲嘧啶（SMZ）	人兽共用	ND~122.29	文献[17,21,25-26,29-30]
		甲氧苄啶（TMP）	人用	ND~103	文献[17,21,25-26,29-30,34-36]
	喹诺酮类 (QNs)	诺氟沙星（NOR）	人兽共用	ND~1 140	文献[17,21,25-26,29-30,34-36,40,43-44,58-64]
		氧氟沙星（OFL）	人兽共用	ND~452	文献[17,21,25-26,29-30,34-36]
		环丙沙星（CIP）	人用	ND~449	文献[17,21,25-26,29-30,34-36]
	四环素类 (TCs)	四环素（TC）	人兽共用	ND~635	文献[17,21,25,26,29-30,34-36,40,43,44,58-64]
	四环素类 (TCs)	土霉素（OTC）	人兽共用	ND~1 290	文献[17,21,25-26,29-30,34-36,40,43-44,58-64]
	大环内酯类 (MLs)	红霉素（ETM）	人兽共用	ND~175.38	文献[17,21,25-26,29-30,34-36,40,43-44,58-64]
	大环内酯类 (MLs)	罗红霉素（ROM）	人用	ND~302	文献[17,21,25-26,29-30, 34-36]
	其他类	林可霉素（LIN）	人兽共用	ND~47.8	文献[17,21,25-26,29-30]
非抗生素类药物	非甾体抗炎药	双氯芬酸（DIC）	人用	ND~278.1	文献[17,21,25-26,29-30, 34-37]
		布洛芬（IBU）	人用	ND~227.1	文献[17,21,25-26,29-30,34-37]
		对乙酰氨基酚（ATP）	人用	ND~320.7	文献[17,21,25-26,29-30,34-37]
	抗癫痫药	卡马西平（CBZ）	人用	ND~54.2	文献[17,21,25-26,29-30,34-37]
	兴奋剂	咖啡因（CAF）	人用	ND~482	文献[17,21,25-26,29-30,34-37]
个人护理品	抗菌剂	三氯生（TCS）	人用	ND~689	文献[17,21,25-26,29-30,34-37]
个人护理品	抗菌剂	三氯卡班（TCC）	人用	ND~3 440	文献[17,21,25-26,29-30,34-37]
注：ND为未检出。

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表 3 PPCPs在水-沉积物体系的分配系数

Table 3. Distribution coefficient of PPCPs in water-sediment system

地区	PPCPs类型	污染物名称	K_d/(L/kg)
太湖^[61]	大环内酯类(MLs)	阿奇霉素（AZM）	72.0
	非抗生素类药物	对乙酰氨基酚（ATP）	0.435
		地尔硫卓（DIL）	12.3
		卡马西平（CBZ）	7.35
		咖啡因（CAF）	0.201
上海青浦区水环境^[29]	非抗生素类药物	酮洛芬（KPF）	2.86
上海青浦区水环境^[29]	个人护理品	三氯卡班（TCC）	5.61
围场县水体^[77]	磺胺类(SAs)	磺胺甲噁唑（SMX）	2.88
	四环素类(TCs)	土霉素（OTC）	2 162.2
	喹诺酮类(QNs)	氧氟沙星（NOR）	926.6
	大环内酯类(MLs)	罗红霉素（ROM）	4.00
	非抗生素类药物	咖啡因（CAF）	1.43
南海海陵湾^[78]	四环素类(TCs)	四环素（TC）	1 608
南海海陵湾^[78]	大环内酯类(MLs)	红霉素（ETM）	359
黄河三角洲^[79]	四环素类(TCs)	四环素（TC）	765.93
黄河三角洲^[79]	大环内酯类(MLs)	红霉素（ETM）	230.14

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