污染场地修复后再利用的典型安全风险及长期监管策略研究

史鹏飞; 彭政; 马妍; 艾圣基; 程芦; 王丽芳; 于靖靖; 李发生

doi:10.12153/j.issn.1674-991X.20220841

污染场地修复后再利用的典型安全风险及长期监管策略研究

doi: 10.12153/j.issn.1674-991X.20220841

史鹏飞^{1, 2, 3,},
彭政²,
马妍³,
艾圣基³,
程芦³,
王丽芳²,
于靖靖¹,
李发生^1, ,

1.
环境基准与风险评估国家重点实验室, 中国环境科学研究院
2.
生态环境部对外合作与交流中心
3.
中国矿业大学(北京)化学与环境工程学院

基金项目: 国家重点研发计划项目(2018YFC1801405)；中国矿业大学（北京）越崎青年学者资助计划（2019QN09）；中央高校基本科研业务费专项资金资助（2022SKHH01）

详细信息

作者简介:
史鹏飞（1995—），男，博士研究生，主要从事污染场地风险管控研究，shijh2021@163.com

通讯作者:
李发生（1966—），男，研究员，博士，主要从事污染场地风险评估与修复研究，lifs@craes.org.cn

中图分类号: X53
计量
- 文章访问数: 250
- HTML全文浏览量: 351
- PDF下载量: 53
- 被引次数: 0
出版历程
- 收稿日期: 2022-08-25
- 录用日期: 2023-04-21
- 修回日期: 2022-10-13
- 网络出版日期: 2023-05-15

Typical safety risk and long-term management strategies for post-remediation site reuse

SHI Pengfei^{1, 2, 3
,},
PENG Zheng²,
MA Yan³,
AI Shengji³,
CHENG Lu³,
WANG Lifang²,
YU Jingjing¹,
LI Fasheng^{1
, ,}

1.
State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese Research Academy of Environmental Sciences
2.
Foreign Environmental Cooperation Center, Ministry of Ecology and Environment
3.
School of Chemical & Environmental Engineering, China University of Mining & Technology (Beijing)

摘要

摘要:
从国内外工程实践看，部分污染程度较重、污染情况复杂的场地，修复后再利用过程中对人体健康、生态环境或工程建设会产生一定的安全风险。长期监管是保障修复后场地安全再利用的核心措施，目前我国在这方面的研究还很不足。统计分析了我国近年来550个污染场地案例数据，结果表明修复后场地再开发为居住用地类型的占比达58.7%；在此基础上剖析了重金属污染场地固化/稳定化后再释放和有机污染场地修复后蒸气入侵2类典型安全风险。借鉴国外的长期监管经验，结合国内案例实践，从长期监测、制度控制、定期回顾、公众参与及场地档案管理5个方面提出了针对上述典型安全风险的长期监管建议。
- 修复后场地 /
- 再利用 /
- 安全风险 /
- 重金属再释放 /
- 有机污染物蒸气入侵 /
- 长期监管
Abstract:
From the view of engineering practices at home and abroad, the reuse of heavily polluted and complex post-remediation site often poses safety risks to human health, ecological environment or engineering construction. Long-term stewardship is the core strategy to ensure the safe reuse of post-remediation sites. However, relevant studies in this field are still insufficient in China. Based on the statistical analysis of 550 cases of contaminated sites in China, the results showed that 58.7% of post-remediation sites were redeveloped for residential purposes. Two typical safety risk problems, including heavy metal re-release after solidification/stabilization and vapor intrusion of organic pollutants, were analyzed. Based on foreign advanced long-term stewardship experience and domestic practices, suggestions for long-term stewardship and improvement of the above typical safety risks were put forward from five aspects, including long-term monitoring, institutional control, regular review, public participation and site archives management.
- post-remediation site /
- reuse /
- safety risk /
- heavy metal release /
- vapor intrusion of organic pollutants /
- long-term stewardship

HTML全文

图 1 我国2011—2022年污染场地再利用时间-区域矩阵分析

注：其他地区包含山东省、山西省、河南省、湖北省、江西省、湖南省、福建省、广西壮族自治区、青海省和新疆维吾尔自治区。

Figure 1. Time-region matrix of contaminated sites reuse in China from 2011 to 2022

下载: 全尺寸图片幻灯片

图 2 我国再利用场地污染物出现频次及修复后再利用类型分析

Figure 2. Occurrence frequency of pollutants and types of post-remediation site reuse in China

下载: 全尺寸图片幻灯片

图 3 污染场地修复后再利用的潜在风险发生过程分析

Figure 3. Process of the potential risk of post-remediation site reuse

下载: 全尺寸图片幻灯片

图 4 我国污染场地修复后再利用长期监管框架和措施建议

Figure 4. Suggestion of long-term stewardship framework and countermeasures for reuse of post-remediation site in China

下载: 全尺寸图片幻灯片

参考文献(52)

[1]	马妍, 王盾, 徐竹, 等.北京市工业污染场地修复现状、问题及对策[J]. 环境工程,2017,35(10):120-124. MA Y, WANG D, XU Z, et al. Current situation, problems and countermeasures of industrial contaminated sites remediation in Beijing[J]. Environmental Engineering,2017,35(10):120-124.
[2]	李旭, 聂小琴, 舒天楚, 等.中美管理政策差异对污染场地安全利用的启示[J]. 环境污染与防治,2021,43(4):510-515. LI X, NIE X Q, SHU T C, et al. The enlightenment of the management policy differences between China and the United States on the safe reuse of contaminated sites[J]. Environmental Pollution & Control,2021,43(4):510-515.
[3]	可欣, 周燕, 张飞杰, 等.污染场地修复药剂安全利用问题及对策[J]. 环境科学研究,2021,34(6):1473-1481. KE X, ZHOU Y, ZHANG F J, et al. Problems and strategies of safe utilization of agents for contaminated sites[J]. Research of Environmental Sciences,2021,34(6):1473-1481.
[4]	马杰. 污染场地VOCs蒸气入侵风险评估与管控[M]. 北京: 科学出版社, 2020.
[5]	HOU D Y, GUTHRIE P, RIGBY M. Assessing the trend in sustainable remediation: a questionnaire survey of remediation professionals in various countries[J]. Journal of Environmental Management, 2016, 184(1): 18-26.
[6]	谷庆宝, 侯德义, 伍斌, 等.污染场地绿色可持续修复理念、工程实践及对我国的启示[J]. 环境工程学报,2015,9(8):4061-4068. doi: 10.12030/j.cjee.20150876 GU Q B, HOU D Y, WU B, et al. Conception and project practice of green and sustainable site remediation and its implications for China[J]. Chinese Journal of Environmental Engineering,2015,9(8):4061-4068. doi: 10.12030/j.cjee.20150876
[7]	土壤污染防治法[EB/OL]. (2018-08-31)[2022-06-28]. http://www.mee.gov.cn/ywgz/fgbz/fl/201809/t20180907_549845.shtml.
[8]	生态环境部. 污染地块风险管控与土壤修复效果评估技术导则(试行): HJ 25.5—2018[S]. 北京: 中国环境出版社, 2018.
[9]	生态环境部. 污染地块地下水修复和风险管控技术导则: HJ 25.6—2019[S]. 北京: 中国环境出版社, 2019.
[10]	于靖靖, 梁田, 罗会龙, 等.近10年来我国污染场地再利用的案例分析与环境管理意义[J]. 环境科学研究,2022,35(5):1110-1119. YU J J, LIANG T, LUO H L, et al. Case analysis and environmental management significance of contaminated site reuse in China from 2011 to 2021[J]. Research of Environmental Sciences,2022,35(5):1110-1119.
[11]	VISENTIN C, da SILVA TRENTIN A W, BRAUN A B, et al. Application of life cycle assessment as a tool for evaluating the sustainability of contaminated sites remediation: a systematic and bibliographic analysis[J]. Science of the Total Environment,2019,672:893-905. doi: 10.1016/j.scitotenv.2019.04.034
[12]	ZHAO F J, MA Y B, ZHU Y G, et al. Soil contamination in China: current status and mitigation strategies[J]. Environmental Science & Technology,2015,49(2):750-759.
[13]	葛锋, 张转霞, 扶恒, 等.我国有机污染场地现状分析及展望[J]. 土壤,2021,53(6):1132-1141. GE F, ZHANG Z X, FU H, et al. Distribution of organic contaminated sites in China: statu quo and prospect[J]. Soils,2021,53(6):1132-1141.
[14]	张海博, 张林波, 李岱青, 等.基于DESYRE模型的污染场地修复决策研究[J]. 环境工程技术学报,2012,2(4):339-348. ZHANG H B, ZHANG L B, LI D Q, et al. Research of decision for contaminated site remediation based on DESYRE model[J]. Journal of Environmental Engineering Technology,2012,2(4):339-348.
[15]	侯德义, 张凯凯, 王刘炜, 等.工业场地重金属污染土壤治理现状与展望[J]. 环境保护,2021,49(20):9-15. HOU D Y, ZHANG K K, WANG L W, et al. Current status and prospect for the remediation of heavy metal contaminated industrial sites[J]. Environmental Protection,2021,49(20):9-15.
[16]	KHAN S, NAUSHAD M, LIMA E C, et al. Global soil pollution by toxic elements: current status and future perspectives on the risk assessment and remediation strategies: a review[J]. Journal of Hazardous Materials,2021,417:126039. doi: 10.1016/j.jhazmat.2021.126039
[17]	CHEN Q Y, TYRER M, HILLS C D, et al. Immobilisation of heavy metal in cement-based solidification/stabilisation: a review[J]. Waste Management,2009,29(1):390-403. doi: 10.1016/j.wasman.2008.01.019
[18]	张长波, 罗启仕, 付融冰, 等.污染土壤的固化/稳定化处理技术研究进展[J]. 土壤,2009,41(1):8-15. ZHANG C B, LUO Q S, FU R B, et al. Advances in solidification/stabilization of contaminated soils[J]. Soils,2009,41(1):8-15.
[19]	常春英, 曹浩轩, 陶亮, 等.固化/稳定化修复后土壤重金属稳定性及再活化研究进展[J]. 土壤,2021,53(4):682-691. CHANG C Y, CAO H X, TAO L, et al. Advances on heavy metal stability and reactivation for soil after solidification/stabilization remediation[J]. Soils,2021,53(4):682-691.
[20]	ZHANG X K, WELLS M, NIAZI N K, et al. Nanobiochar-rhizosphere interactions: implications for the remediation of heavy-metal contaminated soils[J]. Environmental Pollution,2022,299:118810. doi: 10.1016/j.envpol.2022.118810
[21]	马妍, 董彬彬, 徐东耀, 等.VOCs/SVOCs污染土壤常用修复技术及其在美国超级基金污染场地中的应用[J]. 环境工程技术学报,2016,6(4):391-396. MA Y, DONG B B, XU D Y, et al. Common used remediation technologies for volatile and semivolatile organic compounds contaminated soils and their application in US superfund sites[J]. Journal of Environmental Engineering Technology,2016,6(4):391-396.
[22]	杨宾, 李慧颖, 伍斌, 等.污染场地中挥发性有机污染工程修复技术及应用[J]. 环境工程技术学报,2013,3(1):78-84. doi: 10.3969/j.issn.1674-991X.2013.01.014 YANG B, LI H Y, WU B, et al. Engineering remediation techniques and its application for volatile organic compounds-contaminated sites[J]. Journal of Environmental Engineering Technology,2013,3(1):78-84. doi: 10.3969/j.issn.1674-991X.2013.01.014
[23]	王珍霞, 宋久浩, 苑文仪, 等.我国污染场地化学氧化修复技术应用特征及再利用潜在腐蚀风险分析[J]. 环境科学研究,2022,35(5):1140-1149. WANG Z X, SONG J H, YUAN W Y, et al. Application characteristics and potential corrosion risks of chemical oxidation remediation technology for contaminated sites in China[J]. Research of Environmental Sciences,2022,35(5):1140-1149.
[24]	SEDLAZECK K P, VOLLPRECHT D, MÜLLER P, et al. Impact of an in situ Cr(Ⅵ)-contaminated site remediation on the groundwater[J]. Environmental Science and Pollution Research International,2020,27(13):14465-14475. doi: 10.1007/s11356-019-07513-9
[25]	LI D, GUI C X, JI G Z, et al. An interpretation to Cr(Ⅵ) leaching concentration rebound phenomenon with time in ferrous-reduced Cr(Ⅵ)-bearing solid matrices[J]. Journal of Hazardous Materials,2019,378:120734. doi: 10.1016/j.jhazmat.2019.06.011
[26]	冯明玉, 韦黎华, 胡清, 等.固化/稳定化修复后场地中铬的环境行为和归趋: 以我国中部某修复后场地为例[J]. 环境科学研究,2022,35(5):1131-1139. FENG M Y, WEI L H, HU Q, et al. Environmental behavior and fate of chromium in solidification/stabilization post-remediation sites: a case study of a remediation site in central China[J]. Research of Environmental Sciences,2022,35(5):1131-1139.
[27]	常春英, 曹浩轩, 陶亮, 等.淹水和干湿交替对修复后土壤铬的稳定性影响研究[J]. 环境科学研究,2022,35(5):1150-1158. CHANG C Y, CAO H X, TAO L, et al. Effects of flooding and dry-wet alternation on the stability of chromium (Cr) in soil after solidification/stabilization remediation[J]. Research of Environmental Sciences,2022,35(5):1150-1158.
[28]	HOU R J, WANG L W, O'CONNOR D, et al. Effect of immobilizing reagents on soil Cd and Pb lability under freeze-thaw cycles: implications for sustainable agricultural management in seasonally frozen land[J]. Environment International,2020,144:106040. doi: 10.1016/j.envint.2020.106040
[29]	董聪慧, 张惠, 梅祖明.过硫酸盐修复有机污染场地建筑物腐蚀性研究[J]. 佳木斯大学学报(自然科学版),2018,36(5):754-757. DONG C H, ZHANG H, MEI Z M. Building corrosion evaluation for persulfate remediating organic contaminated site[J]. Journal of Jiamusi University (Natural Science Edition),2018,36(5):754-757.
[30]	赵玲, 滕应, 骆永明.我国有机氯农药场地污染现状与修复技术研究进展[J]. 土壤,2018,50(3):435-445. doi: 10.13758/j.cnki.tr.2018.03.001 ZHAO L, TENG Y, LUO Y M. Status of organochlorine pesticide contaminated sites in China and advances in site remediation[J]. Soils,2018,50(3):435-445. doi: 10.13758/j.cnki.tr.2018.03.001
[31]	谭冰, 王铁宇, 李奇锋, 等.农药企业场地土壤中苯系物污染风险及管理对策[J]. 环境科学,2014,35(6):2272-2280. TAN B, WANG T Y, LI Q F, et al. Risk assessment and countermeasures of BTEX contamination in soils of typical pesticide factory[J]. Environmental Science,2014,35(6):2272-2280.
[32]	UNNITHAN A, BEKELE D N, CHADALAVADA S, et al. Insights into vapour intrusion phenomena: current outlook and preferential pathway scenario[J]. Science of the Total Environment,2021,796:148885. doi: 10.1016/j.scitotenv.2021.148885
[33]	YAO Y J, SHEN R, PENNELL K G, et al. A review of vapor intrusion models[J]. Environmental Science & Technology,2013,47(6):2457-2470.
[34]	LIU J W, WEI K H, XU S W, et al. Surfactant-enhanced remediation of oil-contaminated soil and groundwater: a review[J]. Science of the Total Environment,2021,756:144142. doi: 10.1016/j.scitotenv.2020.144142
[35]	US Environmental Protection Agency. Evaluating the vapor intrusion to indoor air pathway from groundwater and soils[R]. Washington DC: Office of Land and Emergency Management, US EPA, 2002.
[36]	BASU N B, SURESH P, RAO C, et al. Integration of traditional and innovative characterization techniques for flux-based assessment of Dense Non-aqueous Phase Liquid (DNAPL) sites[J]. Journal of Contaminant Hydrology,2009,105(3/4):161-172.
[37]	US Environmental Protection Agency. Institutional controls: a guide to planning, implementing, maintaining, and enforcing institutional controls at contaminated sites[R]. Washington DC: Office of Land and Emergency Management, US EPA,2012.
[38]	US Environmental Protection Agency. Assessing protectiveness at sites for vapor intrusion. supplement to the comprehensive five-year review guidance[R]. Washington DC: Office of Land and Emergency Management, US EPA, 2012.
[39]	US Environmental Protection Agency. Comprehensive five-year review guidance[R]. Washington DC: Office of Emergency and Remedial Response, US EPA, 2001.
[40]	FLETCHER T. Neighborhood change at Love Canal: contamination, evacuation and resettlement[J]. Land Use Policy,2002,19(4):311-323. doi: 10.1016/S0264-8377(02)00045-5
[41]	孙群郎.美国工业垃圾污染事件与联邦超级基金法的出台[J]. 社会科学战线,2022(1):113-123. SUN Q L. The industrial waste pollution incidents of the US and the introduction of the federal superfund act[J]. Social Science Front,2022(1):113-123.
[42]	MULDOON J, SCHRAMM L L. Gunnar uranium mine environmental remediation: northern Saskatchewan[C]//Proceedings of ASME 2009 12th International Conference on Environmental Remediation and Radioactive Waste Management, Liverpool, UK, 2010: 621-632.
[43]	LTD CH M. HILL AUSTRALIA. Guidelines on long-term monitoring[R]. CRC for contamination assessment and remediation of the environment, 2016: 1-49.
[44]	LAGINESTRA E, PYM J. Long-term stewardship at a remediated site: a study of land use controls used at Sydney Olympic Park, Australia: Brownfield sites Ⅱ: assessment, rehabilitation and development[C]//2nd International Conference on Prevention. Brussels: Assessment, Rehabilitation and Development of Brownfield Sites, 2004: 85-94.
[45]	刘晶晶, 杨勇, 陈恺.有机污染场地修复工程中的大气环境二次污染防治及案例分析[J]. 环境工程技术学报,2018,8(4):381-389. LIU J J, YANG Y, CHEN K. Secondary air pollution prevention and case study in organic pollutants contaminated site remediation project[J]. Journal of Environmental Engineering Technology,2018,8(4):381-389.
[46]	赵彬, 侯德义, 张昊, 等.汞污染地块风险全生命周期管控技术体系研究[J]. 中国环境科学,2022,42(5):2423-2432. doi: 10.3969/j.issn.1000-6923.2022.05.049 ZHAO B, HOU D Y, ZHANG H, et al. Study on the technical system of life cycle risk management for mercury-contaminated sites[J]. China Environmental Science,2022,42(5):2423-2432. doi: 10.3969/j.issn.1000-6923.2022.05.049
[47]	SCANFERLA P, FERRARI G, PELLAY R, et al. An innovative stabilization/solidification treatment for contaminated soil remediation: demonstration project results[J]. Journal of Soils and Sediments,2009,9(3):229-236. doi: 10.1007/s11368-009-0067-z
[48]	GUO Y M, HOLTON C, LUO H, et al. Identification of alternative vapor intrusion pathways using controlled pressure testing, soil gas monitoring, and screening model calculations[J]. Environmental Science & Technology,2015,49(22):13472-13482.
[49]	JOHNSTON J, MACDONALD GIBSON J. Indoor air contamination from hazardous waste sites: improving the evidence base for decision-making[J]. International Journal of Environmental Research and Public Health,2015,12(12):15040-15057. doi: 10.3390/ijerph121214960
[50]	孙兴凯, 黄海, 王海东, 等.大型污染场地修复过程中的问题探讨与工程实践[J]. 环境工程技术学报,2020,10(5):883-890. doi: 10.12153/j.issn.1674-991X.20190216 SUN X K, HUANG H, WANG H D, et al. Discussion of problems in the process of large-scale contaminate sites remediation and project practice[J]. Journal of Environmental Engineering Technology,2020,10(5):883-890. doi: 10.12153/j.issn.1674-991X.20190216
[51]	韩颖, 赵斌, 孟豪, 等.土壤修复档案管理问题及建议[J]. 环境保护,2022,50(6):54-57. doi: 10.14026/j.cnki.0253-9705.2022.06.009 HAN Y, ZHAO B, MENG H, et al. Problems and suggestions of soil remediation archives management[J]. Environmental Protection,2022,50(6):54-57. doi: 10.14026/j.cnki.0253-9705.2022.06.009
[52]	许亚飞, 余勤飞, 毕如田, 等.发达国家污染场地数据库系统建设及其对我国的借鉴[J]. 环境工程技术学报,2013,3(5):458-464. doi: 10.3969/j.issn.1674-991X.2013.05.071 XU Y F, YU Q F, BI R T, et al. Overview of contaminated sites database system construction in developed countries and the revelation to China[J]. Journal of Environmental Engineering Technology,2013,3(5):458-464. ⊗ doi: 10.3969/j.issn.1674-991X.2013.05.071