Study on the comprehensive utilization of nutrients in the anaerobic digestion process of kitchen waste
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摘要:
餐厨垃圾产量大、危害大、回收价值高,合理利用其中磷的资源价值,可规避其污染风险。综合利用情景分析与物质流分析方法,基于情景分析和养分流动概念模型,对苏南地区餐厨垃圾厌氧消化副产物以3种情景进行处理〔沼液进行水处理,沼渣焚烧(情景1,S1);沼液还田,沼渣制有机肥(情景2,S2);沼液进行水处理,沼渣制有机肥(情景3,S3)〕,以100 t的餐厨垃圾处理规模为参考,分析总磷(TP)的物质流。结果表明:S1的餐厨垃圾中有0.99 kg TP还田,最终有0.96 kg TP进入水稻;S2的餐厨垃圾中有64.05 kg TP还田,最终有62.10 kg TP进入水稻;S3的餐厨垃圾中有8.67 kg TP还田,最终有8.49 kg TP进入水稻。结合经济性能对3种情景进行综合评价,发现S2为餐厨垃圾资源化的最优模式,TP的资源化利用率为91.53%,远高于S1和S3。
Abstract:The output of kitchen waste is large, the recycling value is high, the harm is great, and it is urgent to rationally utilize the value of its phosphorus resources to avoid its pollution risk. Scenario analysis and material flow analysis methods were comprehensively used and, based on the scenario analysis concept model and nutrient flow concept model, the material flow analysis of total phosphorus (TP) was conducted for three by-product treatment scenarios of anaerobic digestion of kitchen waste in southern Jiangsu Province. Among the scenarios, Scenario 1 (S1) was water treatment of biogas slurry and biogas residue incineration, Scenario 2 (S2) was biogas slurry returned to the field and biogas residue to organic fertilizer, and Scenario 3 (S3) was water treatment of biogas slurry and biogas residue to organic fertilizer. Taking the 100 t scale of kitchen waste treatment as a reference, the results showed that for S1, 0.99 kg of TP in the kitchen waste was returned to the field, and finally 0.96 kg TP entered the rice. For S2, 64.05 kg of TP was returned to the field in the kitchen waste, and 62.10 kg TP eventually entered the rice. For S3, 8.67 kg of TP was returned to the field in the kitchen waste, and eventually 8.49 kg TP entered the rice. Combined with the economic performance, the three scenarios were comprehensively evaluated, and it was found that S2 was the optimal mode of kitchen waste resource utilization, and the resource utilization rate of TP was 91.53%, which was much higher than that of S1 and S3.
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Key words:
- kitchen waste /
- biogas slurry /
- biogas residue /
- substance flow analysis /
- scenario analysis
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表 1 试验材料、中间产物、产品和不同沼渣沼液处理情景中的质量和营养浓度
Table 1. Quality and nutrient concentration of experimental materials, intermediate products, products and different biogas slurry treatment scenarios
项目 质量/kg TN浓度/
(g/kg)TP浓度/
(g/kg)含水率/% 试验材料 餐厨垃圾 100 2.20 0.68 80 冲洗水 15 100 预处理残渣 有机残渣 8 5.53 0.6 75 无机残渣 1.9 ≤70 有机残渣 毛油 2.1 0.7 虫粪 1.68 4.01 0.59 65 其他 1.6 23.44 2.4 60 沼渣及沼液
分离物消化液 95.5 2.67 0.61 98 沼液 92.3 2.7 0.6 98.5 沼渣 3.2 26.24 7.68 80 S1 虫粪有机肥 0.27 16.2 3.68 23 水处理废水 88.3 0.07 0.008 99.5 水处理污泥 3.4 21.44 16.07 80 S2 虫粪有机肥 0.27 16.2 3.68 23 沼渣有机肥 1.07 20.31 7.18 30 沼液有机肥 92.3 2.7 0.6 98.5 S3 虫粪有机肥 0.27 16.2 3.68 23 水处理污泥 3.4 21.44 16.07 99.5 沼渣有机肥 1.07 20.31 7.18 30 水处理废水 88.3 0.07 0.008 99.5 表 2 经济性能分析指标
Table 2. Economic performance analysis indicators
处理类型 成本/(元/t) 利润/(元/t) 沼液水处理 300 0 沼渣焚烧 300 0 沼液还田 60 0 沼渣堆肥 150 460 处理情景 技术路径 处理量/t 产品量/t 成本/元 利润/元 净收益/元 S1 沼液水处理 92.3 27 690 0 −28 650.0 沼渣焚烧 3.2 960 0 S2 沼液还田 92.3 5 538 0 −5 525.8 沼渣堆肥 3.2 1.07 480 492.2 S3 沼液水处理 92.3 27 690 0 −27 677.8 沼渣堆肥 3.2 1.07 480 492.2 表 4 S2沼液还田处理成本
Table 4. Sensitivity analysis of S2 biogas slurry returning to the field
元 沼液还田处理量/t 单位处理成本/(元/t) 48 51 54 57 60 63 66 69 72 73.80 3 542.40 3 763.80 3 985.20 4 206.60 4 428.00 4 649.40 4 870.80 5 092.20 5 313.60 78.46 3 766.08 4 001.46 4 236.84 4 472.22 4 707.60 4 942.98 5 178.36 5 413.74 5 649.12 83.07 3 987.36 4 236.57 4 485.78 4 734.99 4 984.20 5 233.41 5 482.62 5 731.83 5 981.04 87.70 4 209.60 4 472.70 4 735.80 4 998.90 5 262.00 5 525.10 5 788.20 6 051.30 6 314.40 92.30 4 430.40 4 707.30 4 984.20 5 261.10 5 538.00 5 814.90 6 091.80 6 368.70 6 645.60 96.92 4 652.16 4 942.92 5 233.68 5 524.44 5 815.20 6 105.96 6 396.72 6 687.48 6 978.24 101.53 4 873.44 5 178.03 5 482.62 5 787.21 6 091.80 6 396.39 6 700.98 7 005.57 7 310.16 106.15 5 095.20 5 413.65 5 732.10 6 050.55 6 369.00 6 687.45 7 005.90 7 324.35 7 642.80 110.76 5 316.48 5 648.76 5 981.04 6 313.32 6 645.60 6 977.88 7 310.16 7 642.44 7 974.72 -
[1] 树萌. 餐厨垃圾无害化处理迫在眉睫[J]. 环境经济,2018(增刊3):94-95. [2] 袁振宏, 罗文, 邢涛, 等. 中科院创新技术破解餐厨垃圾回收难题: 我国餐厨垃圾油气肥绿色联产技术实现资源综合利用[J]. 科技促进发展,2016(3):361-365. [3] 朱琳, 安立超, 戴昕, 等. 餐厨垃圾生物有机肥对贫瘠黄褐土改良的研究[J]. 环境科学研究,2020,33(8):1954-1963.ZHU L, AN L C, DAI X, et al. Improvement of barren yellow cinnamon soil by kitchen waste bio-organic fertilizer[J]. Research of Environmental Sciences,2020,33(8):1954-1963. [4] ABDALLAH M, HAMDAN S, SHABIB A. A multi-objective optimization model for strategic waste management master plans[J]. Journal of Cleaner Production,2021,284:124714. doi: 10.1016/j.jclepro.2020.124714 [5] 吕凡, 章骅, 邵立明, 等. 基于物质流分析餐厨垃圾厌氧消化工艺的问题与对策[J]. 环境卫生工程,2017,25(1):1-9.LÜ F, ZHANG H, SHAO L M, et al. Problems of anaerobic digestion process to deal with food waste and its countermeasures through material flow analysis[J]. Environmental Sanitation Engineering,2017,25(1):1-9. [6] 夏天明, 黄凯锋, 李鸣晓, 等. 湿热预处理对餐厨废弃物厌氧产氢发酵类型的影响[J]. 环境工程技术学报,2014,4(2):150-157.XIA T M, HUANG K F, LI M X, et al. Impact of kitchen waste hydrothermal pre-treatment on anaerobic fermentation type and hydrogen production[J]. Journal of Environmental Engineering Technology,2014,4(2):150-157. [7] BÖRJESON L, HÖJER M, DREBORG K H, et al. Scenario types and techniques: towards a user's guide[J]. Futures,2006,38(7):723-739. doi: 10.1016/j.futures.2005.12.002 [8] YAKUBU S O, FALCONER L, TELFER T C. Scenario analysis and land use change modelling reveal opportunities and challenges for sustainable expansion of aquaculture in Nigeria[J]. Aquaculture Reports,2022,23:101071. doi: 10.1016/j.aqrep.2022.101071 [9] SUN Y, LIU S, WANG P, et al. China's roadmap to plastic waste management and associated economic costs[J]. Journal of Environmental Management,2022,309:114686. doi: 10.1016/j.jenvman.2022.114686 [10] 刘永, 郭怀成, 王丽婧, 等. 环境规划中情景分析方法及应用研究[J]. 环境科学研究,2005,18(3):82-87.LIU Y, GUO H C, WANG L J, et al. Scenario analysis and its application in environmental planning[J]. Research of Environmental Sciences,2005,18(3):82-87. [11] ISLAM M T, HUDA N. Material flow analysis (MFA) as a strategic tool in E-waste management: applications, trends and future directions[J]. Journal of Environmental Management,2019,244:344-361. [12] TASMEEA T, ROY B B, CHOWDHURY R B, et al. Urban metabolism of phosphorus in the food production-consumption system of Bangladesh[J]. Journal of Environmental Management,2021,292:112715. doi: 10.1016/j.jenvman.2021.112715 [13] HAN J C, SHANG F Z, LI P, et al. Coupling Bayesian-Monte Carlo simulations with substance flow analysis for efficient pollutant management: a case study of phosphorus flows in China[J]. Resources, Conservation and Recycling,2021,169:105550. doi: 10.1016/j.resconrec.2021.105550 [14] 党春阁, 王璠, 赵志远, 等. 基于黄磷生产工艺的磷物质流分析及磷污染减排对策[J]. 环境工程技术学报,2020,10(6):1007-1011.DANG C G, WANG F, ZHAO Z Y, et al. Analysis of phosphorus material flow based on yellow phosphorus production process and countermeasures for phosphorus pollution reduction[J]. Journal of Environmental Engineering Technology,2020,10(6):1007-1011. [15] 陈敏鹏, 郭宝玲, 刘昱, 等. 磷元素物质流分析研究进展[J]. 生态学报,2015,35(20):6891-6900.CHEN M P, GUO B L, LIU Y, et al. Research on phosphorus flow analysis: progress and perspectives[J]. Acta Ecologica Sinica,2015,35(20):6891-6900. [16] LALANDER C, ERMOLAEV E, WIKLICKY V, et al. Process efficiency and ventilation requirement in black soldier fly larvae composting of substrates with high water content[J]. Science of the Total Environment,2020,729:138968. doi: 10.1016/j.scitotenv.2020.138968 [17] KAWASAKI K, KAWASAKI T, HIRAYASU H, et al. Evaluation of fertilizer value of residues obtained after processing household organic waste with black soldier fly larvae ( Hermetia illucens)[J]. Sustainability,2020,12(12):4920. doi: 10.3390/su12124920 [18] ZENG Y, de GUARDIA A, DABERT P. Improving composting as a post-treatment of anaerobic digestate[J]. Bioresource Technology,2016,201:293-303. doi: 10.1016/j.biortech.2015.11.013 [19] ESPINOSA-SALGADO R, SAUCEDO-CASTAÑEDA G, MONROY-HERMOSILLO O, et al. Composting a digestate from the organic fraction of urban solid wastes[J]. Revista Mexicana De Ingeniería Química,2020,19(1):1-8. [20] ZHANG Z P, HU M, BIAN B, et al. Full-scale thermophilic aerobic co-composting of blue-green algae sludge with livestock faeces and straw[J]. Science of the Total Environment,2021,753:142079. doi: 10.1016/j.scitotenv.2020.142079 [21] CHIEW Y L, SPÅNGBERG J, BAKY A, et al. Environmental impact of recycling digested food waste as a fertilizer in agriculture: a case study[J]. Resources, Conservation and Recycling,2015,95:1-14. doi: 10.1016/j.resconrec.2014.11.015 [22] YUAN Z W, JI J Y, SHENG H, et al. Animal based diets and environment: perspective from phosphorus flow quantifications of livestock and poultry raising in China[J]. Journal of Environmental Management,2019,244:199-207. [23] ZHU Z L, CHEN D L. Nitrogen fertilizer use in China: contributions to food production, impacts on the environment and best management strategies[J]. Nutrient Cycling in Agroecosystems,2002,63(2):117-127. [24] LIU X W, YUAN Z W, LIU X, et al. Historic trends and future prospects of waste generation and recycling in China's phosphorus cycle[J]. Environmental Science & Technology,2020,54(8):5131-5139. [25] 黄元宸, 刘帅, 宁祉恺, 等. 苏州工业园区餐厨垃圾产生现状及收运方案研究[J]. 环境卫生工程,2021,29(5):62-68. [26] 李笑寒, 陈子惟, 刘咏妍, 等. 基于情景分析的城市餐厨垃圾处理方案研究[J]. 中国环境管理,2013,5(2):17-20. ⊗