工业废水有毒有机物全过程控制技术策略与实践

周岳溪; 宋玉栋; 蒋进元; 席宏波; 赖波

doi:10.3969/j.issn.1674-991X.2011.01.002

工业废水有毒有机物全过程控制技术策略与实践

doi: 10.3969/j.issn.1674-991X.2011.01.002

中国环境科学研究院水污染控制中心

详细信息

作者简介:
周岳溪，男，研究员，博士，主要从事水污染控制工程技术研究

通讯作者:
周岳溪 E-mail: zhouyuexi@263.net

中图分类号: X703.1
计量
- 文章访问数: 7280
- HTML全文浏览量: 220
- PDF下载量: 2159
- 被引次数: 0
出版历程
- 收稿日期: 2010-10-08
- 修回日期: 2010-11-03
- 刊出日期: 2011-01-20

Whole-Process Control Techniques and Practices for Toxic Organics in Industrial Wastewaters

Research Center of Water Pollution Control Technologies,Chinese Research Academy of Environmental Sciences

More Information

Corresponding author: ZHOU Yue-xi E-mail: zhouyuexi@263.net

摘要

摘要: 工业废水有毒有机物削减，是构建我国以人体健康和水生态系统安全为水环境目标的流域水质目标管理体系的重要环节之一。笔者归纳国外成功经验，结合我国国情，提出立足“生产-污染控制”系统的整体优化，对工业废水有毒有机物进行全过程控制的综合防治技术策略：以废水有机物排放源解析为基础，通过生产工艺改进和管理减排等措施减少进入废水处理系统的污染物量；选择废水分质处理策略，根据废水水质特性，通过有机物回收及强化降解技术实现有毒有机废水的预处理，通过高效生物处理技术实现有毒有机物的生物降解，最后通过深度处理进一步削减有毒有机物的排放量。对于大型工业联合体，通过生产装置内部、生产装置之间、生产装置与综合污水处理厂之间的协同优化，实现资源节约和有毒有机物的高效减排。通过减排技术体系的构建和污染物排放标准的制订推动新型适用废水有毒有机物控制技术的研发和应用。
- 有毒有机物 /
- 工业废水 /
- 全过程控制 /
- 分质处理 /
- 预处理
Abstract: Reduction of toxic organics in industrial wastewater was one of the important links to build watershed quality target management system which considered human health and hydroecology safe as the water environmental targets. By learning from foreign experience and considering the actual situation of China, a whole-process technological strategy for toxic organic pollution control, based on the optimization of production and pollution control as an integrated system, was proposed against the disadvantages of traditional end-of-pipe solution. Analysis and characterization of organic pollutants in the wastewater were the base for the whole-process control. Improving of production process and management practice was used to reduce the amount of toxic organics discharged into wastewater. Then water-quality-based treatment processes were selected for wastewater streams with different characterization. Organic recovery and enhanced-degradation techniques were used for the pretreatment of wastewater. High-efficiency biological processes were used for biodegradation of toxic organics and the advanced treatment was used for further removal of toxic organics. For large-scale industrial complex, an optimization approach involving the inner-workshop, inter-workshop and between workshops and wastewater treatment plant, was proposed for resource conservation and high-efficient elimination of toxic organics. Establishment of technical systems and discharge standards for toxic organic elimination could promote the development and application of advanced technologies greatly.
- toxic organic /
- industrial wastewater /
- whole-process control /
- water-quality-based treatment /
- pretreatment

HTML全文

参考文献(28)

[1]	孟伟,张楠,张远,等.流域水质目标管理技术研究（Ⅰ）:控制单元的总量控制技术[J].环境科学研究,2007,20(4):1-8.
[2]	环境保护部.GB21523—2008 杂环类农药工业水污染物排放标准[S].北京:中国环境科学出版社,2008.
[3]	环境保护部.GB3544—2008 制浆造纸工业水污染物排放标准[S].北京:中国环境科学出版社,2008.
[4]	环境保护部.GB 21904—2008 化学合成类制药工业水污染物排放标准[S].北京:中国环境科学出版社,2008.
[5]	US Environmental Protection Agency.Introduction to the national pretreatment program (EPA-833-B-98-002)[R].Washington DC: Office of Wastewater Management,1999.
[6]	EC of the European Parliament and the Council.Directive 2008/1/EC of the European parliament and of the Council of 15 january 2008 Concerning integrated pollution prevention and control (codified version)[J].Office Journal of the European Union,2008,51(L24):8-29.
[7]	European Commission’s Joint Research Center,Institute for Prospective Technological Studies. Reference documents[EB/OL].Seville:European Commission.[2010-10-24].http://eippcb.jrc.es/reference/.
[8]	EC of the European Parliament and the Council. Directive 2000/60/EC of the European parliament and of the council of 23 october 2000 establishing a framework for community action in the field of water policy[J].Office Journal of the European Communities,2000,43(L327):1-72.
[9]	USEPA.Generalized method for conducting industrial toxicity reduction evaluations[R].EPA/600/2-88/070,April 1989.
[10]	杨芳,付江海,曲凤华,等.从源头治理苯酚丙酮生产废水的技术措施[J].化工科技,2009,17(6):52-54.
[11]	江立文,李耀中,周岳溪,等.负载型TiO2固定相光催化氧化剂固定化技术研究[J].工业水处理，2000,20(9):8-11.
[12]	LI K,JIA J L,ZHOU Y X.Preparation,characterization and investigation of immobilized photocatalysts:in Proceeding of the First Asia-Pacifica Regional Conference[C].Fukouka:[s.n.],2001.
[13]	XI B D, KONG X, ZHOU Y X,et al.Photocatalytic degradation of PCP-NA with Pt/TiO2 coated on hollow glass beads:in Proceeding of the First Asia-Pacifica Regional Conference[C].Fukouka:[s.n.],2001.
[14]	席北斗,刘纯新,周岳溪,等.钛酸四丁酯水解制备TiO2光催化氧化五氯苯酚钠[J].中国环境科学,2000,20(5):65-68.
[15]	席北斗,孔欣,刘纯新,等.加铂修饰型催化剂光催化氧化五氯酚[J].环境化学,2001,20(1):27-30.
[16]	蒋进元,刘纯新,周岳溪,等.PVC附载TiO2光催化剂的制备与评价[J].环境工程，2003,21(4):72-74.
[17]	KONG X,LI Y Z,ZHOU Y X.Treatment of synthesized textile wastewater in a fluidized bed photo-catalytic reactor in pilot-scale: in Proceeding of the First Asia-Pacifica Regional Conference[C].Fukouka:[s.n.],2001.
[18]	LI Y Z,KONG X,ZHOU Y X.Treatment of printing and dyeing industrial wastewater by a pilot–scale fluidized bed photocatalytic plant:in Proceeding of the First Asia-Pacifica Regional Conference[C].Fukouka:[s.n.],2001.
[19]	江立文,李耀中,周岳溪,等.流化床光催化反应器动力学模式[J].中国环境科学,2000,20(6):540-543.
[20]	江立文,李耀中,周岳溪,等.流化光催化反应器降解4BS 染料的研究[J].中国给水排水，2001,17(2):12-15.
[21]	蒋进元,李勇,王国威,等.Fenton法处理腈纶聚合废水[J].环境科学研究.2010,23(7):897-901.
[22]	YANG B, YU G,SHUAI D.Electrocatalytic hydrodechlorination of 4-chlorobiphenyl in aqueous solution using palladized nickel foam cathode[J].Chemosphere,2007,67:1361-1367.
[23]	宋玉栋,杨健,杨靖晖,等.曝气生物流化床处理高浓度含酚废水[J].环境科学研究，2010，23（7）：930-935.
[24]	彭光霞，周岳溪，何绪文，等.高含盐有机废水MDAT-IAT 生物处理工艺研究[J].环境科学研究.2006,19(3):71-74.
[25]	王发珍,周岳溪,左东升,等.A／DAT．IAT生物膜工艺与活性污泥法处理高含盐废水对比试验[J].环境工程,2007,25(5):28-30.
[26]	高欢,蒋进元,胡翔,等.活性染料高温厌氧生物降解研究[J].环境科学研究,2007,20(4):102-105.
[27]	高欢,周岳溪,胡翔,等.含盐染料废水高温厌氧处理工艺特性研究[J].环境工程，2007,25(3):9-11.
[28]	中国环境科学研究院水污染控制技术研究中心.污水同步生物脱氮除磷－光催化氧化深度除理技术[J].研究与发展,2007,(8):1-24.