钢渣作为湿法脱硫吸收剂的实验研究

Experimental Study on Steel Slag Used as Wet Flue Gas Desulfurization Absorbent

  • 摘要: 以钢渣作为吸收剂利用喷射鼓泡法进行湿法脱硫工艺试验研究,通过分析钢渣脱硫前后的组分变化以及脱硫反应机理,研究不同钢渣乳液浓度、喷射管淹没深度下系统的工艺参数,确定系统最佳的反应条件。当钢渣乳液浓度为25%以上,喷射管淹没深度130 mm,pH为6.6~6.8时,系统脱硫效率可达70%以上。钢渣中参与脱硫反应的成分主要为CaO,MgO,Fe2O3,Al2O3等,脱硫反应后的钢渣中游离氧化钙(f–CaO)和MgO浓度大幅降低,避免了钢渣综合利用时因f–CaO和MgO遇水而产生的膨胀问题。分别利用钢渣乳液和石灰石粉末作为吸收剂进行对比试验,结果表明,钢渣乳液与石灰石具有相同的脱硫效果和反应趋势,说明钢渣完全可以取代石灰石作为湿法脱硫吸收剂。

     

    Abstract: Experimental study on jet bubbling wet flue gas desulfurization (FGD) by using steel slag as an absorbent was carried out, and mechanism of FGD reaction studied based upon components of steel slag emulsion variance after FGD reaction. Optimal experiment condition was concluded by considering concentration of steel slag emulsion and depth of jet pipe submerged. Experimental results showed that FGD efficiency could be reached over 70% when the concentration of steel slag emulsion was 25%, the depth of jet pipe submerged was 130 mm, and pH was 6.6-6.8. It was concluded that components of CaO, MgO, Fe2O3, Al2O3 contained in steel slag could be effective in FGD desulfurization, and content of f-CaO and MgO in steel slag emulsion decreased after the FGD reaction, thus avoid the problem of FGD by-product expansion in case of water caused by f-CaO and MgO. Comparative experiments were conducted by using steel slag emulsion and limestone powder as absorbents, and the results showed obvious agreement obtained by using steel slag emulsion and limestone as FGD reaction respectively, and therefore steel slag could be used as wet FGD absorber replacing limestone.

     

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