新型助凝剂海藻酸钠的助凝效能及作用机制研究

祝苑, 潘丁瑞, 汪艳, 成淑媛, 王立章, 王倩, 赵爽

祝苑, 潘丁瑞, 汪艳, 成淑媛, 王立章, 王倩, 赵爽. 新型助凝剂海藻酸钠的助凝效能及作用机制研究[J]. 环境工程技术学报, 2019, 9(6): 680-684. DOI: 10.12153/j.issn.1674-991X.2019.05.150
引用本文: 祝苑, 潘丁瑞, 汪艳, 成淑媛, 王立章, 王倩, 赵爽. 新型助凝剂海藻酸钠的助凝效能及作用机制研究[J]. 环境工程技术学报, 2019, 9(6): 680-684. DOI: 10.12153/j.issn.1674-991X.2019.05.150
ZHU Yuan, PAN Dingrui, WANG Yan, CHENG Shuyuan, WANG Lizhang, WANG Qian, ZHAO Shuang. Study on coagulation aid efficiency and mechanism of new coagulant sodium alginate[J]. Journal of Environmental Engineering Technology, 2019, 9(6): 680-684. DOI: 10.12153/j.issn.1674-991X.2019.05.150
Citation: ZHU Yuan, PAN Dingrui, WANG Yan, CHENG Shuyuan, WANG Lizhang, WANG Qian, ZHAO Shuang. Study on coagulation aid efficiency and mechanism of new coagulant sodium alginate[J]. Journal of Environmental Engineering Technology, 2019, 9(6): 680-684. DOI: 10.12153/j.issn.1674-991X.2019.05.150

新型助凝剂海藻酸钠的助凝效能及作用机制研究

详细信息
    作者简介:

    祝苑(1997—),女,主要从事新型水处理药剂的研究, 15252086702@163.com

    通讯作者:

    赵爽 E-mail: zhaoshuang5186@163.com

  • 中图分类号: X703

Study on coagulation aid efficiency and mechanism of new coagulant sodium alginate

More Information
    Corresponding author:

    ZHAO Shuang: Shuang ZHAO E-mail: zhaoshuang5186@163.com

  • 摘要: 将海藻酸钠(SA)作为助凝剂,与混凝剂聚合氯化铝(PAC)复配使用,在模拟地表水样的混凝处理中探究其助凝效能,并考察溶液pH对混凝效果的影响,同时通过混凝出水Zeta电位分析其助凝作用机理。结果表明:对模拟地表水样,PAC与SA复配使用时最佳投加量分别为4.00及0.06 mg/L,此时浊度和UV254的去除率分别可达81.9%和78.7%;溶液pH对混凝效果的影响较大,在pH为7.00时SA的助凝效果最佳,此时浊度及UV254的去除率分别可达84.0%和83.7%。与传统助凝剂聚丙烯酰胺(PAM)的对比研究表明,在各自最佳使用条件下,SA可以得到与PAM相当的助凝效果,且SA的投加量远低于PAM,具有较大的成本优势。
    Abstract: Sodium alginate (SA) was used as coagulant aid, combined with the coagulant of polyaluminium chloride (PAC), to explore its coagulation aid efficiency in the coagulation treatment of simulated surface water samples, and the effect of solution pH on coagulation efficiency investigated. Also its coagulation aid mechanism was analyzed by the measurement of Zeta potential of the coagulation effluent. Results showed that the optimal dosage of PAC and SA was 4.00 mg/L and 0.06 mg/L for simulated surface water samples. Under this condition, turbidity and UV254 removal rates reached 81.9% and 78.7%, respectively. Coagulation efficiency was influenced dramatically by solution pH, and coagulation aid effect of SA was best when pH was 7.00. In this condition, turbidity and UV254 removal rate could reach 84.0% and 83.7%, respectively. Additionally, comparative study results showed that coagulation aid efficiency of SA was equal to that of traditional coagulant aid PAM under the optimal conditions. However, SA dosage was much lower than that of PAM, which was a great cost advantage in water treatment.
  • [1]

    EDZWALD J K, TOBIASON J E . Enhanced coagulation:US requirements and a broader view[J]. Water Science and Technology, 1999,40(9):63-70.

    [2]

    BELL-AJY K, ABBASZADEGAN M, IBRAHIM E , et al. Conventional and optimized coagulation for NOM removal[J]. Journal American Water Works Association, 2000,92(10):44-58.

    [3] 韩宏大, 叶伟, 叶长青 , 等. 新型聚合铝的生产性试验研究[J]. 环境科学, 2006,27(4):704-708.

    HAN H D, YE W, YE C Q , et al. Plant scale test of a new efficient poly-aluminum chloride[J]. Environmental Science, 2006,27(4):704-708.

    [4] 岳峥, 马东兵 . 水处理药剂研究进展[J]. 中国资源综合利用, 2008,126(9):33-35.

    YUE Z, MA D B . Development of research on coagulants in water treatment[J]. China Resources Comprehensive Utilization, 2008,126(9):33-35.

    [5] 湛含辉, 李小彬, 戴财胜 , 等. 有机絮凝剂的混凝机理研究[J]. 煤炭科学技术, 2004,32(1):35-37.

    ZHAN H H, LI X B, DAI C S , et al. Research on coagulation flocculation mechanism of organic flocculant[J]. Coal Science and Technology, 2004, 32(1): 32(1):35-37.

    [6]

    SILLANPAA M, NCIBI M C, MATILAINEN A , et al. Removal of natural organic matter in drinking water treatment by coagulation:a comprehensive review[J]. Chemosphere, 2019,190:54-71.

    [7]

    HUANG X, ZHAO Y X, GAO B Y , et al. Polyacrylamide as coagulant aid with polytitanium sulfate in humic acid-kaolin water treatment:effect of dosage and dose method[J]. Journal of the Taiwan Institute of Chemical Engineers, 2016,64:173-179.

    [8]

    YAO M, NAN J, CHEN T , et al. Influence of flocs breakage process on membrane fouling in coagulation/ultrafiltration process:effect of additional coagulant of poly-aluminum chloride and polyacrylamide[J]. Journal of Membrane Science, 2015,491:63-72.

    [9]

    ZHU H C, ZHANG Y, YANG X G , et al. Polyacrylamide grafted cellulose as an eco-friendly flocculant:key factors optimization of flocculation to surfactant effluent[J]. Carbohydrate Polymers, 2016,135:145-152.

    [10] 安东, 顾斌, 张涵 , 等. 饮用水处理中聚丙烯酰胺对氯胺消毒生成NDMA的贡献[J]. 给水排水, 2017,43:41-43.

    AN D, GU B, ZHANG H , et al. Contribution of polyacrylamide to formation of NDMA during chloramination in drinking water treatment[J]. Water and Wastewater Engineering, 2017,43:41-43.

    [11]

    YANG Z L, GAO B Y, WANG Y , et al. The effect of additional poly-diallyl dimethyl ammonium-chloride on the speciation distribution of residual aluminum(Al)in a low DOC and high alkalinity reservoir water treatment[J]. Chemical Engineering Journal, 2012,197:56-66.

    [12] 赵立志, 杜国勇, 冯英 , 等. 水处理中的无机混凝剂与有机絮凝剂的协同作用[J]. 化工时刊, 2005,9(1):21-25.

    ZHAO L Z, DU G Y, FENG Y , et al. Synergism of inorganic coagulation agents and organic flocculator in water processing[J]. Chemical Industry Times, 2005,9(1):21-25.

    [13] 张善明, 刘强, 张善垒 . 从海带中提取高粘度海藻酸钠[J]. 食品工业科技, 2002,23(3):86-87.
    [14]

    LEE K Y, MOONEY D J . Alginate:properties and biomedical applications[J]. Progress in Polymer Science, 2011,37(1):106-126.

    [15]

    HAGEN A, SKJAK B G, DOMISH M . Pharmacokinetics of sodium alginate in mice[J]. European Journal of Pharmaceutical Sciences, 1996,4(Suppl 1):100.

    [16] 樊李红, 杜予民, 唐汝培 , 等. 海藻酸钠/水性聚氨酯共混膜的结构表征和性能测试[J]. 分析科学学报, 2002,18(6):441-444.

    FAN L H, DU Y M, TANG R P , et al. Structure and properties of sodium alginate/waterborne polyurethane blend films[J]. Journal of Analytical Science, 2002,18(6):441-444.

    [17]

    ZHAO S, GAO B Y, WANG Y . Influence of a new coagulant aid-enteromorpha extract on coagulation performance and floc characteristics of aluminum sulfate coagulant in kaolin-humic acid solution treatment[J]. Colloids & Surfaces A Physicochemical & Engineering Aspects, 2013,417(20):161-169.

    [18]

    ZHAO S, GAO B Y, YUE Q Y , et al. Influence of enteromorpha polysaccharides on variation of coagulation behavior,flocs properties and membrane fouling in coagulation-ultrafiltration process[J]. Journal of Hazardous Material, 2015,285(21):294-303.

    [19]

    BI S, WANG C, CAO Q , et al. Studies on the mechanism of hydrolysis and polymerization of aluminum salts in aqueous solution:correlations between the “core-links” model and “cage-like”Keggin-Al13 model[J]. Coordination Chemistry Reviews, 2004,248(5/6):441-455.

    [20] 周勤, 肖锦, 朱云 . 硫酸铝去除给水中腐殖酸机理研究[J]. 工业水处理, 2000,20(5):18-20.

    ZHOU Q, XIAO J, ZHU Y . The study of humic acids removal by aluminum sulfate[J]. Industrial Water Treatment, 2000,20(5):18-20.

    [21] 金鹏康, 王晓昌 . 天然有机物的混凝特性研究[J]. 西安建筑科技大学学报, 2000,32(2):155-159.

    JIN P K, WANG X C . A study on the characteristics of coagulation of natural organic matters[J]. Journal Xi’an University of Architecture & Technology, 2000,32(2):155-159.

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出版历程
  • 收稿日期:  2019-04-15
  • 发布日期:  2019-11-19

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